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采用激光对大气等离子喷涂7YSZ热障涂层进行表面重熔处理,探讨基体预热和Al2O3溶胶涂敷对激光重熔层裂纹愈合的影响,研究处理后热障涂层的耐CMAS熔盐腐蚀性能。结果表明:涂层经过激光重熔和基体预热后的激光重熔处理后,与未经重熔处理涂层的CMAS腐蚀厚度基本相同;而采用表面Al2O3溶胶涂敷加激光重熔的热障涂层的CMAS腐蚀厚度明显减小,表明Al2O3溶胶涂敷加激光重熔工艺可以有效地减轻CMAS熔盐侵蚀,其机理是表面形成的Al2O3薄膜溶于CMAS后生成了难熔晶体钙长石,降低了熔盐的流动性和腐蚀性。 相似文献
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Degradation of thermal barrier coatings (TBCs) caused by calcium-magnesium-alumina-silica (CMAS) glassy penetration is becoming an urgent issue for TBCs industrial applications. In this work, yttrium aluminum garnet (Y3Al5O12, YAG) nano-powders were synthesized through a chemical co-precipitation route. The resistance of YAG ceramic to glassy CMAS infiltration at 1250?°C was evaluated. YAG ceramic bulk sintered at 1700?°C for 10?h was comprised of a single garnet-type Y3Al5O12 phase. The molten CMAS glass was suppressed on the surface of the YAG ceramic at 1250?°C. A chemical reaction between YAG and the molten CMAS glass did not occur at 1250?°C for 24?h, suggesting that YAG could act as an impermeable material against glassy CMAS deposits in the TBC field. 相似文献
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