柔性AgNWs/ITO/WO3薄膜的制备及其电致变色性能

文摘为适应电致变色领域越来越丰富的柔性化需求,解决柔性基底上直接制备电致变色薄膜性能不佳的问题。以聚对苯二甲酸乙二醇酯(PET)/银纳米线(AgNWs)为基底,采用室温直流反应磁控溅射制备了氧化铟锡(ITO)/氧化钨(WO_3)薄膜,研究了AgNWs/ITO复合电极的光电性能以及PET/AgNWs/ITO/WO_3薄膜的电致变色性能。结果表明,通过加镀ITO过渡层,克服了PET/AgNWs/WO_3薄膜存在的着色不均匀、单次循环后性能迅速衰退等问题。最终获得了透过率调制为57.4%(550 nm处)、69.6%(1 000 nm处),着褪色响应时间分别为10.4 s和9.9 s,相应的着褪色效率分别为27.79 cm~2/C和40.45 cm~2/C的高性能柔性电致变色薄膜。薄膜在超过500次循环稳定测试以及2 000次弯折测试后仍能保证较高的透过率调制,展现出了在柔性电致变色领域的巨大应用潜力。     

Study on the Deformation Behavior of Mg-Gd-Y-Zn-Mn Wrought Magnesium Alloys by Visco-plastic Self-consistent Modeling

The plastic deformation behavior of new Mg-Gd-Y-Zn-Mn magnesium alloys gains great necessity to clarify and understand the mechanism deeply. In the present work， the tensile mechanical property test and visco-plastic self-consistent (VPSC) model are used to investigate the activities of deformation modes of VW84M and VW94M magnesium alloys during the tensile deformation. The results show that the mechanical properties of the above extruded alloys are similar but VW94M has higher strength than VW84M after the same aging process. Compared with the extruded alloys， the as-aged alloys have significantly higher activation of pyramidal slip at the later stage of plastic deformation. In addition， the as-aged VW94M alloy with higher strength has the largest activity of pyramidal slip. In summary， the addition of Gd increases the critical resolved shear stress (CRSS) in each slip system of VW94M， while the increase in the strength and the decrease in the elongation of as-aged alloys are associated with the significant activation of pyramidal slip.     

超高强韧稀土镁合金直筒段锻造成形工艺

基于航天型号对超高强韧稀土镁合金构件产品的迫切需求，本文以航天器中的直筒段产品为研究对象，采用近等温锻造挤压成形工艺技术，开展VW84M高强韧稀土镁合金材料的锻造工艺性能研究，分析了直筒段的工艺结构特点，制定了直筒段的锻造成形工艺，通过三维建模、数值模拟技术和成形工艺试验，研究了直筒段的成形过程，分析了坯料的金属流动、温度变化特点，并通过成形工艺试验试制出锻件产品。结果表明，VW84M稀土镁合金在440 ℃的锻造温度时，在合适的挤压速度下具备良好的塑性成形性能，该材料具备实际工程应用能力；数值模拟得到的挤压载荷为64.72 MN，实际挤压载荷为60 MN，相差7.8 %，数值模拟结果与工程试验有较高的结合度；工艺试验得到的直筒锻产品，切、轴向力学性能指标优于预期，抗拉强度不小于340 MPa、屈服强度不小于210 MPa、延伸率不小于6 %的指标值。直筒段产品金属流线分布较为均匀，切向力学性能优于轴向。     

Design and experimental research of a sub-Newton N2O monopropellant thruster with inner-heater

Nitrous oxide（N₂O） is a green propellant with excellent application prospects. A subNewton N₂O monopropellant thruster with inner-heater and a N₂O self-pressurization stable supply system with regenerative heat compensation are designed in this paper. The experimental research of the thruster is described, including measurements of preheating power, activation temperature, vacuum thrust, specific impulse, life-span and pulsed operation performance. By inserting t...     

Microstructure and Hot Deformation Behavior of Mg-9Al-3Si-0.375Sr-0.78Y Alloy

Using Gleeble-3500 thermal simulator， the high temperature plastic deformation behavior and microstructure evolution of Mg-9Al-3Si-0.375Sr-0.78Y alloy are investigated at the temperature of 523 K?673 K and the strain rate of 10-3 s-1?10 s-1. True strain-true stress curves show the characteristics of the typical dynamically recrystallization process. The Arrhenius constitutive equation of the hyperbolic model is established. The average activation energy and the strain rate sensitivity index are， respectively， 221.578 kJ.mol-1 and 0.137. The result shows that the α-Mg phase exhibits dynamic recrystallization (DRX) characteristics obviously. But no DRX occurs in theβ-Mg17Al12 phase. Hot deformation does not affect the primary Mg2Si phase. Under the conditions of low temperature (523 K?673 K) and high strain rate (1 s-1?10 s-1)， the flow instability and macro-defects such as crack appear in the specimens. However， there are finer recrystallization grains. Under the conditions of high temperature (≥673 K) or low strain rate， the microstructure of the alloy shows good homogeneity. The size of the primary Mg2Si phase is uniform， the size of the β-Mg17Al12 phase is small， and the distribution of the β-Mg17Al12 phase is uniform.