前驱体法制备Ta4HfC5超纯超细纳米粉体

利用实验室自制铪酸酯和钽酸酯为原料,经水解缩合后得到了含铪钽元素的聚合物PHT,引入酚醛(PF)作为C源,制备了Ta_4HfC_5前驱体,经固化、高温裂解后,获得了超纯超细Ta_4HfC_5纳米粉体。通过XRD、元素分析和SEM对不同工艺条件下陶瓷产物的晶相组成和微观形貌进行了表征;对陶瓷粉体进行了粒度分析。结果表明,合成的前驱体结构稳定,常温避光储存3个月后黏度几乎没有变化,对于复材加工的工艺适应性良好。在酚醛用量3.25 wt%(以PHT质量分数100%计算)、煅烧温度为1 450℃、保温时间为1.5 h的合成条件下,可以得到纯相的Ta_4HfC_5粉体,晶粒尺寸为25～50 nm,粒径分布在100～200 nm之间,Dv(50)=136 nm。     

多孔氮化硅高温氧化特性分析

采用TG-DSC、XRD、SEM、ICP 等分析手段,对某一典型多孔氮化硅样品进行4 个不同温度点的

静态和微动态连续氧化试验,最高氧化温度为1 400℃。结果表明:多孔氮化硅在0. 1 MPa 静态空气气氛下,

800℃之前,氧化反应非常微弱,800℃以上可见明显的氧化反应,1 000℃以上氧化反应加剧,增重速率加快,并

优先发生在表面与外部孔壁处,之后再发生在样品的内部孔隙处,氧化反应受界面处的化学动力学控制,以被

动氧化为主,主要生成物是SiO2,属吸热反应。当生成的SiO2 将氮化硅表面和孔壁处覆盖时,在其界面处,随

着温度的进一步升高或时间的延长,会生成Si2N2O,且需要注意防范样品可能出现脆性断裂情况。此外,同等

温度下,动态氧化气氛将加速氮化硅的氧化,特别是多孔和粉末状样品。

     

Biaxial tensile behavior of Ti-6Al-4V under proportional loading

The biaxial tensile behavior of isotropic Ti-6Al-4 V is characterized in this paper. A novel cruciform specimen was designed and optimized to achieve uniform stress and strain distribution within the gauge area. Biaxial tensile tests were conducted at three different loading ratios by the biaxial testing machine. The Digital Image Correlation (DIC) technique was applied to determine strain distribution, and a high-speed camera was employed to record the fracture process. An Inverse Analysis (IA) approach with a combined experimental and numerical method was proposed to determine the true stresses at the gauge section of the specimen during biaxial tensile tests. The results indicate that the initial yield locus can be described by the Cazacu criterion accurately, whereas the Mises criterion can predict better the strengthening behavior of Ti-6Al-4 V in the first quadrant in the principal stress space.     

TC4-DT钛合金线性摩擦焊接头组织特征及其形成机制

研究TC4-DT损伤容限型钛合金线性摩擦焊(linear friction welding,LFW)接头的组织特征及形成机制。利用光镜和扫描电镜对接头各区域微观组织进行表征,利用显微硬度计测试接头的显微硬度分布。结果表明:接头焊缝区(WZ)发生动态再结晶,焊接过程中WZ温度超过β转变点,焊后快冷的条件下发生了β→α′及β→α两种相变并析出了大量α′马氏体以及二次层片α;TC4-DT钛合金母材(BM)组织具有较高的变形抗力,使得接头形成的热力影响区(TMAZ)较窄。TMAZ内组织在强烈的热力耦合作用下拉长变形并破碎,焊后快冷的条件下析出少量α′马氏体及大量二次层片α;毗邻TMAZ的热影响区(HAZ)基本保留了BM不同位向的α集束的组织特征,但受热的影响α集束内α/β相界两侧元素相互扩散,层间β消耗,初生α长大;WZ组织的细晶强化和第二相强化,TMAZ组织的应变强化和第二相强化,以及HAZ内α相的长大使得接头上述区域显微硬度均高于BM。     

CFRP/TC4叠层结构制孔技术对比实验

因CFRP、TC4材料的物理性能差异较大，导致CFRP/TC4叠层构件切削性能匹配性较差，钻削过程中存在界面损伤、CFRP孔壁损伤难以调控的问题。针对上述问题，本文采用变参数啄式钻削工艺、变参数钻削工艺和恒参数钻削工艺对CFRP/TC4叠层结构进行了制孔实验，并对不同工艺条件下的轴向力、界面质量、TC4的切屑形态、CFRP层孔壁质量进行了对比分析。结果表明：相对于其他两种钻削工艺，在变参数啄式钻削工艺条件下，TC4材料层轴向力明显较高，产生短带状和短螺旋状切屑；CFRP层出口和入口处的孔径更接近于名义孔径，孔壁缺陷较少，表面粗糙度相对较小。     

切削参数对Ti-6Al-4V锻件与粉末冶金工件表面粗糙度的影响对比

文摘表征了已加工Ti-6Al-4V锻件和粉末冶金工件表面形貌,利用正交回归试验得到了两种材料表面粗糙度值的数学模型,经过显著性检验两个数学模型能够准确地预测表面粗糙度值变化趋势。结果表明,Ti-6Al-4V锻件表面出现了进给划痕、切屑碎片和表面撕裂缺陷,粉末冶金材料表面出现了除了进给划痕、切屑碎片和撕裂外的微孔隙缺陷;两种工件表面粗糙度值均受到进给量的影响程度最大,同时粉末冶金材料内部残余微孔隙的存在导致切削速度对其表面粗糙度值的影响程度比较大。     

大气探测激光雷达校飞样机研制与飞行验证

星载激光雷达是高精度测量全球温室气体和气溶胶垂直廓线的重要手段，大气环境监测卫星大气探测激光雷达(ACDL)在国际首次采用激光积分路径差分吸收技术测量全球CO2柱浓度，采用532 nm高光谱探测技术测量气溶胶和云的廓线。星载激光雷达载荷研制期间，同步研制一套主要功能一致的机载大气探测激光雷达校飞样机，并开展机载飞行试验，获取了大量飞行试验及其对比数据，提供了机载平台真实的数据源，对于优化ACDL激光雷达系统参数和研究星载数据反演算法至关重要。最后在机载飞行平台下，验证了优于1 ppm的CO2柱浓度测量精度和优于15%的气溶胶测量精度。未来利用该机载样机可以进一步开展星地对比验证。     

Hardware qualification for scientific ballooning missions

The European Stratospheric Balloon Observatory (ESBO) initiative aims at simplifying the access to stratospheric balloon missions. We plan to provide platforms and support with instrument design in order to support scientists. During the design process, the inevitable question of qualification for the harsh flight conditions arises. Unfortunately, there is no existing standard for qualification of stratospheric ballooning hardware. Thus, we developed a qualification procedure for use within ESBO and similar projects.In this paper, we present our analysis of the environmental conditions in the stratosphere. While conditions at typical balloon float altitudes are similar to the space environment, there are also some relevant differences. For example, the thermal environment is dominated by radiation and thermal conduction, but the remaining atmosphere still supports a certain amount of convection. The remaining atmospheric pressure in the stratosphere also leads to reduced arcing distances. Vibrational loads are far less than for space missions, but quasi-static or shock loads may occur. The criticality of radiation increases with mission duration.Based on the environmental conditions, we present the qualification procedures for ESBO, which are based on the European Cooperation for Space Standardization (ECSS) standards for space systems. Overtesting against too high requirements leads to overengineering, driving mission cost and mitigating the advantages of balloons over space missions. Therefore, we modified the ECSS standards to fit typical scientific ballooning missions over several days at altitudes up to 40 km. Furthermore, we analyzed design rules for space systems with regard to their relevance for scientific ballooning, including material and component selection. We present the experience from the hardware qualification process for the ESBO prototype STUDIO (Stratospheric UV Demonstrator of an Imaging Observatory). Even though boundary conditions are different for each individual mission, we aimed for a broader approach: We investigated more general requirements for scientific ballooning missions to support future flights.     

外物损伤对TC4 钛合金的高周疲劳强度的影响

为了研究外物损伤对航空发动机叶片疲劳性能的影响规律,将直径为3、4 mm的钢珠利用空气炮加速到约300 m/s对TC4合金平板试样进行外物损伤试验,利用3维体式显微镜和扫描电子显微镜(SEM)分别观察外物损伤的宏观特征和微观特征。结果表明:在随后的高周疲劳试验中外物损伤容易诱发疲劳裂纹的萌生,且试样的疲劳强度随损伤深度的增加而降低;疲劳源一般位于损伤区域的表面位置,因为试样在冲击过程中在损伤区域形成了微观裂纹和缺口。     

电动膨胀循环液氧甲烷变推力发动机动态特性研究

电动泵压式液体火箭发动机受到了广泛的关注，然而电池有限的输出功率和过于沉重的质量成为限制电动泵压式发动机发展的重要因素。为此本文提出了一种电机驱动燃料泵和涡轮驱动氧泵的电动膨胀循环液体火箭发动机方案，并着重研究了该型发动机的动态响应特性。首先给出了20 kN级电动膨胀循环发动机的技术指标和部组件参数，进一步基于AMESim平台建立了全系统动力学模型，验证了方案的可行性和部组件动力学模型的准确性，并深入研究了单点工况和调节工况的动态响应特性。结果表明，针对启动过程而言，涡轮泵调整时间较电动泵长，这降低了系统响应速度，但工况越高，系统响应速度越快；高工况启动时，甲烷在冷却通道内的剧烈相变和跨临界状态的不连续物性相互耦合易引发系统振荡；就调节过程而言，推力调节时普遍存在超调或凹坑现象，且系统在两相同工况之间调节时，正调响应速度快于负调，这也导致阶跃幅值相等条件下的系统调整时间随目标工况升高而缩短。