大曲率复合材料结构的缺陷特征与超声检测

采用超声回波法对大曲率碳纤维增强树脂基复合材料零件进行超声A 扫描，并对缺陷进行定位。结合缺陷区域和非缺陷区域的细观形貌金相图、宏观表面状态以及厚度测量结果的对比分析，讨论了缺陷形态与其回波波形特征的对应关系，以及缺陷可能的形成原因。结果表明，缺陷在细观尺度上呈现多处分层、气孔和孔隙密集缺陷，在宏观尺度上表现为零件表面贫胶与厚度增厚。缺陷的性质与超声A扫描的检测结果相吻合，缺陷的位置集中在零件大曲率部位，其形成原因与复合材料制造工艺密切相关。     

A novel surrogate modeling strategy of the mechanical properties of 3D braided composites

In this paper, a surrogate-based modeling methodology is developed and presented to predict the elastic properties of three dimensional (3D) four-directional braided composites. Using this approach, the prediction process becomes feasible with only a limited number of training points. The surrogate models constructed using Finite Element (FE) method and Diffuse Approximation, reduce the computational time and cost for preparing experimental samples. In the FE model, multiscale method is applied to couple the computations of elastic properties at microscale and mesoscale. Subsequently, a parametric study is performed to analyze the effects of the three design parameters on the elastic properties. Satisfactory results are obtained via the surrogate-based modeling predictions, which are compared with the experimental measurements. Moreover, the predictions obtained from surrogate models concur well with the FE predictions. This study orients a new direction for predicting the mechanical properties based on surrogate models which can effectively reduce the sample preparation cost and computational efforts.     

Influence of TiB2 particles on machinability and machining parameter optimization of TiB2/Al MMCs

In situ formed TiB₂ particle reinforced aluminum matrix composites (TiB₂/Al MMCs) have some extraordinary properties which make them be a promising material for high performance aero-engine blade. Due to the influence of TiB₂ particles, the machinability is still a problem which restricts the application of TiB₂/Al MMCs. In order to meet the industrial requirements, the influence of TiB₂ particles on the machinability of TiB₂/Al MMCs was investigated experimentally. Moreover, the optimal machining conditions for this kind of MMCs were investigated in this study. The major conclusions are: (1) the machining force of TiB₂/Al MMCs is bigger than that of non-reinforced alloy and mainly controlled by feed rate; (2) the residual stress of TiB₂/Al MMCs is compressive while that of non-reinforced alloy is nearly neutral; (3) the surface roughness of TiB₂/Al MMCs is smaller than that of non-reinforced alloy under the same cutting speed, but reverse result was observed when the feed rate increased; (4) a multi-objective optimization model for surface roughness and material removal rate (MRR) was established, and a set of optimal parameter combinations of the machining was obtained. The results show a great difference from SiC particle reinforced MMCs and provide a useful guide for a better control of machining process of this material.     

纤维增韧陶瓷基复合材料的比例极限应力与残余热应力关系

从细观力学角度分析并建立了纤维增韧陶瓷基复合材料从制备温度冷却到室温过程中产生的残余热应力与复合材料的比例极限应力的关系模型。该模型表明,减少复合材料的残余热应力或提高复合材料的纤维与基体的模量比,均可提高复合材料的比例极限应力。通过单调拉伸实验测试了先驱体浸渍裂解法(PIP)制备的2D SiC/SiC复合材料的比例极限应力,并采用文中建立的比例极限应力与残余热应力关系模型,计算出复合材料SiC基体的残余热应力为-19.5 MPa。分析表明,该结果是合理的。此外,引用了公开文献报道的5种复合材料体系数据,用于验证文中所建立的比例极限应力与残余热应力关系模型的适应性和可靠性,计算结果与实验结果最大误差为18.6%,表明该模型具有较好的适应性和可靠性,可为纤维增韧陶瓷基复合材料的研究提供新思路。     

液体天然橡胶对湿法混炼制备天然橡胶/白炭黑复合材料性能的影响

采用湿法混炼工艺制备天然橡胶/白炭黑(W(NR/SiO_2))复合材料,并采用液体天然橡胶(LNR)为增容剂,探讨了LNR对复合材料硫化特性、橡胶加工性能、白炭黑分散性、静态力学性能及动态性能的影响。结果表明:LNR具有较好的增容效果;使用LNR增容后,胶料的正硫化时间缩短,在白炭黑为70 phr时T_(90)缩短4.16 min,加工性能改善;白炭黑在NR中的分散性提高;胶料力学性能得到改善,在白炭黑为60 phr时最明显,拉伸强度和撕裂强度分别提高25.73%和66.59%;LNR增容后胶料的抗湿滑性提高且滚动阻力降低。复合材料良好的相容性是LNR与NR和白炭黑两相同时发生作用形成增容界面的结果。     

基体合金相组成对硼化物增强镁锂基复合材料组织和性能的影响

采用原位合成法制备了硼化物增强Mg-Li基复合材料。针对基体为Mg-14Li-1Al-1Y的复合材料力学性能仍不能满足工业应用需求的缺陷,以Mg-9Li-1Al-1Y镁锂合金为基体制备了硼化物增强镁锂基复合材料(其成分为(Mg-9Li-1Al-1Y)-6B_4C)。研究了Li含量对基体合金和复合材料组织和性能的影响。试验结果表明:合金Mg-9Li-1Al-1Y与合金Mg-14Li-1Al-1Y相比,其双相区组织晶粒更加细小,各力学性能均有所提高。(Mg-9Li-1Al-1Y)-6B_4C复合材料与Mg-9Li-1Al-1Y合金相比,硬度提高了66%,抗拉强度提高了31.33%,伸长率降低了15.5%。(Mg-9Li-1Al-1Y)-6B_4C与(Mg-14Li-1Al-1Y)-6B_4C相比,屈服强度降低了15.4%,硬度提高了29.3%,抗拉强度和伸长率基本保持不变。以上试验结果表明:随着Li含量的降低复合材料的力学性能没有得到提高,没有实现基体合金强度增加从而相应复合材料强度增加的试验预期,说明相比镁锂基复合材料强化机制中第二相强化与细晶强化的作用,基体强化作用较弱难以体现。     

固体冲压发动机喷管用C/C-SiC复合材料

采用"化学气相渗透+先驱体浸渍裂解"(CVI+PIP)混合工艺制备固体冲压发动机用C/C-SiC复合材料喷管内层,综合考查复合材料的微观结构、弯曲性能和抗烧蚀性能以及固冲发动机C/C-SiC喷管内层水压和点火实验。结果表明:复合材料的弯曲强度达到197 MPa,且断裂破坏行为呈现典型的韧性模式;复合材料具有优异的抗氧化烧蚀性能,氧化烧蚀200 s后线烧蚀率仅为0.0063 mm·s-1;研制的C/C-SiC复合材料构件的水压爆破压强为6.5 MPa,表明构件具有良好的整体承载能力;C/C-SiC复合材料喷管内层高温综合性能通过了固体冲压发动机点火实验考核。     

Theoretical aspects of selecting repeated unit cell model in micromechanical analysis using displacement-based finite element method

Repeated Unit Cell(RUC)is a useful tool in micromechanical analysis of composites using Displacement-based Finite Element(DFE)method,and merely applying Periodic Displacement Boundary Conditions(PDBCs)to RUC is almost a standard practice to conduct such analysis.Two basic questions arising from this practice are whether Periodic Traction Boundary Conditions(PTBCs,also known as traction continuity conditions)are guaranteed and whether the solution is independent of selection of RUCs.This paper presents the theoretical aspects to tackle these questions,which unify the strong form,weak form and DFE method of the micromechanical problem together.Specifically,the solution’s independence of selection of RUCs is dealt with on the strong form side,PTBCs are derived from the weak form as natural boundary conditions,and the validity of merely applying PDBCs in micromechanical Finite Element(FE)analysis is proved by referring to its intrinsic connection to the strong form and weak form.Key points in the theoretical aspects are demonstrated by illustrative examples,and the merits of setting micromechanical FE analysis under the background of a clear theoretical framework are highlighted in the efficient selection of RUCs for Uni Directional(UD)fiber-reinforced composites.     

先进复合材料国防科技重点实验室的航空树脂基复合材料研发进展

归纳先进复合材料国防科技重点实验室在航空先进树脂基复合材料方面的应用和研究进展.研制出超薄热塑性无纺织物层间增韧技术以实现提高复合材料的CAI性能.设计出的多夹层结构具有多层吸收拓展频带的作用,使多夹层隐身复合材料的吸收频宽达1 ～ 18GHz.高韧性树脂基复合材料和耐高温复合材料技术得到发展,并形成预浸料-热压灌成型、液态成型和自动化制造技术体系.发展复合材料固化、树脂流动、固化变形等模拟优化技术,并建立复合材料数据库技术.建立先进复合材料国防科技重点实验室可在支撑航空装备研制,在航空复合材料创新引领、体系主导、基础支撑和保障应用方面发挥作用.     

Effect of interface debonding on matrix multicracking evolution of fiber-reinfroced ceramic-matrix composites

An analytical methodology was developed to investigate the effect of fiber/matrix interface debonding on matrix multicracking evolution of fiber-reinforced CMCs(ceramic-matrix composites). The Budiansky-Hutchinson-Evans shear-lag model was adopted to analyse the micro-stress field of the damaged composites. The critical matrix strain energy criterion, which presupposes the existence of an ultimate or critical matrix strain energy with matrix, was obtained to simulate the matrix multicracking evolution of CMCs. With the increase of the applied stress, the matrix multicracking and fiber/matrix interface debonding occurred to dissipate the additional energy entered into the composites. The fiber/matrix interface debonded length under matrix multicracking evolution was obtained by treating the interface debonding as a particular crack propagation problem. The conditions for no-debonding and debonding during the evolution of matrix multicracking were discussed in terms of two interfacial properties, i.e., the interface shear stress and interface debonded toughness. When the fiber/matrix interface was bonded, the matrix multicracking evolution was much more intense compared with the interface debonding; when the fiber/matrix interface was debonded, the matrix crack density increased with the increasing of interface shear stress and interface debonded energy. The theoretical results were compared with experimental data of unidirectional SiC/CAS(calcium alumina silicate), SiC/CAS-Ⅱ and SiC/borosilicate composites.