排序方式: 共有3条查询结果,搜索用时 6 毫秒
1
1.
曹海琳%张杰%黄玉东%杨晓波 《宇航材料工艺》2004,34(2):29-32
以氢氧化铝、氧化铬和磷酸为原料制备磷酸铬铝,通过对反应体系粘度的监测,控制反应程度、确定反应时间。采用DSC-TG和XRD分析研究体系固化特性和耐热性能。对层间剪切强度进行测试.初步评价磷酸铬铝复合材料的性能。结果表明,控制反应时间为1h时可以得到转化率较高、粘度适当的体系。DSC—TG分析表明,该体系固化成型温度低于200℃,成型工艺简单,同时结合。XRD分析证明此材料体系具有优异的耐高温性能。对其复合材料层剪强度的研究发现,增强体材料表面进行涂层保护可有效地克服体系对增强体的腐蚀.有利于复合材料性能的改善。 相似文献
2.
I.V. Delidovich O.P. Taran A.N. Simonov L.G. Matvienko V.N. Parmon 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》2011
The article analyzes new and previously reported data on several catalytic and photochemical processes yielding biologically important molecules. UV-irradiation of formaldehyde aqueous solution yields acetaldehyde, glyoxal, glycolaldehyde and glyceraldehyde, which can serve as precursors of more complex biochemically relevant compounds. Photolysis of aqueous solution of acetaldehyde and ammonium nitrate results in formation of alanine and pyruvic acid. Dehydration of glyceraldehyde catalyzed by zeolite HZSM-5-17 yields pyruvaldehyde. Monosaccharides are formed in the course of the phosphate-catalyzed aldol condensation reactions of glycolaldehyde, glyceraldehyde and formaldehyde. The possibility of the direct synthesis of tetroses, keto- and aldo-pentoses from pure formaldehyde due to the combination of the photochemical production of glycolahyde and phosphate-catalyzed carbohydrate chain growth is demonstrated. Erythrulose and 3-pentulose are the main products of such combined synthesis with selectivity up to 10%. Biologically relevant aldotetroses, aldo- and ketopentoses are more resistant to the photochemical destruction owing to the stabilization in hemiacetal cyclic forms. They are formed as products of isomerization of erythrulose and 3-pentulose. The conjugation of the concerned reactions results in a plausible route to the formation of sugars, amino and organic acids from formaldehyde and ammonia under presumed ‘prebiotic’ conditions. 相似文献
3.
1