Quantitative Assessments of the Martian Hydrosphere

In this paper, we review current estimates of the global water inventory of Mars, potential loss mechanisms, the thermophysical characteristics of the different reservoirs that water may be currently stored in, and assess how the planet’s hydrosphere and cryosphere evolved with time. First, we summarize the water inventory quantified from geological analyses of surface features related to both liquid water erosion, and ice-related landscapes. They indicate that, throughout most of Martian geologic history (and possibly continuing through to the present day), water was present to substantial depths, with a total inventory ranging from several 100 to as much as 1000 m Global Equivalent Layer (GEL). We then review the most recent estimates of water content based on subsurface detection by orbital and landed instruments, including deep penetrating radars such as SHARAD and MARSIS. We show that the total amount of water measured so far is about 30 m GEL, although a far larger amount of water may be stored below the sounding depths of currently operational instruments. Finally, a global picture of the current state of the subsurface water reservoirs and their evolution is discussed.     

Volatile Trapping in Martian Clathrates

Thermodynamic conditions suggest that clathrates might exist on Mars. Despite observations which show that the dominant condensed phases on the surface of Mars are solid carbon dioxide and water ice, clathrates have been repeatedly proposed to play an important role in the distribution and total inventory of the planet’s volatiles. Here we review the potential consequences of the presence of clathrates on Mars. We investigate how clathrates could be a potential source for the claimed existence of atmospheric methane. In this context, plausible clathrate formation processes, either in the close subsurface or at the base of the cryosphere, are reviewed. Mechanisms that would allow for methane release into the atmosphere from an existing clathrate layer are addressed as well. We also discuss the proposed relationship between clathrate formation/dissociation cycles and how potential seasonal variations influence the atmospheric abundances of argon, krypton and xenon. Moreover, we examine several Martian geomorphologic features that could have been generated by the dissociation of extended subsurface clathrate layers. Finally we investigate the future in situ measurements, as well as the theoretical and experimental improvements that will be needed to better understand the influence of clathrates on the evolution of Mars and its atmosphere.     

Ceramic ChemCam Calibration Targets on Mars Science Laboratory

The ChemCam instrument on the Mars Science Laboratory rover Curiosity will use laser-induced breakdown spectroscopy (LIBS) to analyze major and minor element chemistry from sub-millimeter spot sizes, at ranges of ～1.5–7?m. To interpret the emission spectra obtained, ten calibration standards will be carried on the rover deck. Graphite, Ti?metal, and four glasses of igneous composition provide primary, homogeneous calibration targets for the laser. Four granular ceramic targets have been added to provide compositions closer to soils and sedimentary materials like those expected at the Gale Crater field site on Mars. Components used in making these ceramics include basalt, evaporite, and phyllosilicate materials that approximate the chemical compositions of detrital and authigenic constituents of clastic and evaporite sediments, including the elevated sulfate contents present in many Mars sediments and soils. Powdered components were sintered at low temperature (800?°C) with a small amount (9?wt.%) of lithium tetraborate flux to produce ceramics that retain volatile sulfur yet are durable enough for the mission. The ceramic targets are more heterogeneous than the pure element and homogenous glass standards but they provide standards with compositions more similar to the sedimentary rocks that will be Curiosity’s prime targets at Gale Crater.     

Cometary Dust

This review presents our understanding of cometary dust at the end of 2017. For decades, insight about the dust ejected by nuclei of comets had stemmed from remote observations from Earth or Earth’s orbit, and from flybys, including the samples of dust returned to Earth for laboratory studies by the Stardust return capsule. The long-duration Rosetta mission has recently provided a huge and unique amount of data, obtained using numerous instruments, including innovative dust instruments, over a wide range of distances from the Sun and from the nucleus. The diverse approaches available to study dust in comets, together with the related theoretical and experimental studies, provide evidence of the composition and physical properties of dust particles, e.g., the presence of a large fraction of carbon in macromolecules, and of aggregates on a wide range of scales. The results have opened vivid discussions on the variety of dust-release processes and on the diversity of dust properties in comets, as well as on the formation of cometary dust, and on its presence in the near-Earth interplanetary medium. These discussions stress the significance of future explorations as a way to decipher the formation and evolution of our Solar System.