Thermally evolved gas analysis (TEGA) of hyperarid soils doped with microorganisms from the Atacama Desert in southern Peru: Implications for the Phoenix mission

TEGA, one of several instruments on board of the Phoenix Lander, performed differential scanning calorimetry and evolved gas analysis of soil samples and ice, collected from the surface and subsurface at a northern landing site on Mars. TEGA is a combination of a high temperature furnace and a mass spectrometer (MS) that was used to analyze samples delivered to the instrument via a robotic arm. The samples were heated at a programmed ramp rate up to 1000 °C. The power required for heating can be carefully and continuously monitored (scanning calorimetry). The evolved gases generated during the process can be analyzed with the evolved gas analyzer (a magnetic sector mass spectrometer) in order to determine the composition of gases released as a function of temperature. Our laboratory has developed a sample characterization method using a pyrolyzer integrated to a quadrupole mass spectrometer to support the interpretations of TEGA data. Here we examine the evolved gas properties of six types of hyperarid soils from the Pampas de La Joya in southern Peru (a possible analog to Mars), to which we have added with microorganisms (Salmonella typhimurium, Micrococcus luteus, and Candida albicans) in order to investigate the effect of the soil matrix on the TEGA response. Between 20 and 40 mg of soil, with or without ∼5 mg of lyophilized microorganism biomass (dry weight), were placed in the pyrolyzer and heated from room temperature to 1200 °C in 1 h at a heating rate of 20 °C/min. The volatiles released were transferred to a MS using helium as a carrier gas. The quadrupole MS was ran in scan mode from 10 to 200 m/z. In addition, ∼20 mg of each microorganism without a soil matrix were analyzed. As expected, there were significant differences in the gases released from microorganism samples with or without a soil matrix, under similar heating conditions. Furthermore, samples from the most arid environments had significant differences compared with less arid soils. Organic carbon released in the form of CO₂ (ion 44 m/z) from microorganisms evolved at temperatures of ∼326.0 ± 19.5 °C, showing characteristic patterns for each one. Others ions such as 41, 78 and 91 m/z were also found. Interestingly, during the thermal process, the release of CO₂ increased and ions previously found disappeared, demonstrating a high-oxidant activity in the soil matrix when it was subjected to high temperature. Finally, samples of soil show CO₂ evolved up to 650 °C consistent with thermal decomposition of carbonates. These results indicate that organics mixed with these hyperarid soils are oxidized to CO₂. Our results suggest the existence of at least two types of oxidants in these soils, a thermolabile oxidant which is highly oxidative and other thermostable oxidant which has a minor oxidative activity and that survives the heat-treatment. Furthermore, we find that the interaction of biomass added to soil samples gives a different set of breakdown gases than organics resident in the soil. The nature of oxidant(s) present in the soils from Pampas de La Joya is still unknown.     

Soil carbon distribution and site characteristics in hyper-arid soils of the Atacama Desert: A site with Mars-like soils

The soil carbon content and its relation to site characteristics are important in evaluating current local, regional, and global soil C storage and projecting future variations in response to climate change. In this study we analyzed the concentration of organic and inorganic carbon and their relationship with in situ climatic and geological characteristics in 485 samples of surface soil and 17 pits from the hyper-arid area and 51 samples with 2 pits from the arid–semiarid region from the Atacama Desert located in Peru and Chile. The soil organic carbon (SOC) in hyperarid soils ranged from 1.8 to 50.9 μg C per g of soil for the 0–0.1 m profile and from 1.8 to 125.2 μg C per g of soil for the 0–1 m profile. The analysis of climatic (temperature and precipitation), elevation, and some geologic characteristics (landforms) associated with hyper-arid soils explained partially the SOC variability. On the other hand, soil inorganic carbon (SIC) contents, in the form of carbonates, ranged from 200 to 1500 μg C per g of soil for the 0–0.1 m profile and from 200 to 3000 μg C per g of soil for the 0–1.0 m profile in the driest area. The largest accumulations of organic and inorganic carbon were found near to arid–semiarid areas. In addition, the elemental carbon concentrations show that the presence of other forms of inorganic carbon (e.g. graphite, etc.) was negligible in these hyperarid soils. Overall, the top 1 m soil layer of hyperarid lands contains ∼11.6 Tg of organic carbon and 344.6 Tg of carbonate carbon. The total stored carbon was 30.8-fold the organic carbon alone. To our knowledge, this is the first study evaluating the total budget carbon on the surface and shallow subsurface on ∼160,000 km² of hyperarid soils.     

Flaring loop parameters estimated from solar decimeter type U-like and type J-like fine structures

This work presents the analysis of five fine structures in the solar radio emission, observed between June 2000 and October 2001 by the Brazilian Solar Spectroscope (BSS), in the decimeter frequency band of 950–2500 MHz. Based on their morphological characteristics identified in the dynamic spectra, the fine structures had been classified as type U-like or type J-like bursts. Such emissions are variants of the type III bursts. They support the hypothesis of generation by plasma emission mechanism, from interaction of electron beams accelerated during solar flares, propagating along closed magnetic structures, within the trapped plasma of the solar corona. The spectral and temporal characteristics of the five fine structures had been obtained from the dynamic spectra and the parameters of the agent and the emitting source have been determined, assuming both fundamental and harmonic emissions. The analysis revealed the flux density of the structures is less than 20–80 s.f.u. For assumption of harmonic emission, the interval of values for the source parameters estimated are: the loop size is (0.3–5.1) × 10¹⁰ cm; the electron beam velocity is in the range of 0.16–0.53 c; the temperature of coronal loop top is of the order of (0.25–1.55) × 10⁷ K; and the low limit for the magnetic field is of 7–26 G. These results are in agreement with previous determinations reported in the literature.     

X-38 integrated aero- and aerothermodynamic activities

The characterisation of the aeroshape selected for the X-38 [Crew Return Vehicle (CRV) demonstrator] is presently being performed as a co-operative endeavour between NASA, DLR (through its TETRA Program), and the European Space Agency (ESA) with Dassault Aviation integrating the aerodynamic and aerothermodynamic activities. The methodologies selected for characterizing the aerodynamic and aerothermodynamic environment of the X-38 are presented.     

Effects of Low Energetic Neutral Atoms on Martian and Venusian Dayside Exospheric Temperature Estimations

The heating of the upper atmospheres and the formation of the ionospheres on Venus and Mars are mainly controlled by the solar X-ray and extreme ultraviolet (EUV) radiation (λ = 0.1–102.7 nm and can be characterized by the 10.7 cm solar radio flux). Previous estimations of the average Martian dayside exospheric temperature inferred from topside plasma scale heights, UV airglow and Lyman-α dayglow observations of up to ∼500 K imply a stronger dependence on solar activity than that found on Venus by the Pioneer Venus Orbiter (PVO) and Magellan spacecraft. However, this dependence appears to be inconsistent with exospheric temperatures (<250 K) inferred from aerobraking maneuvers of recent spacecraft like Mars Pathfinder, Mars Global Surveyor and Mars Odyssey during different solar activity periods and at different orbital locations of the planet. In a similar way, early Lyman-α dayglow and UV airglow observations by Venera 4, Mariner 5 and 10, and Venera 9–12 at Venus also suggested much higher exospheric temperatures of up to 1000 K as compared with the average dayside exospheric temperature of about 270 K inferred from neutral gas mass spectrometry data obtained by PVO. In order to compare Venus and Mars, we estimated the dayside exobase temperature of Venus by using electron density profiles obtained from the PVO radio science experiment during the solar cycle and found the Venusian temperature to vary between 250–300 K, being in reasonable agreement with the exospheric temperatures inferred from Magellan aerobraking data and PVO mass spectrometer measurements. The same method has been applied to Mars by studying the solar cycle variation of the ionospheric peak plasma density observed by Mars Global Surveyor during both solar minimum and maximum conditions, yielding a temperature range between 190–220 K. This result clearly indicates that the average Martian dayside temperature at the exobase does not exceed a value of about 240 K during high solar activity conditions and that the response of the upper atmosphere temperature on Mars to solar activity near the ionization maximum is essentially the same as on Venus. The reason for this discrepancy between exospheric temperature determinations from topside plasma scale heights and electron distributions near the ionospheric maximum seems to lie in the fact that thermal and photochemical equilibrium applies only at altitudes below 170 km, whereas topside scale heights are derived for much higher altitudes where they are modified by transport processes and where local thermodynamic equilibrium (LTE) conditions are violated. Moreover, from simulating the energy density distribution of photochemically produced moderately energetic H, C and O atoms, as well as CO molecules, we argue that exospheric temperatures inferred from Lyman-α dayglow and UV airglow observations result in too high values, because these particles, as well as energetic neutral atoms, transformed from solar wind protons into hydrogen atoms via charge exchange, may contribute to the observed planetary hot neutral gas coronae. Because the low exospheric temperatures inferred from neutral gas mass spectrometer and aerobraking data, as well as from CO⁺ ₂ UV doublet emissions near 180–260 nm obtained from the Mars Express SPICAM UV spectrograph suggest rather low heating efficiencies, some hitherto unidentified additional IR-cooling mechanism in the thermospheres of both Venus and Mars is likely to exist. An erratum to this article can be found at     

Decomposition of sodium formate and L- and D-alanine in the Pampas de La Joya soils: Implications as a new geochemical analogue to Martian regolith

The organic compounds on the Martian surface are still undetectable by the previous Viking mission that has been sent to Mars even though they are expected to be there by exogenous and/or endogenous synthesis. The high abiotic reactivity has been the most acceptable explanation for the apparently absence of organic matter in the regolith.     

The future regulation of suborbital flight in Europe

The EU 7th Framework Project FAST20XX [1] aimed to enlarge the foundations of suborbital high-speed transportation in a wide variety of fields. One of the key issues of this project was to outline a desirable regulatory framework that would best serve the interests of all European stakeholders in this new activity.