耐高温有机无机杂化聚酰亚胺树脂及其复合材料

文摘综述了近年来国内外在有机无机杂化聚酰亚胺树脂及其复合材料方面的研究进展,重点介绍了含笼状倍半硅氧烷和硅氧烷结构的有机无机杂化聚酰亚胺树脂的制备方法,对树脂的分子结构与其耐热性和热氧化稳定性之间的关系进行了分析总结,并对有机无机杂化聚酰亚胺树脂及其复合材料的应用和未来发展进行了探讨。     

Solar-photon sail hovering orbits about single and binary asteroids

Solar-photon sails can be useful for missions towards and about asteroids. Indeed, for the interplanetary transfer phase, missions to asteroids often require a large variation in inclination and solar-photon sails perform very well for such high energy missions. In the same way, solar-photon sails are also expected to perform well in the phase about the asteroid. This paper studies single and binary asteroids’ hovering regions by using a sailcraft. In order to consider a sailcraft with its own mass and shape, the mutual polyhedral method (usually used to study asteroid dynamics) is used; therefore, the sailcraft is designed by means of tetrahedra. The procedure to obtain the hovering regions about a single asteroid is presented and an accurate analysis of the control variables is carried out. Moreover, control torques required to maintain hovering orbits are obtained by considering the gravitational torques acting on the sailcraft due to the asteroid. In the end, the theory for hovering orbits is extended to binary-asteroid systems and applied to the binary system 1999 KW4.     

多型面复合材料支架成型技术

阐述了一种多型面复合材料支架整体成型技术,重点对工艺方案、模具设计、铺层工艺优化设计、固化方式进行了探究。结果表明:采用一体化成型方案,能够实现一种多型面复合材料支架的成型。通过工艺研究,突破了组合式模具设计,对称、阶梯过渡的铺层,真空辅助硅橡胶加压关键技术。产品具有较优的成型质量、尺寸精度及力学性能。复合材料制件内部无分层、疏松、孔隙等缺陷,纤维体积分数可控制在(60±3)%,孔隙率测试值均低于1.0%。产品安装面平面度优于0.3 mm,角度公差在±0.1°范围内。随炉试件力学性能高于设计指标,满足用户使用要求。     

笼形低聚硅倍半氧烷纳米材料及其应用

分析了笼形低聚硅倍半氧烷(POSS)单体的结构特点，评述了它的典型合成方法，介绍了最新合成路线，归纳了POSS纳米材料的基本特征，举例说明了这种无机一有机杂化材料在航空航天领域的潜在用途。指出这种新材料今后的主要发展方向是降低生产成本、研制新的功能化POSS单体、开发性能优良的POSS纳米杂化材料、探讨结构与性能之间关系以能动地设计制造POSS纳米结构材料。     

Reachable set estimation for spacecraft relative motion based on bang-bang principle

For spacecraft formation flight, the information of relative motion reachable set is very important, which can be used to predict the operating boundary of adjacent spacecraft and thus to ensure the safety of spacecraft operation. In this paper, we aim at developing a numerical method to approximate the reachable set for spacecraft relative motion. In particular, we focus on the quality of the approximation and the computational cost. Based on the bang-bang control principle, a polyhedral approximation algorithm is proposed to compute the reachable set of a relative motion spacecraft system. An inner approximation and an outer approximation of the reachable set for the system can be obtained. We prove that the approximation quality measured in Hausdorff distance can be guaranteed. The method is easy to implement and has low computational cost. Finally, the effectiveness of the algorithm is demonstrated by experimental simulation.     

耐高温柔性PI 气凝胶的合成与性能

以3,3’,4,4’ -联苯四酸二酐(BPDA)和含咪唑环的芳香族二胺,2-(4-氨基苯基) -5-氨基苯并
咪唑(4-APBI)或2-(3-氨基苯基) -5-氨基苯并咪唑(3-APBI) 为聚合单体,以八( 氨基苯基) 聚倍半硅氧烷
(OAPS)为交联剂,采用超临界CO2 干燥工艺制备了两种PI 气凝胶,PIA-1(BPDA/4-APBI/ OAPS) 与PIA-2
(BPDA/3-APBI/ OAPS)。研究表明,制备的PI 气凝胶具有纳米串珠状的微观结构,其泡孔最可几孔径分别为
22 nm(PIA-1)与14 nm(PIA-2)。PIA-1 与PIA-2 的密度分别为0. 105 和0. 080 g/ cm3,BET 表面积分别为
693 和302 m2 / g。此外,制备的PI 气凝胶具有良好的柔韧性与耐热稳定性,Tg 超过了350℃,T5
d 超过了530℃。