The ‘soot line’: Destruction of presolar polycyclic aromatic hydrocarbons in the terrestrial planet-forming region of disks

Interstellar material is highly processed when subjected to the physical conditions that prevail in the inner regions of protoplanetary disks, the potential birthplace of habitable planets. Polycyclic aromatic hydrocarbons (PAHs) are abundant in the interstellar medium, and they have also been observed in the disks around young stars, with evidence for some modification in the latter. Using a chemical model developed for sooting flames, we have investigated the chemical evolution of PAHs in warm (1000–2000 K) and oxygen-rich (C/O < 1) conditions appropriate for the region where habitable planets may eventually form. Our study focuses on (1) delineating the conditions under which PAHs will react and (2) identifying the key reaction pathways and reaction products characterizing this chemical evolution. We find that reactions with H, OH and O are the main pathways for destroying PAHs over disk timescale at temperatures greater than about 1000 K. In the process, high abundances of C₂H₂ persist over long timescales due to the kinetic inhibition of reactions that eventually drive the carbon into CO, CO₂ and CH₄. The thermal destruction of PAHs may thus be the cause of the abundant C₂H₂ that has been observed in disks. We propose that protoplanetary disks have a ‘soot line’, within which PAHs are irreversibly destroyed via thermally-driven reactions. The soot line will play an important role, analogous to that of the ‘snow line’, in the bulk carbon content of meteorites and habitable planets.     

Modeling solar proton access to geostationary spacecraft with geomagnetic cutoffs

Solar energetic particle (SEP) cutoffs at geosynchronous orbit are sensitive to moderate geomagnetic activity and undergo daily variations due to the day–night asymmetry of the magnetosphere. At geosynchronous orbit, cutoff rigidity also has a large directional dependence, with the highest cutoff rigidity corresponding to ions arriving from magnetic east and lowest cutoff rigidity corresponding to ions incident from the west. Consequently, during geomagnetically quiet periods, the SEP flux observed by an eastward facing particle detector is significantly lower than observed by a westward facing particle detector. During geomagnetically disturbed periods the cutoff is suppressed allowing SEPs access well inside of geosynchronous, so that the east–west SEP flux ratio approaches unity. Variations in the east–west SEP flux ratio observed by GOES Energetic Particle Sensors (EPS) have recently been reported by Rodriguez et al. (2010). In NOAA’s operational processing of EPS count rates into differential fluxes, the differential flux is treated as isotropic and flat over the energy width of the channel. To compare modeled SEP flux with GOES EPS observations, the anisotropy of the flux over the EPS energy range and field of view must be taken into account. A technique for making direct comparisons between GOES EPS observations and SEP flux modeled using numerically computed geomagnetic cutoffs is presented. Initial results from a comparison between modeled and observed flux during the 6–11 December 2006 SEP event are also presented. The modeled cutoffs reproduce the observed flux variations well but are in general too high.