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《中国航空学报》2019,32(11):2516-2525
The stress corrosion cracking (SCC) susceptibility of 2297 Al-Li alloy in 1 M NaCl + 0.01 M H2O2 solution (CP solution) and 1 M NaCl + 0.01 M H2O2 + 0.6 M Na2SO4 solution (CPS solution) was investigated by slow-strain rate tests at various strain rates ranging from 10−5 s−1 to 10−7 s−1. The roles of H2O2 and SO42− in the corrosion process were estimated by potentiodynamic polarization and electrochemical impedance spectroscopy. 2297 Al-Li alloy does not fracture ascribed to SCC in CP solution, while it undergoes SCC in CPS solution. In CPS solution, with a decreasing strain rate from 10−5 s−1 to 10−7 s−1, the SCC susceptibility firstly rises and then declines exhibiting a peak value at a strain rate of 10−6 s−1. H2O2 promotes the active dissolution while SO42− lowers the corrosion rate. The SCC fracture is associated with a decline in the dissolution rate of the crack tip by SO42−, which leads to stress concentration. In CPS solution, a reduction in the local dissolution rate of the crack tip leads to stress concentration, resulting in SCC fracture. As the preferred initiation site for a crack, pits also show a noteworthy effect on SCC of 2297 Al-Li alloy. 相似文献
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Titanium alloy plays a crucial role in the electrochemical field due to its excellent corrosion resistance. The passivation and dissolution behaviors of Ti-6.5Al-2Zr-1Mo-1V(TA15) alloy in Na Cl solution were studied by simulating the electrochemical machining process in a rotating condition, which made the anode in a state with alternating high and low current density. Electron probe micro analysis, ultra-depth microscope, scanning electron microscope, and X-ray photoelectron spectrometer were u... 相似文献
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