环氧改性氰酸酯树脂研究

分别采用E20和E51环氧树脂与双酚A型二氰酸酯(BADCy)共聚来改善氰酸酯树脂的力学性能.用DSC,FTIR研究了两种不同分子量的环氧改性氰酸酯体系的反应性,发现E20和E51对BADCy的固化反应均有催化作用,但E20的催化作用强于E51.断面SEM表明,经E20和E51改性的BADCy断口处存在大量的韧涡.但改性体系的热变形温度(HDT)和吸水率有所下降,当配比(质量)相同时,E51/BADCy体系比E20/BADCy体系具有更高的HDT和较小的吸水率.     

Random copolymer membrane coated PBO fibers with significantly improved interfacial adhesion for PBO fibers/cyanate ester composites

Poly(p-phenylene-2,6-benzobisoxazole) (PBO) fibers possess excellent dielectric, mechanical properties and heat resistance. However, the surface of PBO fibers is smooth and highly chemical inert, resulting in poor interfacial compatibility to polymer matrix, which severely limits its wider application in high-performance fiber-reinforced resin matrix composites. In this work, random copolymers (P(S-co-BCB-co-MMA)) containing benzocyclobutene in the side-chain were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization, which were then utilized to form dense random copolymer membrane on the surface of PBO fibers by thermally cross-linking at 250 °C (PBO@P fibers). Four kinds of synthesized P(S-co-BCB-co-MMA) with different number-average molar mass (M_n) were well controlled and possessed narrow dispersity. When the M_n was 32300, the surface roughness of PBO@P fibers was increased from 11 nm (PBO fibers) to 39 nm. In addition, PBO@P fibers presented the optimal interfacial compatibility with bisphenol A cyanate (BADCy) resins. And the single fiber pull-out strength of PBO@P fibers/BADCy micro-composites was 4.5 MPa, increasing by 45.2% in comparison with that of PBO fibers/BADCy micro-composites (3.1 MPa). Meantime, PBO@P fibers still retained excellent tensile strength (about 5.1 GPa). Overall, this work illustrates a simple and efficient surface functionalization method, which would provide a strong theoretical basis and technical support for controlling the surface structure & chemistry of inert substrates.     

环氧改性氰酸酯复合材料工艺性研究

对环氧E-51改性双酚A型氰酸酯(BADCy)复合材料的铺敷性进行了研究，发现BADCy树脂和环氧E-51树脂经适当预聚后在室温下具有一定的粘性，可制作出具有室温铺敷性的复合材料预浸料。研究还发现，氰酸酯的纯度对预聚反应影响较大，工业品的BADCy具有较高的反应活性，而提纯后的BADCy反应活性低。少量环氧E-51对BADCy的预聚反应有明显促进作用，但大于5份后，这种促进作用不明显。