叠层穿刺CF/Al复合材料准静态拉伸力学行为与失效机制

针对新型的叠层穿刺碳纤维织物增强铝基复合材料（CF/Al复合材料），通过细观力学数值模拟与实验结合的方法研究了其在准静态拉伸载荷作用下的渐进损伤与断裂力学行为。复合材料经向拉伸弹性模量、极限强度与断裂应变的实验结果分别为129.61 GPa、630.14 MPa和0.75%，细观力学模型预测误差分别为-9.41%、7.57%和1.33%，均匀化计算的宏观应力-应变曲线与实验曲线总体上相符。经向拉伸变形初期首先出现经/纬纱交织处基体合金的局部损伤，随着拉伸应变量的增大依次发生纬纱和穿刺纱的横向开裂，拉伸变形后期基体合金与经纱失效引起宏观应力-应变曲线的急剧下降，复合材料拉伸断口表现为经纱轴向断裂及纬纱和穿刺纱横向开裂共存的形貌特征，纤维拔出和基体断裂导致的经纱轴向断裂是诱发复合材料最终失效的主要机制。     

The adjusted optical properties for Galileo/BeiDou-2/QZS-1 satellites and initial results on BeiDou-3e and QZS-2 satellites

Solar Radiation Pressure (SRP) is the dominant non-gravitational perturbation for GNSS (Global Navigation Satellite System) satellites. In the absence of precise surface models, the Empirical CODE Orbit Models (ECOM, ECOM2) are widely used in GNSS satellite orbit determination. Based on previous studies, the use of an a priori box-wing model enhances the ECOM model, especially if the spacecraft is a stretched body satellite. However, so far not all the GNSS system providers have published their metadata. To ensure a precise use of the a priori box-wing model, we estimate the optical parameters of all the Galileo, BeiDou-2, and QZS-1 (Quasi Zenith Satellite System) satellites based on the physical processes from SRP to acceleration. Validation using orbit prediction proves that the adjusted parameters of Galileo and QZS-1 satellites exhibit almost the same performance as the corresponding published and “best guess” values. Whereas, the estimated parameters of BeiDou-2 satellites demonstrate an improvement of more than 60% over the initial “guess” values. The resulting optical parameters of all the satellites are introduced into an a priori box-wing model, which is jointly used with ECOM and ECOM2 model in the orbit determination. Results show that the pure ECOM2 model exhibits better performance than the pure ECOM model for Galileo, BeiDou-2 GEO and QZS-1 orbits. Combined with the a priori box-wing model the ECOM model (ECOM+BW) results in the best Galileo, BeiDou-2 GEO and QZS-1 orbits. The standard deviation (STD) of satellite laser ranging residuals reduce by about 20% and 5% with respect to the pure ECOM2 model for Galileo and BeiDou-2 GEO orbits, while the reductions are about 40% and 60% for QZS-1 orbits in yaw-steering and orbit-normal mode respectively. BeiDou-2 IGSO and MEO satellite orbits do not benefit much from the a priori box-wing model. In summary, we suggest setting up a unified SRP model of ECOM+BW for Galileo, QZS-1, and BeiDou-2 orbits based on the adjusted metadata. In addition, we estimate the optical parameters of BeiDou-3e and QZS-2 satellites using a limited number of tracking stations. Results regarding the unified SRP model indicate the same advantages, the STD of satellite laser ranging residuals reduces by about 30% and 20% for QZS-2 and BeiDou-3e orbits respectively over orbit products without a priori model. The estimation procedure is effective and easy to apply to the new emerging satellites in the future.     

Microstructure,porosity and mechanical properties of selective laser melted AlSi10Mg

Finite element modeling (FEM), microscopy, X-ray computed tomography (CT) and mechanical property tests were used to study the microstructure, porosity and mechanical properties of an AlSi10Mg alloy produced by selective laser melting (SLM). The simulation of the melt pool and thermal history under different energy densities produced an optimized result with an energy density of 44.5 J·mm⁻³. The high cooling rate during the SLM process significantly refined the previous α-Al dendrites. The growth direction of the network-like Al-Si eutectic structure at different orientations confirmed the anisotropic nature of the microstructure. Furthermore, the microhardness, tensile testing and fracture analysis results proved that there were no obvious distinctions in the strength between the transverse and longitudinal directions, and that the ductility was anisotropic, possibly due to the shape and distribution of the pores. The pores measured by X-ray CT at different energy densities confirmed that the sphericity of the pores was inversely related to pores volumes. With optimized processing conditions, the porosity of the selective laser melted sample decreased leading to the improved fabricated fuel system component via SLM.     

热发射过程中发射箱蒙皮力学性能损伤与试验研究

文中选择大、中、小3种典型结构尺寸的发射箱，利用计算流体动力学（Computational fluid dynamics，CFD）仿真软件Fluent对发射箱蒙皮表面在导弹发射过程中的力、热环境进行了仿真分析。以铝合金材料为例，对发射箱蒙皮材料在燃气流环境中力学性能损伤情况进行了烧蚀试验研究。研究结果表明，随着烧蚀时间延长，铝合金材料力学性能损伤存在一个突变点，在1.5 s内下降不明显，但是当烧蚀时间延长至2.0 s时，力学性能急剧下降至0。该研究结果为铝合金发射箱轻量化设计、热防护设计和使用次数设计等提供了数据支撑。     

连续玄武岩纤维及其复合材料耐腐蚀特性

通过考察玄武岩纤维在蒸馏水、氢氧化钠溶液及盐酸中煮沸3h后的强度与质量变化,及其复合材料在8种化学介质中分别浸泡15d、30d和90d后的力学性能与表面形态变化,对一种国产连续玄武岩纤维及其复合材料的耐化学介质腐蚀性能进行了实验研究.结果表明,该玄武岩纤维及其复合材料都有很好的耐水及耐碱性能,且纤维的耐碱性能优于其耐酸性能.由于玄武岩纤维的耐酸碱性能差异,使复合材料具有如下腐蚀特性:酸性介质中,复合材料弯曲强度和弯曲模量同步降低;碱性介质中,复合材料弯曲强度降低,而弯曲模量几乎保持不变.     

不同酚醛树脂对芳纶纸蜂窝性能的影响

为研究酚醛树脂对芳纶纸蜂窝性能的影响,本文采用两种不同的酚醛树脂制备芳纶纸蜂窝芯材,对所制备蜂窝芯材的压缩性能和剪切性能进行测试,同时结合蜂窝端面树脂分布观察、树脂与芳纶纸接触角测量等方法,分析了两种树脂所制备蜂窝芯材性能出现差异的原因,结果表明：树脂中溶剂水的挥发速度、树脂与芳纶纸之间的表面张力会影响树脂在蜂窝壁上的树脂分布;蜂窝芯材树脂含量相同时,其节点两侧的树脂胶柱有利于提高蜂窝芯材压缩强度,但树脂堆积在节点后会降低蜂窝壁厚,造成蜂窝的剪切强度和模量下降。     

改性双马来酰亚胺树脂预浸料性能研究

采用二烯丙基双酚A(Ortho-dially Bisphenol A,以下简称O-DABPA)对T型双马来酰亚胺(Bismaleimide,以下简称BMI)树脂进行改性,并用红外光谱(Fourier TransformInfrared,以下简称FT-IR)、差式扫描量热仪(Differential ScanningCalorimetry,以下简称DSC)对改性前后的树脂结构及固化反应进行测定,利用热熔预浸法对改性BMI树脂制备预浸料,考查了预浸料的力学性能及高温下的弯曲性能。结果表明,在175℃下二烯丙基双酚A和T型双马来酰亚胺树脂质量比为1∶1,反应时间为1 h时,改性BMI树脂制备的预浸料工艺性良好,单向板层间剪切强度为84.86 Mpa,在240℃时,弯曲强度及模量分别为1 326.41 MPa和120.31 GPa,强度保留率为76.73%。     

熔融渗硅工艺制备的SiCf/SiC复合材料微观结构与性能

SiC纤维增强SiC陶瓷基复合材料（SiC_f/SiC复合材料）在航空发动机热端部件方面具有重要应用。本文以第二代碳化硅纤维为增强材料,采用熔融渗硅工艺制备出SiC_f/SiC复合材料,测试复合材料的基本物理性能及常规力学性能,并利用Micro-CT、SEM对试样的微观结构和断面进行了表征分析。结果显示：SiC_f/SiC复合材料的体积密度为2.78 g/cm³,开气孔率小于2.0%,基体较为致密,1 200 ℃时热导率（厚度方向）为14.30 W/（m?K）,室温~1 200 ℃厚度方向和面内方向的线胀率分别为0.59%、0.56%,平均热胀系数分别为5.02×10^-6、4.73×10^-6/K;室温面内拉伸强度典型值为317 MPa,SEM显示试样断面具有明显的纤维拔出效应,弯曲强度和层间拉伸强度典型值分别达794和49 MPa。     

二烯丙基双酚 A 共聚双马来酰亚胺改性氰酸酯树脂的性能

采用二烯丙基双酚A和二苯甲烷型双马来酰亚胺与双酚A型氰酸酯共聚,以改善氰酸酯树脂的工艺和耐热性能;利用DSC,TGA,DMA表征了树脂的固化行为和耐热性能;此外,还研究了树脂的力学性能及高频下的介电性能。结果表明,改性后的氰酸酯树脂固化反应温度降低了约60℃,改性树脂固化物在氮气气氛下Td5约400℃,Tg约270℃,显示了良好的耐热性能。在7~15 GHz宽频范围下,改性树脂的介电常数3,介电损耗0.008~0.01,显示了良好的介电性能。     

国产T700级碳纤维增强双马树脂基复合材料的力学性能

采用扫描电子显微镜(SEM)、反气相色谱(IGC)和X射线光电子能谱仪(XPS)对国产T700级碳纤维和东丽T700S碳纤维的表面形貌、表面能和表面化学特性进行表征,测试两种碳纤维增强双马树脂基复合材料的力学性能,考察国产碳纤维复合材料的界面黏结性能、韧性和湿热性能。结果表明:碳纤维表面特性(表面形貌、表面能和表面化学组成等)对复合材料界面黏结性能具有显著影响;国产T700级碳纤维/QY9611复合材料在室温下的界面黏结性能优于T700S/QY9611复合材料;国产T700级碳纤维/QY9611复合材料的韧性优异,冲击后压缩强度达到了国外先进复合材料IM7/5250-4的水平;经湿热处理后的层间剪切强度仍与T700S/QY9611复合材料相当,说明国产T700级碳纤维/QY9611复合材料具备良好的湿热性能。