内氧化制备A1_2O_3/Cu复合材料载流条件下表面磨损形貌和摩擦学性能研究(英文)

Two Al2O3/Cu composites containing 0.24 wt.% Al2O3 and 0.60 wt.% Al2O3 separately are prepared by internal oxidation. Effects of sliding speed and pressure on the frictional characteristics of the composites and copper against brass are investigated and compared. The changes in morphology of the sliding surface and subsurface are examined with scanning electron microscope （SEM） and energy dispersive X-ray spectrum （EDS）. The results show that the wear resistance of the Al2O3/Cu composites is superior to that of copper under the same conditions, Under a given electrical current, the wear rate of Al2O3/Cu composites decreases as the Al2O3-content increases, However, the wear rates of the Al2O3/Cu composites and copper increase as the sliding speed and pressure increase under dry sliding condition. The main wear mechanisms for Al2O3/Cu composites are of abrasion and adhesion; for copper, it is adhesion, although wear by oxidation and electrical erosion can also be observed as the speed and pressure rise.     

铝铜点焊的研究

提出了铝铜过渡接头的点焊新方法,用交流焊机点焊铝铜,解决了Al2O3氧化膜层的破碎问题。从而可利用热活化、压力、电磁搅拌力,使铝铜固溶,扩散和铝液面移动,完成铝铜点焊,获得比铝强度高的焊接接头,为铝代铜的运用提供了一种特殊的途径。     

离子辅助沉积Al膜层增强Ti811钛合金高温微动疲劳抗力

为提高Ti811钛合金高温微动疲劳抗力,利用离子辅助沉积技术在Ti811钛合金表面制备Al膜层。对比研究多弧离子镀(MIP)和离子辅助多弧沉积(IAD)Al膜层的膜基界面成分分布、膜基结合强度、显微硬度、摩擦学性能。探讨IAD铝膜层对Ti811合金微动疲劳抗力的影响。结果表明,利用离子辅助多弧沉积技术可以获得膜基结合强度高、硬度低、减摩润滑性能好的Al膜层,该膜层能够显著提高Ti811钛合金350℃时的微动疲劳抗力。     

模拟实际飞机腐蚀介质中高强铝合金材料腐蚀行为研究

利用电偶腐蚀,动电位扫描等方法,模拟飞机运行条件下实际腐蚀介质中LY12,LC4高强铝合金等飞机常用的结构材料偶接后的腐蚀情况进行研究。LY12,LC4铝合金的腐蚀均由点蚀开始,发展成层状翘起,以至腐蚀剥落。不同偶接金属的搭配对腐蚀的影响也很大,偶接状态下其腐蚀电化学行为以电位负的金属为主。     

SiC_P/Al复合材料界面反应动力学研究

用复合铸造法制备的SiC_μ/Al复合材料,加热到一定温度并保温不同时间以改变其界面反应程度,通过确定复合材料中的分含量及其与温度和时间之间的相互关系,对界面反应动力学进行了研究,并导出动力学方程,由此求出反应动力学的参数。     

LY12cz铝合金晶间腐蚀模拟试验研究

用金属间化合物 θ(CuAl₂)、S(Al₂CuMg)、MnAl₆与纯Al(L1)组成多电极体系,以模拟LY12cz合金的晶界区.通过电化学测试、SEM和能谱分析等方法研究了该合金晶间腐蚀机理.证实其晶间腐蚀是由沿晶界偏析的强化相与贫Cu区所组成的多电极体系引起的.在含Cl^－离子的中性溶液中,S相是导致晶间腐蚀的主要阳极相.S相首先发生阳极溶解,随后,贫铜区、MnAl₆相逐步随S相一起溶解.以这种方式沿晶界形成了阳极溶解通道,导致晶间腐蚀.     

稀土元素及杂质在铝锂合金中的作用研究现状与发展

 综述了稀土元素和杂质对铝锂合金微观组织及力学性能的作用,概括了杂质致脆及稀土微合金化的规律与机制,根据已有研究结果,对目前铝锂合金的发展与应用中需要引起重视的问题,提出了某些观点与建议。     

SiCw/Al复合材料热挤压模具设计及其对挤压棒材组织和性能的影响

用具有宏观夹铝带的ＳｉＣｗ／Ａｌ复合材料的热挤压余,对热挤压压余中的金属流线进行了观察并建立了金属流线方程,为抗日夺模具的设计提供了指导原则。本文用曲线形状较金属流线形状陆的流线凹模进行挤压,结果表明,使用该种凹模能够有效地消除金属“死区”并在一定程度上减少了晶须折断,从而提高了挤压棒的强度。     

溶胶-凝胶法制备复合材料用氧化铝基体及涂层研究

采用溶胶—凝胶法,分别研究了用三种起始物异丙醇铝［Ａｌ（ＯＣ３Ｈ７ｉ）３］、氯化铝（ＡｌＣｌ３·６Ｈ２Ｏ）、硝酸铝［Ａｌ（ＮＯ３）３·９Ｈ２Ｏ）］,制备碳纤维三维编织物增强复合材料用氧化铝基体及涂层的工艺,考察了三种体系反应物配比、水解温度、反应时间等因素对制得的三种溶胶体系性能的影响,获得了较佳的溶胶配制参数;还考察了三种溶胶体系在通常情况下和在编织物中的凝胶化情况,获得了较佳的凝胶化条件;同时还研究了不同条件下三种凝胶的裂解产物及其晶体类型。结果表明,不管经过何种途径,凝胶在经１２６０℃裂解后均可获得α－Ａｌ２Ｏ３。     

Microstructure and Properties of Low-pressure Cold Sprayed Al-based Composite Coatings on Magnesium Alloy Surface

Pure Al and Al-30% Al2O3 composite coatings are prepared on the surface of AZ31B magnesium alloy by low-pressure cold spraying. The morphology and structure of the coatings are analyzed by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD), and the effects of the addition of Al2O3 on the microstructure of the Al-based coatings are discussed. The mechanical properties and corrosion resistance of the coatings are fully evaluated by the micro-hardness tester, electronic tensile machine, and electrochemical workstation. The results show that the coating structure is more uniform and denser, and the porosity is significantly reduced after the addition of Al2O3. The interfaces between the coatings and the magnesium alloy substrate are distinct, and the coatings and the substrate are mechanically combined. Compared with the pure Al coating, the microhardness of the Al-Al2O3 composite coating is increased to 61.1 HV0.2, and the bonding strength reaches above 53.1 MPa. The self-corrosion potential of the two coatings is higher than that of the magnesium alloy, and the self-corrosion current density is significantly lower than that of the magnesium alloy substrate. The Al-based coatings prepared by low-pressure cold spraying have high hardness, good bonding strength, and good corrosion resistance, which can be used for the repair and protection of magnesium alloy structural parts.