TiB_2粉料的合成与纯化研究

基于SHS还原反应合成TiB2 混合粉料 ,研究了酸洗条件对TiB2 纯度的影响。实验结果表明 ,TiO2 B2 O3 Mg三元系统的化学反应由两部分组成 ,第一部分由金属Mg还原出B和Ti单体 ,第二部分由两种单体化合反应生成TiB2 。TiB2 粉料的纯度主要取决于酸洗条件。提高盐酸浓度、增加酸过量和延长酸洗时间可以提高TiB2 粉料的纯度 ,而升高酸洗温度还可以大大加快酸洗速度     

燃烧室头部进气规律对煤粉燃烧效率的影响

用实验方法研究了火焰筒式煤粉燃烧室头部进气规律对燃烧效率的影响。通过对6种结构的头部配气方案的分析比较,得出了煤粉燃烧室合理的头部配气方案,为今后煤粉燃烧室的设计和工作状态的选择提供了重要的实验依据。     

隔层式多脉冲发动机点火延迟数值仿真研究

隔层式多脉冲发动机点火过程较常规发动机有很多不同,为获得端燃型隔层式多脉冲发动机的点火延迟特性及其影响因素,建立物理和数学模型,采用MpCCI耦合器作为FLUENT与ANSYS的数据交换平台,模拟点火燃气填充隔层和隔层变形过程;采用FLUENT计算多脉冲发动机火焰传播过程及填充过程。计算结果表明,与传统固体火箭发动机相比,在相同点火药量的情况下,多脉冲发动机的点火延迟大大增加;推进剂燃速越高,点火延迟越小;燃烧室自由容积越大,点火延迟越大;隔层材料对点火延迟影响较小。可以通过适当加大点火药量和提高燃速来减小点火延迟。     

液相先驱体转化法制备ZrC粉末及合成机理

以氯氧化锆、丙醇、丙三醇和乙酰丙酮等为基本原料合成了锆的有机先驱体溶液,采用液相先驱体转化法在1 500℃制备了ZrC粉末。运用FTIR对锆的先驱体溶液的组成、结构以及形成机理进行了分析,用XRD和EDS分析了粉末的形成机理,用SEM观察了粉末的形貌。结果表明,有机锆的先驱体溶液具有螯和的链状或网状结构;先驱体溶液干燥后的粉末呈蜂窝状结构,在不同热处理温度下获得面心立方的ZrC粉末。经过热力学计算结果表明,C还原锆的氧化物开始生成ZrC的最低温度为1594℃,实验温度低于理论温度,在1500℃时获得面心立方的ZrC材料。     

正十二烷和甲基环己烷在超燃燃烧室中的点火和稳焰特性研究

主要研究了液态单组份碳氢燃料在超燃燃烧室中的点火和稳焰性能,所用燃料为正十二烷和甲基环己烷,研究结果可以为超燃冲压发动机的燃料制备提供部分依据。试验在以蓄热式加热器为核心的直连式试验台上进行,超燃燃烧室进口总温在1040~1100K范围内,进口马赫数2.03,进口空气流量2.0kg/s左右,点火器为燃气发生器,采用串联凹腔作为火焰稳定装置,在第一个凹腔前常温燃料垂直喷射到燃烧室中。研究结果表明:与正十二烷相比,甲基环己烷在来流总温较低的超声速流中更容易被点燃和实现稳火,但总体来讲,当燃烧室进口总温低于1100K时,常温液态燃料的点火和稳焰性能较差。理论分析了两种燃料的蒸发特性,计算结果表明在来流参数相同时,甲基环己烷的蒸发特性优于正十二烷。利用一维分析方法结合试验测量的壁面静压、燃烧室入口马赫数和空气流量,得到了正十二烷和甲基环己烷不同工况时的总温分布和出口燃烧效率。     

粉末渗铌探讨

本文通过团体粉末渗铌试验，分析了渗剂成分、渗入时间与温度对不同材料渗层的影响，研究与探讨了渗层的组织和性能。对４５钢、Ｔ１０钢、９ＣｒＳｉ钢和ＧＣｒ１５钢等材料采用铌铁粉末进行的渗铌处理，均可形成一定厚度的铌渗层，且表层硬度提高很多，摩擦力矩数值反映渗铌后摩擦系数减少。     

含纳米金属粉的推进剂点火实验及燃烧性能研究

利用CO2激光点火系统对含有纳米铝粉和纳米镍粉的AP／HTPB推进剂进行激光点火实验,测量了推进剂在不同激光功率和压强下的点火延迟时间,对推进剂的燃速、常压点火温度和爆热也进行了测量。同时,利用氧化还原滴定法测定燃烧残渣中活性铝含量。结果表明,纳米铝粉(n—Al)的点火阀值比普通铝粉(g-A1)的点火阀值小几个数量级,加入纳米铝粉可有效地缩短推进剂点火延迟时间。而在纳米镍粉为催化剂的协同作用下,推进剂燃速明显提高,点火延迟时间也大大减少,Al在推进剂燃烧过程中的燃烧效率得以提高,同时燃烧残渣中活性铝含量也明显降低。     

Modelling ignition probability with pairwise mixing-reaction model for flame particle tracking

Reduced order models for ignition analysis can offer insights into ignition processes and facilitate the combustor optimization. In this study, a Pairwise Mixing-Reaction (PMR) model is formulated to model the interaction between the flame particle and the surrounding cell mixture during Lagrangian flame particle tracking. Specifically, the model accounts for the two-way coupling of mass and energy between the flame particle and the surrounding shell layer by modelling the corresponding turbulent mixing, chemical reaction and evaporation process if present. The state of a flame particle, e.g., burnt, hot gas or extinguished, is determined based on particle temperature. This model can properly describe the ignition process with a spark kernel being initiated in a nonflammable region, which is of practical importance in certain turbine engines and has not been rigorously accounted for by the existing models based on the estimation of local Karlovitz number. The model is integrated into an ignition probability analysis platform and is demonstrated for a methane/air bluff-body flame with the flow and fuel/air mixing characteristics being extracted from a non-reacting simulation. The results show that for the spark location being at the extreme fuel-lean outer shear layer of the recirculation zone, PMR can yield ignition events with a significant number of active flame particles. The mechanisms for the survival of the initial flame particles and the entrainment of the survived flame particles into the recirculation zone are analyzed. The results also show that the ignition probability map from PMR agrees well with the experimental observation: a high ignition probability in the shear layer of the recirculation zone near the mean stoichiometric surface, and low ignition probabilities inside the recirculation zone and the top stagnation region of the recirculation zone. The parametric study shows that the predicted shape of the ignition progress factor and ignition probability is in general insensitive to the model parameters and the model is adequate for quantifying the regions with high ignition probabilities.     

One-dimensional numerical investigation on multi-cylinder gasoline engine fueled by micro-emulsions,CNG, and hydrogen in dual fuel mode

This research work is the novel state-of-the-art technology performed on multi-cylinder SI engine fueled compressed natural gas, emulsified fuel, and hydrogen as dual fuel. This work predicts the overall features of performance, combustion, and exhaust emissions of individual fuels based on AVL Boost simulation technology. Three types of alternative fuels have been compared and analyzed. The results show that hydrogen produces 20% more brake power than CNG and 25% more power than micro-emulsion fuel at 1500 r/min, which further increases the brake power of hydrogen, CNG, and micro-emulsions in the range of 25%, 20%, and 15% at higher engine speeds of 2500–4000 r/min, respectively. In addition, the brake-specific fuel consumption is the lowest for 100% hydrogen, followed by CNG 100% and then micro-emulsions at 1500 r/min. At 2500–5000 r/min, there is a significant drop in brake-specific fuel consumption due to a lean mixture at higher engine speeds. The CO, HC, and NO_x emissions significantly improve for hydrogen, CNG, and micro-emulsion fuel. Hydrogen fuel shows zero CO and HC emissions and is the main objective of this research to produce 0% carbon-based emissions with a slight increase in NO_x emissions, and CNG shows 30% lower CO emissions than micro-emulsions and 21.5% less hydrocarbon emissions than micro-emulsion fuel at stoichiometric air/fuel ratio.     

PS-PVD用CeO2掺杂8YSZ团聚粉末及其涂层

在纳米ZrO₂-8%Y₂O₃(摩尔分数)(8YSZ)粉末中掺杂20%(质量分数)微米级CeO₂粉末,并通过喷雾干燥合成CeO₂-8YSZ(CYSZ)复合团聚粉体。借助激光粒度仪和扫描电镜(SEM)及附带能谱仪(EDS)考察羧甲基纤维素黏结剂(carboxymethyl cellulose,CMC)质量分数对复合团聚粉体性能影响。采用PS-PVD制备具有柱状结构的CYSZ热障涂层,对涂层截面和表面进行EDS分析。采用X射线衍射(XRD)和X射线光电子能谱(XPS)分析涂层物相。结果表明:黏结剂质量分数达到2%时可获得球形度高、粒度分布均匀的团聚粉体;制备的涂层中Ce元素呈均匀分布;涂层物相基本为t-相结构,其中Ce⁴⁺取代Zr⁴⁺进入ZrO₂晶格形成类质同象的固溶体结构,显示出CeO₂掺杂对t-相向m-相转变的抑制作用;所制备CYSZ涂层在1100℃,水冷循环100次后仍保持完整,展现出较高的抗热冲击性能。