Element Abundances and Isotope Ratios in the Giant Planets and Titan

This paper reviews our present knowledge about elemental and isotopic ratios in the Giant Planets and Titan. These parameters can provide key information about the formation and evolution of these objects. Element abundances, especially after the results of the Galileo Probe Mass Spectrometer in Jupiter, strongly support the formation model invoking an initial core formation (Mizuno, 1980; Pollack et al., 1996). They also suggest that solar composition icy planetesimals (SCIPs) brought the heavy elements to Jupiter. The Jupiter value of D/H appears to be representative of the protosolar value, while the D/H enrichment observed on Uranus and Neptune is consistent with the formation scenario of these planets. The ¹⁵N/¹⁴N measurement in Jupiter seems to be representative of its protosolar value. Future measurements are expected to come from the Cassini and Herschel space mission, as well as the ALMA submillimeter observatory. This revised version was published online in August 2006 with corrections to the Cover Date.     

Search for organic molecules in the outer solar system

Recent developments of millimeter astronomy have led to the discovery of more and more complex molecules in the interstellar medium. In a similar way, attempts have been made to detect complex molecules in the atmospheres of the most primitive bodies of the Solar System, i.e. outer planets and comets, as well as in Titan's atmosphere. An important progress has been achieved thanks to the continuous development of infrared astronomy, from the ground and from space vehicles. In particular, an important contribution has come from the IRIS-Voyager infrared spectrometer with the detection of prebiotic molecules on Titan, and some complex organic molecules on Jupiter and Saturn. Another important result has been the observation of carbonaceous material in the immediate surroundings of Comet Halley's nucleus. In the near future, the search for organic molecules in the outer Solar System should benefit from the developments of large millimeter antennae, and in the next decade, from the operation of infrared Earth-orbiting spacecrafts (ISO, SIRTF).     

The 2.5 to 5 microns spectrum of comet Halley from the IKS instrument of Vega

Results of the 2.5–5 micron spectroscopic channel of the IKS instrument on Vega are reported and the data reduction process is described. H₂O and CO₂ molecules have been detected with production rates of 10³⁰ s⁻¹ and 1.5 10²⁸ s⁻¹ respectively. Emission features between 3.3 and 3.7 microns are tentatively attributed to CH - bearing compounds - CO is marginally detected with a mixing ratio CO/H₂O 0.2. OH emission and H₂O - ice absorption might also be present in the spectra.     

Infrared Spectroscopy of Solar-System Planets

Most of our knowledge regarding planetary atmospheric composition and structure has been achieved by remote sensing spectroscopy. Planetary spectra strongly differ from one planet to another. CO₂ signatures dominate on Mars, and even more on Venus (where the thermal component is detectable down to 1 μm on the dark side). Spectroscopic monitoring of Venus, Earth and Mars allows us to map temperature fields, wind fields, clouds, aerosols, surface mineralogy (in the case of the Earth and Mars), and to study the planets’ seasonal cycles. Spectra of giant planets are dominated by H₂, CH₄ and other hydrocarbons, NH₃, PH₃ and traces of other minor compounds like CO, H₂O and CO₂. Measurements of the atmospheric composition of giant planets have been used to constrain their formation scenario.     

The Planets and Titan Observed by ISO

Infrared spectroscopic observations of planets and Saturn's satellite Titan with the Infrared Space Observatory led to many significant discoveries that improved our understanding on the formation, physics and chemistry of these objects. The prime results achieved by ISO are: (1) a new and consistent determination of the D/H ratios on the giant planets and Titan; (2) the first precise measurement of the ¹⁵N/¹⁴N ratio in Jupiter, a valuable indicator of the protosolar nitrogen isotopic ratio; (3) the first detection of an external oxygen flux for all giant planets and Titan; (4) the first detection of some stratospheric hydrocarbons (CH₃, C₂H₄, CH₃C₂H, C₄H₂, C₆H₆); (5) the first detection of tropospheric water in Saturn; (6) the tentative detection of carbonate minerals on Mars; (7) the first thermal lightcurve of Pluto. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

The instrument IKS and its calibration

The IKS infrared spectro-photometer will fly on board the VEGA platforms. It is designed to characterize the size, temperature and emissivity of the Comet Halley nucleus, to identify the major gaseous components of the inner coma and to detect the emission of the cometary grains. This paper presents the “calibration” experiments required to reduce the raw data: (i) absolute wavelength calibration of the filter wheels; (ii) modeling of the internal signal, as a function of the temperature of the different sub-systems; (iii) absolute and spectral responsivities of each of the spectrometric and photometric channels, as a function of the wavelength and position of the source in the field of view. Finally, we shall indicate the expected S/N ratios.     

The infrared synthetic spectrum of comet Halley

In order to prepare infrared sounding of comet Halley from the flyby VEGA probes, we have computed the synthetic spectrum between 2.5 and 15 μ of a typical comet at a heliocentric distance of ～ 0.8 AU. The present paper is particularly devoted to the contribution from the cometary gases. For a selection of 20 possible parent molecules, the most efficient excitation process is resonant fluorescence by the solar radiation field. The H₂O, CO, CO₂, CH₄, NH₃ and H₂CO molecules are the best candidates for detection by the IKS infrared spectrometers aboard the VEGA probes. For the water molecule, collisions are too rare to ensure thermal equilibrium in the whole coma ; therefore a limited number of fluorescence lines are expected to be present in the H₂O vibrational bands.     

Radar: The Cassini Titan Radar Mapper

The Cassini RADAR instrument is a multimode 13.8 GHz multiple-beam sensor that can operate as a synthetic-aperture radar (SAR) imager, altimeter, scatterometer, and radiometer. The principal objective of the RADAR is to map the surface of Titan. This will be done in the imaging, scatterometer, and radiometer modes. The RADAR altimeter data will provide information on relative elevations in selected areas. Surfaces of the Saturn’s icy satellites will be explored utilizing the RADAR radiometer and scatterometer modes. Saturn’s atmosphere and rings will be probed in the radiometer mode only. The instrument is a joint development by JPL/NASA and ASI. The RADAR design features significant autonomy and data compression capabilities. It is expected that the instrument will detect surfaces with backscatter coefficient as low as −40 dB.RADAR Team LeaderThis revised version was published online in July 2005 with a corrected cover date.     

Primordial matter in the outer solar system: A study of its chemical composition from remote spectroscopic analysis

Our knowledge of the primordial matter from the objects of the outer solar system has made a considerable progress over the past years, in spite of the lack of any in situ measurements of these objects at the present time. The recent progress of ground-based instrumentation and the launch of the two Voyager fly-by missions have provided a huge amount of new informations about the origin and the evolution of the primitive Solar System objects.The most significant discoveries concerning the atmospheres of the Giant Planets can be summarized as follows: (1) there does not seem to be any differentiation in the internal structure of Jupiter during the planet's history; thus, the H₂/He ratio measured on Jupiter seems to be representative of the H/He ratio of the Primordial Nebula; (2) there is some evidence for a helium differentiation, relative to hydrogen, in Saturn's interior; (3) there seems to be a carbon enrichment on both Jupiter and Saturn by a factor about 2; this result is consistent with a model in which the planetary core is formed first, and the atmosphere accreted by this core in a second stage; (4) the D/H ratio measured on Jupiter should be representative of the D/H value in the Primordial Nebula, 4.5 billion years ago; this value is 2 to 5 times larger than the mean value measured in the local interstellar medium now; (5) Titan's atmosphere is dominated by nitrogen and contains traces of organic and prebiotic molecules (HCN, C₂N₂, HC₃N); the chemical composition of Titan's atmosphere could be favorable for the early stages of life development.The small bodies of the Solar System — asteroïds and comets — are still very poorly known. However they contain a key information about the physical and chemical properties of dust in the Primordial Nebula and the interstellar medium. With the launch of expected fly-by missions towards Comet Halley and, possibly, towards asteroïds, we may hope to know a new development of our understanding of these objects, comparable to the progress we have known on the Giant Planets over the past ten years.