Mesospheric ozone densities deduced from solar occultation measurements

Quartz-UV occultation measurements by the satellite Interkosmos-16 have been used to calculate ozone densities at altitudes between 50 and 90 km for the period August to October 1976. Below 65 km densities agree well with the Krueger-Minzner-model. Mesopause densities have been studied in some detail. A certain percentage of the profiles show close correlation with the model of Shimazaki and Laird (with a pronounced minimum below the mesopause) while others fit better to the Park and London model (no minimum). This variability of the ozone density may be caused by different processes in the photo-chemistry of ozone. Two possible causes, the temperature dependent rate coefficients and the odd hydrogen processes are discussed in greater detail.     

Ozone trends in the mid-latitude stratopause region based on microwave measurements at Lindau (51.66° N, 10.13° E), the ozone reference model,and model calculations

We compared 8 years of ozone measurements taken at Lindau (51.66° N, 10.13° E) at altitudes between 40 and 60 km using the microwave technique with the CIRA ozone reference model that was established 20 years ago (Keating et al., 1990). We observed a remarkable decrease in ozone density in the stratopause region (i.e., an altitude of 50 km), but the decrease in ozone density in the middle mesosphere (i.e., up to 60 km in altitude) is slight. Likewise, we observed only a moderate decrease in the atmospheric region below the stratopause. Other studies have found the strongest ozone decrease at 40 km and a more moderate decrease at 50 km, which is somewhat in contradiction to our results. This decrease in ozone density also strongly depends on the season. Similar results showed model calculations using the GCM COMMA-IAP when considering the increase in methane. In the lower mesosphere/stratopause region, the strongest impact on the concentration of odd oxygen (i.e., O₃ and O) was observed due to a catalytic cycle that destroys odd oxygen, including atomic oxygen and hydrogen radicals. The hydrogen radicals mainly result from an increase in water vapor with the growing anthropogenic release of methane. The finding suggesting that the stratopause region is apparently attacked more strongly by the water vapor increase has been interpreted in terms of the action of this catalytic cycle, which is most effective near the stratopause and amplified by a positive feedback between the ozone column density and the ozone dissociation rate, thereby chemically influencing the ozone density. However, the rising carbon dioxide concentration cools the middle atmosphere, thereby damping the ozone decline by hydrogen radicals.     

Gravity Wave Mixing and Effective Diffusivity for Minor Chemical Constituents in the Mesosphere/Lower Thermosphere

The influence of gravity waves (GWs) on the distributions of minor chemical constituents in the mesosphere-lower thermosphere (MLT) is studied on the basis of the effective diffusivity concept. The mixing ratios of chemical species used for calculations of the effective diffusivity are obtained from numerical experiments with an off-line coupled model of the dynamics and chemistry abbreviated as KMCM-MECTM (Kuehlungsborn Mechanistic general Circulation Model—MEsospheric Chemistry-Transport Model). In our control simulation the MECTM is driven with the full dynamical fields from an annual cycle simulation with the KMCM, where mid-frequency GWs down to horizontal wavelengths of 350 km are resolved and their wave-mean flow interaction is self-consistently induced by an advanced turbulence model. A?perturbation simulation with the MECTM is defined by eliminating all meso-scale variations with horizontal wavelengths shorter than 1000 km from the dynamical fields by means of spectral filtering before running the MECTM. The response of the MECTM to GWs perturbations reveals strong effects on the minor chemical constituents. We show by theoretical arguments and numerical diagnostics that GWs have direct, down-gradient mixing effects on all long-lived minor chemical species that possess a mean vertical gradient in the MLT. Introducing the term wave diffusion (WD) and showing that wave mixing yields approximately the same WD coefficient for different chemical constituents, we argue that it is a useful tool for diagnostic irreversible transport processes. We also present a detailed discussion of the gravity-wave mixing effects on the photochemistry and highlight the consequences for the general circulation of the MLT.     

The Lyman-alpha absorption anomaly in satellite occulation measurements as a tracer for some thermospheric composition variations

The absorption anomaly of Lyman-alpha radiation in satellite occultation experiments is known as the fact that extinction above 100 km is much stronger than absorption by atmospheric O₂ alone would explain. Additional absorption by NO or H₂O has been suggested but none has been clearly identified so far. The additional absorption occurs predominantly in middle and high latitudes of the winter hemisphere, but has also been found in equatorial latitudes. Recent measurements of NO would explain the Lyman-alpha absorption anomaly. The high densities of the additional Lyman-alpha absorber at lower latitudes could be explained by transport processes through global circulation systems of the higher thermosphere. Structural variations of the neutral gas derived from occultation measurements seem to indicate that thermospheric low pressure systems in mid latitudes modulate the transport of tracer constituents and heat energy from higher latitudes to the equator.     

Ozone chemical equilibrium in the extended mesopause under the nighttime conditions

For retrieval of atomic oxygen and atomic hydrogen via ozone observations in the extended mesopause region (～70–100?km) under nighttime conditions, an assumption on photochemical equilibrium of ozone is often used in research. In this work, an assumption on chemical equilibrium of ozone near mesopause region during nighttime is proofed. We examine 3D chemistry-transport model (CTM) annual calculations and determine the ratio between the correct (modeled) distributions of the O₃ density and its equilibrium values depending on the altitude, latitude, and season.The results show that the retrieval of atomic oxygen and atomic hydrogen distributions using an assumption on ozone chemical equilibrium may lead to large errors below ～81–87?km. We give simple and clear semi-empirical criterion for practical utilization of the lower boundary of the area with ozone’s chemical equilibrium near mesopause.