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考察了天然水体中常见的SiO_3~(2-)对KMnO_4/FeSO_4工艺混凝除磷的影响。SiO_3~(2-)存在时KMnO_4/FeSO_4工艺混凝除磷的效能随着溶液pH的升高呈现先增加后降低的趋势。SiO_3~(2-)浓度为1.0 mmol/L,溶液pH值为4~6时,SiO_3~(2-)可促进KMnO_4/FeSO_4工艺除磷的效能,KMnO_4/FeSO_4工艺对磷的去除效果分别增加了6.0%,9.9%和6.3%;溶液pH值为7~9时,SiO_3~(2-)可显著抑制KMnO_4/FeSO_4工艺除磷的效能,KMnO_4/FeSO_4工艺对磷的去除效果分别降低了14.76%,32.6%和17.3%。KMnO_4/FeSO_4工艺形成的絮体颗粒物表面ζ电位显著降低,溶液中残余铁的量明显提高。另外,水中SiO_3~(2-)对KMnO_4/FeSO_4工艺形成的絮体颗粒物的组成和表面特征均有一定影响。该研究为KMnO_4/FeSO_4工艺混凝除磷技术的推广提供了必要的理论基础。 相似文献
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To better understand the formation of H2O2 in the ozonation of nitrobenzene and its role for the oxidation,a batch reactor of nitrobenzene ozonation was set up.The variables such as pH value,ozone dosage,and the presence of hydroxyl radical scavenger were investigated.The results showed that high accumulations of H2O2 were generally formed at low pH values and low ozone dosages.Moreover,H2O2 mainly formed after nitrobenzene was oxidized by hydroxyl radical during ozonation of the intermediates,such as p-nitrophenol,which reacted with ozone quickly in water.A small amount of additional H2O2 enhanced the nitrobenzene removal slightly.The kinetic study showed that nitrobenzene degradation fitted with pseudo-second-order kinetics well in the experiment.The kinetic constant values correlated linearly with the concentrations of H2O2 added.Thus,it is expected that the H2O2 formed in oxidation of nitrobenzene may initiate ozone decomposition to form hydroxyl radical and finally enhance the degradation of aromatic compounds to a certain extent. 相似文献
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采用数值手段研究了来流马赫数对飞机座舱附近区域气动加热的影响,计算的来流马赫数为0.8~2.0,基于翼展的雷诺数为107。通过分析飞机蒙皮表面的温度分布、表面摩擦因数、壁面法向速度梯度和热流量等物理量,给出了飞机头部座舱附近区域的气动热分布情况。计算结果表明,随着来流马赫数的增加,壁面法向速度梯度增大,飞机对称面上的平均温度、表面摩擦因数和热流量随之增大。此外,针对某型号飞机的计算结果表明,座舱附近区域上表面中心线上的平均温度与来流马赫数、自由来流温度之间呈一定的函数关系。 相似文献
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采用格子Boltzmann方法对雷诺数(基于射流出口宽度和出口最大速度)为42和65的二维不可压缩平面射流进行了数值模拟。研究结果表明,在射流的自相似区,射流中心轴线速度按-1/3指数规律衰减并且射流按2/3指数率扩展,与理论分析及实验结果吻合。在射流的远场区域,中心轴线上瞬态速度的时间历程与频谱分析展示出速度的周期变化特性,并且周期性分量引起的相互作用不应被忽略;相比较而言,速度的周期性分量在近场区不明显。 相似文献
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Oscillation phenomena in far field region of plane jets are studied by lattice Boltzmann method over a range of Reynolds numbers (Re) from 16 to 65. Numerical results show that the instantaneous centerline velocities show periodic oscillation behavior in far field region when Re〉38. In contrast, the periodic behavior is invisible in corresponding flow field when Re≤38. For the cases of Re≤38, the exchange of momentum due to straining mo- tion gradually dominates the downstream flow filed, which qualitatively suggests the possibility of iet instability. 相似文献
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对近20年来的飞机座舱空气调节方法进行了综述.首先,对飞机座舱微环境下的空气质量、污染物扩散、热舒适性等进行了分析评估.然后,阐述了飞机座舱空气环境研究的实验和数值方法.最后,进一步分析了相关研究方法的优缺点,并对不同研究方法的前瞻性研究对象和新一代环控系统进行了展望. 相似文献
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