采用水热合成的方法,以硫脲(NH2CSNH2)为硫源和还原剂,合成出了二硫化钼/石墨烯(Mo S2/Graphene)复合电催化剂用于电解水制氢.将其旋涂到掺杂氟的Sn O2透明导电玻璃(FTO)上制备成Mo S2/Graphene薄膜进行电催化分解水制氢性能测试.研究发现,Mo S2/Graphene的催化活性较纯纳米Mo S2提高了近一倍.这是由于通过化学耦合作用选择性生长在石墨烯上的层状Mo S2其边缘拥有丰富的活性位点,同时石墨烯作为良好的导电基体也能大大加快了电子的转移速度.在0.5 mol/L H2SO4溶液中,Mo S2/Graphene旋涂到FTO上的层数为12层时,其电催化制氢效率最高:起峰电位提前到0.085 V,在0.2 V的过电位下电流密度达到了-4.5 m A/cm2.层状Mo S2/Graphene电催化剂作为Pt族贵金属的替代品,具有广阔的应用前景. 相似文献
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吸波材料的性能是影响雷达隐身的关键因素,其研究对军用和民用都具有非常重要的意义。石墨烯由于其独特的吸波性能,成为吸波材料研究的一大热点。本文综述了石墨烯/铁氧体、石墨烯/金属微粉、石墨烯/磁性金属、石墨烯/导电聚合物和石墨烯/磁性材料/导电聚合物等复合吸波材料在吸波领域的最新研究应用现状,并展望了吸波材料未来发展趋势。 相似文献
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Graphene nanosheets(GNSs) strengthened AgCuTi composite filler(AgCuTi_G) was used to braze C/C composite and Ti-6Al-4V. The effects of GNSs on the wettability of AgCuTi_G filler on the C/C composite surface and the interfacial microstructure and mechanical properties of brazed joints were investigated. The results indicate that the addition of GNSs reduced the wettability of AgCuTi_G. The interfacial microstructure of brazed joints evolved with the addition of GNSs, where Ti_3Cu_4 and TiCu_4 were converted to TiCu and the thickness of the reaction layer adjacent to the base material decreased. The maximum shear strength of joints brazed at 0.3 wt% GNSs was 23.3 MPa(880℃/10 min). Further adding GNSs deteriorated the shear strength of the joints. Fracture of the joints occurred in the C/C composite substrate and the TiC layer adjacent to C/C composite. 相似文献
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电阻作为重要的元器件在电气电子及其他非电领域得到了广泛应用,对其阻值进行准确溯源和量值传递至关重要。相较于实物电阻计量标准,量子化霍尔电阻标准稳定性和准确性更高。目前我国国家/国防量子化霍尔电阻计量基准是基于砷化镓-铝砷化镓异质材料制成的,其对环境温度和外磁场要求高,普通计量实验室难以复现。石墨烯材料的出现为新型量子化霍尔电阻基准/标准的研制提供了可能。本文简述了石墨烯材料的制备方法及其量子化霍尔效应,介绍了石墨烯量子化霍尔效应的国外研究现状,分析了基于石墨烯材料的量子化霍尔电阻标准在研制过程中存在的问题,旨在为我国新型量子化霍尔电阻标准的研制提供参考。 相似文献
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基于量子化霍尔效应建立电阻标准是当今前沿计量技术,是国际上定义电阻单位的最高标准,其核心部件是量子化霍尔电阻样品,传统砷化镓样品通常需要工作在10 T以上的强磁场环境中,磁体研制难度大,成本高,不易推广应用。随着量子电阻标准小型化、低成本化和国产化的发展,研制低磁场量子化霍尔电阻样品是发展趋势。介绍了砷化镓、石墨烯和铁磁拓扑材料三种低磁场量子电阻样品的原理,总结了研究现状和存在的问题,从磁场、温度、测量不确定度和技术成熟度等方面分析了三种方法的优势及不足,旨在为我国发展低磁场量子电阻标准提供理论基础。 相似文献
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The effect of hydrogen on the growth mechanism of pyrocarbon has attracted much attention. The influence of hydrogen on the dissociation from CH4to C2H2on pristine graphene,N-doped graphene and vacancy graphene have been investigated by using density functional theory.There are two kinds of heterogeneous reaction pathways when the hydrogen is involved, i.e., dehydrogenation reactions and H-abstraction reactions. The transition state calculations were performed to acquire the reaction pathways on... 相似文献
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《中国航空学报》2022,35(10):56-66
Under hypersonic flow conditions, the complicated gas-graphene interactions including surface catalysis and surface ablation would occur concurrently and intervene together with the thermodynamic response induced by spacecraft reentry. In this work, the competing effects of surface heterogeneous catalytic recombination and ablation characteristics at elevated temperatures are investigated using the Reactive Molecular Dynamics (RMD) simulation method. A Gas-Surface Interaction (GSI) model is established to simulate the collisions of hyper-enthalpy atomic oxygen on graphene films in the temperature range of 500–2500 K. A critical temperature Tc around 900 K is identified to distinguish the graphene responses into two parts: at T < Tc, the heterogeneous surface catalysis dominates, while the surface ablation plays a leading role at T > Tc. Contradicting to the traditional Arrhenius expression that the recombination coefficient increases with the increase of surface temperature, the value is found to be relatively uniform at T < Tc but declines sharply as the surface temperature increases further due to the competing ablation effect. The occurrence of surface ablation decreases the amounts of active sites on the graphene surface for oxygen adsorption, leading to reduced recombination coefficient from both Langmuir-Hinshelwood (L-H) and Eley-Rideal (E-R) mechanisms. It suggests that the traditional Computational Fluid Dynamics (CFD) simulation method, which relies on the Arrhenius-type catalysis model, would result in large discrepancies in predicting aerodynamic heat for carbon-based materials during reentry into strong aerodynamic thermal environment. 相似文献