PBT弹性体微相分离及对其力学性能的影响研究

为了获得微相分离对宽温PBT叠氮聚醚弹性体力学性能的影响规律,用红外光谱分析法(FT-IR)和动态热力学分析法(DMA)研究了PBT叠氮聚醚弹性体产生微相分离的机理和影响因素。用调节硬段含量、交联参数的方法调控其微相分离,控制适当的微相分离程度可显著改善推进剂的力学性能。研究结果表明:在二元醇扩链的弹性体体系中,当硬段含量约为15%时,弹性体发生相对最大比例的微相分离,体现出较佳的综合力学性能。通过微相分离的调控可获得宽温范围内综合力学性能较好的叠氮聚醚推进剂用粘合剂基体材料。     

Assessment of between-floor structural and topological properties on cognitive map development in multilevel built environments

The present study investigated cognitive map development in multilevel built environments. Three experiments were conducted in complex virtual buildings to examine the effects of five between-floor structural factors that may impede the accuracy of humans’ ability to build multilevel cognitive maps. Results from Experiments 1 and 2 (of three experiments) revealed that difficulties in developing multilevel cognitive maps are not solely caused by the z-axis offset, as is suggested in the literature, but are due to the factorial combination of a between-floor overlap and a z-axis offset. Results from Experiment 2 showed that this process becomes substantially more difficult when the reference directions between different floors have an angular offset from each other. Finally, results from Experiment 3 demonstrated that confusing between-floor heading shifts in aligned buildings did not make it reliably harder to build multilevel cognitive maps. The implications of these findings are discussed in terms of theories of mental representations in multilayered three-dimensional spaces, as well as for architectural design.     

叠层穿刺CF/Al复合材料准静态拉伸力学行为与失效机制

针对新型的叠层穿刺碳纤维织物增强铝基复合材料（CF/Al复合材料），通过细观力学数值模拟与实验结合的方法研究了其在准静态拉伸载荷作用下的渐进损伤与断裂力学行为。复合材料经向拉伸弹性模量、极限强度与断裂应变的实验结果分别为129.61 GPa、630.14 MPa和0.75%，细观力学模型预测误差分别为-9.41%、7.57%和1.33%，均匀化计算的宏观应力-应变曲线与实验曲线总体上相符。经向拉伸变形初期首先出现经/纬纱交织处基体合金的局部损伤，随着拉伸应变量的增大依次发生纬纱和穿刺纱的横向开裂，拉伸变形后期基体合金与经纱失效引起宏观应力-应变曲线的急剧下降，复合材料拉伸断口表现为经纱轴向断裂及纬纱和穿刺纱横向开裂共存的形貌特征，纤维拔出和基体断裂导致的经纱轴向断裂是诱发复合材料最终失效的主要机制。     

Ti6242合金微观组织差异及其演变对拉伸和疲劳性能影响

典型近α型钛合金Ti6242合金制备盘锻件的综合力学性能与其棒材原始微观组织特征密切相关。本研究选取具有明显微观组织特征差别的3种Ti6242钛合金棒材为研究对象,定量化评估不同Ti6242钛合金棒材锻造态、固溶态和固溶+时效态的微观组织差别和演变规律,并讨论棒材微观组织差别和演变对综合力学性能的影响。研究结果显示具有明显差别的不同棒材微观组织在经历相同的固溶和时效处理后,其初生α相体积分数差别趋于相近,而初生α相的尺寸分布和形状分布等微观组织特征仍保留差别;力学性能结果显示室温拉伸力学性能趋于近似,而低周疲劳和保载疲劳力学性能对微观组织特征较为敏感。对比不同特征组织和力学性能分析结果,具有细小非等轴状且没有明显取向集中分布初生α相的棒材原始组织有助于获得更好的疲劳性能。     

阳极氧化对TiAl合金高温氧化行为和力学性能的影响

采用电化学阳极氧化技术在含NH4F的乙二醇电解液中对TiAl合金进行阳极氧化处理。研究阳极氧化对TiAl合金高温氧化行为和力学性能的影响。结果表明:由于“卤素效应”,阳极氧化处理的TiAl合金经高温氧化后表面形成致密、连续的Al₂O₃氧化膜,有效阻止了氧的内扩散,进而显著提高合金的抗高温氧化性能。经1000℃氧化100 h后,阳极氧化试样增重由未经阳极氧化处理试样的85.86 mg/cm²降至0.67 mg/cm²。另一方面,阳极氧化TiAl合金表面硬度和弹性模量随高温氧化时间延长呈先降低后升高的趋势。阳极氧化TiAl合金在高温服役后,合金的摩擦系数较未经阳极氧化处理试样上升,但表面耐磨性先降低后升高。这是由于TiAl合金经阳极氧化后,表面形成了一层富铝含氟氧化膜,由于氧化膜中F元素在高温氧化过程中与Ti、Al结合形成卤化物,卤化物蒸气选择性扩散在原始氧化膜处形成致密的Al₂O₃保护膜。阳极氧化对TiAl合金力学性能的影响主要是由于氧化膜中Al₂O₃的含量变化所致。     

超细CL‑20的可控批量制备及降感技术

为了批量制备低感度超细六硝基六氮杂异伍兹烷(CL-20),用作固体推进剂的高能添加剂,以氧化锆球(0.8 mm或0.3 mm)为研磨介质,采用HLG-05型粉碎设备制备了两种超细类球形CL-20。用激光粒度仪、扫描电子显微镜(SEM)、X射线衍射(XRD)、傅里叶红外光谱(FTIR)和拉曼光谱(Raman)对CL-20样品进行了相应的表征;用差示扫描量热(DSC)研究了样品的热分解性能;测试了样品的撞击、摩擦和静电火花感度。结果表明:制备的微米级和亚微米级CL-20平均粒径分别为3.43μm和320 nm,表面光滑,类球形;其晶型不变,无质杂峰;超细CL-20的分解峰温稍有下降,活化能降低,其静电火花感度略有提高,但撞击感度分别降低了24.6%和108.4%,摩擦感度下降了8%和20%;机械感度降低效果明显,在高能固体推进剂中有较大的应用前景。     

吸气式电推进系统可行条件分析

吸气式电推进系统作为有可能实现长寿命超低轨飞行的技术而被关注。根据不同轨道环境条件，采用管状结构进气道、以及机械增压的吸气方式，讨论了吸气式电推进系统所需的可行条件。分析表明，在轨高度180~240km，航天器所需总功耗与迎风面之比需要大于2kW/m2，电推力器比冲需大于4×104m/s，方可满足推阻平衡需求。分析得出，实现吸气式系统在地球轨道的运用，关键技术在于增加气体收集效率并且降低收集功耗，同时电推力器的效率还需进一步提升。     

Numerical investigation on flow and heat transfer characteristics of supercritical RP-3 in inclined pipe

Numerical simulations of flow and heat transfer to supercritical RP-3 through the inclined tubes have been performed using LS k–e model embedded in Fluent. The physical properties of RP-3 were obtained using the generalized corresponding state laws based on the fourcomponent surrogate model. Mass flow rate is 0.3 g/s, system pressure is 3 MPa, inlet temperature is 373 K. Inclination of the inclined pipe varied from -90° to 90°, with heat flux varied from 300 k W/m~2 to 400 kW/m~2. Comparison between the calculated result and the experimental data indicates the range of error reasonable. The results of ±45° show that temperature inhomogeneity in inclined pipe produce the secondary flow in its cross section due to the buoyancy force. Depending on the strength of the temperature inhomogeneity, there will be two different forms of secondary flow and both contribute to the convective heat transfer in the pipe. The secondary flow intensity decreases when the inhomogeneity alleviates and thermal acceleration will play a leading role. It will have a greater impact on the turbulent flow to affect the convective heat transfer in the pipe. When changing the inclination, it affects the magnitude of the buoyant component in flow direction. The angle increases, the buoyancy component decreases. And the peak temperature of wall dominated by the secondary flow will move forward and increase in height.     

热/力耦合作用下基于应力分析的冰破坏准则

根据飞机热除冰的物理过程,考虑外部空气动力和蒙皮表面加热的作用,建立了NACA 0012翼型前缘冰层应力计算模型。采用有限元方法和平面三角形单元对控制方程组进行了求解,获得了外部空气动力和蒙皮表面加热对冰层黏附界面应力的影响规律。研究表明:蒙皮表面不加热时,来流速度影响了黏附界面应力的强度,来流攻角影响了黏附界面应力的分布,冰-蒙皮间黏附界面切应力最大值随来流速度呈近似线性增大趋势,但外部空气动力很难造成冰层破坏。蒙皮表面加热时,冰-蒙皮间黏附界面的耦合应力和冰层内部的主应力随着热流密度的增大而增大,很容易超过剪切强度,这是造成冰破坏的关键因素。耦合冰-蒙皮剪切强度随界面温度的变化关系,初步建立了基于应力分析和热/力耦合作用的冰破坏判断准则。外部空气动力产生的界面应力和蒙皮表面加热产生的界面热应力之和，必须大于与蒙皮表面温度相关的剪切强度，则冰层发生破坏，破坏位置是耦合应力超过剪切强度的区域。      

A review of friction stir joining of SiCp/Al composites

SiCp/Al composites have excellent comprehensive properties and have been widely used in aerospace, automotive industry and other fields. Due to the huge difference in performance between SiC particles and matrix alloys, traditional fusion welding methods are difficult to meet the join requirements of SiCp/Al composites. Friction stir joining (friction stir welding), as a solid phase joining process, has been proved to be a new technology with fine prospect in joining SiCp/Al composites compared with fusion welding process. Although some progress has been made in recent years, there are still full of challenges. In this paper, the research status of friction stir joining of SiCp/Al composites in recent years is expatiated, including the weldability of SiCp/Al composites, the macrostructure and the microstructure of joints, mechanical properties of joints, and tool wear and monitoring. Furthermore, the existing challenges of friction stir joining of SiCp/Al composites are summarized and the future development directions are prospected.