SiO2f/SiO2复合材料自身及其与铜、不锈钢的钎焊

采用AgCuTi活性钎料,在880℃/10min规范下成功实现了SiO2f/SiO2自身、SiO2f/SiO2与Cu和SiO2f/SiO2与1Cr18Ni9Ti三种接头的连接。实验结果表明,三种接头中靠近SiO2f/SiO2母材的界面处均形成了一层薄薄的扩散反应层组织,反应层中出现了Ti和O的富集,根据两者的原子比例推断生成了TiO2相;另外,三种接头中心区都形成了由灰色相和白色相共同组成的Ag-Cu共晶组织,其中灰色相为Cu基固溶体,白色相为Ag基固溶体。接头剪切强度结果显示,SiO2f/SiO2/Cu接头剪切强度为12.4MPa,SiO2f/SiO2/1Cr18Ni9Ti接头剪切强度为18.4MPa,接头中的残余应力是决定接头强度大小的重要因素之一。     

结合钎焊和氩弧焊方法对钛合金/Nb/不锈钢接头的连接

利用AgCu-1.8Ti和AgCu-4.4Ti两种钎料对Nb与0Cr17N i4Cu4Nb不锈钢进行润湿性研究,并钎焊Nb与0Cr17N i4Cu4Nb接头。AgCu-1.8Ti在Nb与0Cr17N i4Cu4Nb上的润湿角均小于AgCu-4.4Ti。分析接头组织发现,AgCu-4.4Ti钎料接头中在靠近不锈钢侧存在约50μm宽的富Ti层,而AgCu-1.8Ti钎料接头中未发现该富Ti层。利用氩弧焊将TC4与Nb预先焊好后再用两种钎料钎焊Nb和不锈钢,测定TC4/Nb/0Cr17N i4Cu4Nb接头的室温拉伸强度。数据显示,AgCu-1.8Ti钎料接头的室温拉伸强度平均值达到222.2MPa,而AgCu-4.4Ti钎料接头强度仅有133.8MPa,所有接头均断于Nb与0Cr17N i4Cu4Nb界面。     

Interfacial characteristics in CNTs-AgCuTi systems

AgCuTi-based composite fillers reinforced with Carbon Nanotubes（CNTs） were prepared by mechanical ball milling and ultrasonic agitation. The morphological features, chemical components, and melting characteristics of the composite fillers with different content of CNTs addition were investigated using Field Emission Scanning Electron Microscopy（FESEM）, XRay Diffraction（XRD） and a Differential Scanning Calorimeter（DSC）. After being heated at 900 ℃, the microstructure of the composite fillers was ...     

Feasibility study of thermo-compensated resistance brazing welding of C/C composites and T2 copper with AgCuTi filler metal

The dissimilar materials joining of C/C composites to T2 copper were performed successfully by thermo-compensated Resistance Brazing Welding (RBW) with AgCuTi filler powder. The interfacial microstructure, phase composition, and shear strength of the resistance brazed joints were investigated by the relevant analysis method. Experiment results indicated that the order affecting the shear strength of the C/C-Cu joint was welding current, welding pressure, and welding time in turn. The shear strength of backward thermo-compensated RBW was higher than that of forward thermo-compensated RBW due to the Peltier effect. The maximum shear strength of the C/C-Cu joint was 11.56 MPa in the optimized welding parameter with welding current of 8.0 kA, welding time of 60 ms, and welding pressure of 0.10 MPa by backward thermo-compensated RBW. The interface structure at the resistance brazed joint with this welding parameter was C/C composites/TiC/Cu (s.s)/T2 copper. The TiC phase was verified at the interface of the brazed joint by Scanning Electron Microscope (SEM), Energy-Dispersive X-ray Spectrometer (EDS), and X-ray Diffraction (XRD). Considerable fractures occurred in the C/C composites and partial fracture occurred at the interfacial reaction layer.