The carbon dioxide cycle

The seasonal CO₂ cycle on Mars refers to the exchange of carbon dioxide between dry ice in the seasonal polar caps and gaseous carbon dioxide in the atmosphere. This review focuses on breakthroughs in understanding the process involving seasonal carbon dioxide phase changes that have occurred as a result of observations by Mars Global Surveyor.     

Seasonal patterns of condensation and sublimation cycles in the cryptic and non-cryptic regions of the South Pole

The South Pole of Mars is characterized by an asymmetric residual ice cap composed of water ice and CO₂ ice. On the opposite side of the residual cap, there exists an area called cryptic region which is relatively free of ice during summer time. Many fan-shaped km-scale structures apparently caused by a wind-blown system of dust-laden gas jets occurred dozens degrees of Ls before the complete sublimation of the CO₂ frost layer. We have examined the seasonal cycles of condensation and sublimation in the cryptic and non-cryptic regions by using the topographic data from the MOLA/MGS measurements. Using the MOLA topography data collected over one Martian year (1999–2001), we have studied the temporal elevation change and the seasonal cycle of the carbon dioxide frost on the southern polar caps. We have produced mapping of the seasonal CO₂ frost thickness variation for seven Ls (30°, 60°, 90°, 120°, 150°, 180°, 210°, 240°, 270° and 330°). It is found that the time variations of the CO₂ frost thickness in these two regions are quite similar. The greatest thickness of the CO₂ frost layer is about 0.76–0.78 m in both places occurs at Ls = 150°.     

A new Mars radiation environment model with visualization.

A new model for the radiation environment to be found on the planet Mars due to Galactic Cosmic Rays (OCR) has been developed at the NASA Langley Research Center. Solar modulated primary particles rescaled for Mars conditions are transported through the Martian atmosphere, with temporal properties modeled with variable timescales, down to the surface, with altitude and backscattering patterns taken into account. The Martian atmosphere has been modeled by using the Mars Global Reference Atmospheric Model--version 2001 (Mars-GRAM 2001). The altitude to compute the atmospheric thickness profile has been determined by using a model for the topography based on the data provided by the Mars Orbiter Laser Altimeter (MOLA) instrument on board the Mars Global Surveyor (MGS) spacecraft. The Mars surface composition has been modeled based on averages over the measurements obtained from orbiting spacecraft and at various landing sites, taking into account the possible volatile inventory (e.g., CO2 ice, H2O ice) along with its time variation throughout the Martian year. Particle transport has been performed with the HZETRN heavy ion code. The Mars Radiation Environment Model has been made available worldwide through the Space Ionizing Radiation Effects and Shielding Tools (SIREST) website, a project of NASA Langley Research Center.     

Global MGS TES data and Mars-GRAM validation

Mars Global Reference Atmospheric Model (Mars-GRAM 2001) is an engineering-level Mars atmosphere model widely used for many Mars mission applications. From 0 to 80 km, it is based on NASA Ames Mars General Circulation Model (MGCM), while above 80 km it is based on University of Michigan Mars Thermospheric General Circulation Model. Mars-GRAM 2001 and MGCM use surface topography from Mars Global Surveyor Mars Orbiter Laser Altimeter (MOLA). Validation studies are described comparing Mars-GRAM with a global summary data set of Mars Global Surveyor Thermal Emission Spectrometer (TES) data. TES averages and standard deviations were assembled from binned TES data which covered surface to ∼40 km, over more than a full Mars year (February 1999–June 2001, just before start of a Mars global dust storm). TES data were binned in 10° × 10° latitude–longitude bins (36 longitude bins, centered at 5°–355°, by 18 latitude bins, centered at −85° to +85°), and 12 seasonal bins (based on 30° increments of L_s angle). Bin averages and standard deviations were assembled at 23 data levels (temperature at 21 pressure levels, plus surface temperature and surface pressure). Two time-of-day bins were used: local time near 2 or 14 h. Two dust optical depth bins were used: infrared optical depth, either less than or greater than 0.25 (which corresponds to visible optical depth less than or greater than about 0.5). For interests in aerocapture and precision entry and landing, comparisons focused on atmospheric density. TES densities versus height were computed from TES temperature versus pressure, using assumptions of perfect gas law and hydrostatics. Mars-GRAM validation studies used density ratio (TES/Mars-GRAM) evaluated at data bin center points in space and time. Observed average TES/Mars-GRAM density ratios were generally 1 ± 0.05, except at high altitudes (15–30 km, depending on season) and high latitudes (>45°N), or at most altitudes in the southern hemisphere at L_s ∼ 90° and 180°. Compared to TES averages for a given latitude and season, TES data had average density standard deviation about the mean of ∼2.5% for all data, or ∼1–4%, depending on time of day and dust optical depth. Average standard deviation of TES/Mars-GRAM density ratio was 8.9% for local time 2 h and 7.1% for local time 14 h. Thus standard deviation of observed TES/Mars-GRAM density ratio, evaluated at matching positions and times, is about three times the standard deviation of TES data about the TES mean value at a given position and season.     

Martian cloud systems: Current knowledge and future observations

In this paper we summarise the current understanding of Martian condensate and dust clouds. The paper is particularly concerned with the spatial, temporal and seasonal characteristics of the clouds. The condensate clouds are composed of water and ice particles and occasionally CO₂ particles. Dust clouds are composed of material from the surface and redistributed over the planet through the weather systems. The apparent lack of annual reproductivity of these dust storms forms a major unresolved problem. We discuss in this paper the types of observations needed in future space missions, in particular the requirements for the NASA Mars Geochemical Climatology Orbiter Mission planned for the end of this decade.     

Evolution of the Martian water cycle.

The current Martian water cycle is extremely asymmetric, with large amounts of vapor subliming off a permanent north polar water ice cap in northern summer, but with no apparent major source of water vapor in the southern hemisphere. Detailed simulations of this process with a three-dimensional circulation model indicate that the summertime interhemispheric exchange (Hadley cell) is very much stronger than transport by eddies in other seasons. As a result, water ice would be distributed globally were it not for the buffering action of regolith soil adsorption which limits the net flux of water vapor off the north polar cap to amounts that are insignificant even on the scale of thousands of years. It has been suggested that the polar layered deposits are the result of exchange on these long time scales, driven by changes in Martian orbital parameters. We therefore are conducting simulations to test the effect of varied orbital parameters on the Martian water cycle. We find that when the perihelion summer pole is charged with a polar water ice cap, large quantities of water are quickly transfered to the aphelion summer pole, setting up an annual cycle that resembles the present one. Thus, the adsorptivity of the Martian regolith may be in the narrow range where it can limit net transport from the aphelion but not the perihelion pole.     

Kinetic temperature and carbon dioxide from broadband infrared limb emission measurements taken from the TIMED/SABER instrument

The Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) experiment is one of four instruments on NASA’s Thermosphere–Ionosphere–Energetics and Dynamics (TIMED) satellite. SABER measures broadband infrared limb emission and derives vertical profiles of kinetic temperature (Tk) from the lower stratosphere to approximately 120 km, and vertical profiles of carbon dioxide (CO₂) volume mixing ratio (vmr) from approximately 70 km to 120 km. In this paper we report on SABER Tk/CO₂ data in the mesosphere and lower thermosphere (MLT) region from the version 1.06 dataset. The continuous SABER measurements provide an excellent dataset to understand the evolution and mechanisms responsible for the global two-level structure of the mesopause altitude. SABER MLT Tk comparisons with ground-based sodium lidar and rocket falling sphere Tk measurements are generally in good agreement. However, SABER CO₂ data differs significantly from TIME-GCM model simulations. Indirect CO₂ validation through SABER-lidar MLT Tk comparisons and SABER-radiation transfer comparisons of nighttime 4.3 μm limb emission suggest the SABER-derived CO₂ data is a better representation of the true atmospheric MLT CO₂ abundance compared to model simulations of CO₂ vmr.     

Optical properties of dust and the opacity of the Martian atmosphere

Particulate component of the Mars atmosphere composed by micron-sized products of soil weathering and water ice clouds strongly affects the current climate of the planet. In the absence of a dust storm so-called permanent dust haze with τ ≈ 0.2 in the atmosphere of Mars determines its thermal structure. Dust loading varies substantially with the season and geographic location, and only the data of mapping instruments are adequate to characterize it, such as TES/MGS and IRTM/Viking. In spite of vast domain of collected data, no model is now capable to explain all observed spectral features of dust aerosol. Several mineralogical and microphysical models of the atmospheric dust have been proposed but they cannot explain the pronounced systematic differences between the IR data (τ = 0.05–0.2) and measurements from the surface (Viking landers, Pathfinder) which give the typical “clear” optical depth of τ ≈ 0.5 from one side, and ground-based observations in the UV–visible range showing much more transparent atmosphere, on the other side. Also the relationship between τ₉ and the visible optical depth is not well constrained experimentally so far. Future focused measurements are therefore necessary to study Martian aerosol.     

Spectroscopic observation of Mars

Visible and near-infrared reflectance spectroscopy has proven a powerful tool for exploring the geology of Mars. Most of this data has been obtained from Earth, but the technique is ideally suited to orbital application, as proposed for the U.S. Mars Geoscience/Climatology Orbiter mission. Spectral reflectance in the near-UV and visible is highly diagnostic of ferric-iron mineralogy, and has shown that Fe³⁺ in the ubiquitous bright dust and soil is amorphous or poorly-crystalline. Other iron-oxide minerals, indicative of other modes or episodes of crustal alteration, may be found in spatially localized deposits. Clay minerals (hydroxylated silicates) have diagnostic vibrational absorptions throughout the near-infrared. While some form of bound water and/or OH has been known on Mars for many years, a new result presented here is the identification of structural OH in a dilute or poorly crystalline magnesian clay. Salts such as carbonates, sulfates, and nitrates have not yet been detected in martian soils but have diagnostic spectral features in the 3- to 4-μm region, best suited to Mars-orbital observation. Analysis of reflectance spectra of low-albedo regions is a primary source of evidence for a basaltic or ultramafic crust, with identification of abundant clinopyroxene and possible detection of other mafic minerals. The distinctive near-infrared spectral shape of dark regions indicates that the dark materials commonly consist of relatively unaltered rocks or rock fragments very thinly coated by (or mixed with) bright oxidized material similar to the global dust. Visible and near-infrared reflectance spectroscopy is also a sensitive technique for detecting and analyzing water ice, as has been demonstrated on Mars by observations of the north polar cap.     

Cloud optical thickness feedbacks in the CO2 climate problem

A radiative-convective equilibrium model is developed and applied to study cloud optical thickness feedbacks in the CO₂ climate problem. The basic hypothesis is that in the warmer and moister CO₂-rich atmosphere, cloud liquid water content will generally be larger than at present, so that cloud optical thickness will be larger too. For clouds other than thin cirrus, the result is to increase the albedo more than to increase the greenhouse effect. Thus the sign of the feedback is negative: cloud optical properties alter in such a way as to reduce the surface and tropospheric warming caused by the addition of CO₂. This negative feedback can be substantial. When observational estimates of the temperature dependence of cloud liquid water content are employed in the model, the surface temperature change due to doubling CO₂ is reduced by about one half.     

Predicting the effects of gas diffusivity on photosynthesis and transpiration of plants grown under hypobaria

As part of a Bio-regenerative Life Support System (BLSS) for long-term space missions, plants will likely be grown at reduced pressure. This low pressure will minimize structural requirements for growth chambers on missions to the Moon or Mars. However, at reduced pressures the diffusivity of gases increases. This will affect the rates at which CO₂ is assimilated and water is transpired through stomata. To understand quantitatively the possible effects of reduced pressure on plant growth, CO₂ and H₂O transport were calculated for atmospheres of various total pressures (101, 66, 33, 22, 11 kPa) and CO₂ concentrations (0.04, 0.1 and 0.18 kPa). The diffusivity of a gas is inversely proportional to total pressure and shows dramatic increases at pressures below 33 kPa (1/3 atm). A mathematical relationship based on the principle of thermodynamics was applied to low pressure conditions and can be used for calculating the transpiration and photosynthesis of plants grown in hypobaria. At 33 kPa total pressure, the stomatal conductance increases by a factor of three with the boundary layer conductance increasing by a factor of ∼1.7, since the leaf conductance is a function of both stomatal and the boundary layer conductance, the overall conductance will increase resulting in significantly higher levels of transpiration as the pressure drops. The conductance of gases is also regulated by stomatal aperture in an inverse relationship. The higher CO₂ concentration inside the leaf air space during low pressure treatments may result in higher CO₂ assimilation and partial stomata closure, resulting in a decrease in transpiration rate. The results of this analysis offer guidelines for experiments in pressure and high CO₂ environments to establish ideal conditions for minimizing transpiration and maximizing the plant biomass yield in BLSS.     

火星尘埃与探测

火星表面尘埃与太阳辐射、热辐射的相互作用直接影响火星大气的结构、热平衡和动力学过程,并会产生改变火星表面反照率和火星地貌的长期效应.火星尘埃环境还对登陆于火星表面的着陆器能源系统和光学载荷等系统构成影响.为此需开展火星大气尘埃的直接就位探测.在介绍了火星的尘埃特性与主要探测方法基础上,提出了采用微质量计技术开展火星表面尘埃就位探测的综合探测器方案.探测器包含3种传感器.尘埃累积传感器通过设置其敏感晶体表面朝上,可以探测火星表面尘埃的沉积质量与速率;荷电尘埃传感器通过加置不同极性的偏置电压,可以探测荷正电尘埃和荷负电尘埃的累积特性;磁尘传感器通过在敏感晶体后加设小型永久磁铁,可以探测磁性尘埃的累积特性.传感器感测质量范围为10^-11~10^-4g.火星尘埃综合探测器可应用于未来的火星着陆探测计划.     

Physical implications of discrepancy between summer and winter PC indices observed in the course of magnetospheric substorms

The PC index based on a statistically justified relationship between the polar cap magnetic activity and the interplanetary electric field E_KL has been derived as a value standardized for the E_KL intensity regardless of season, UT and hemisphere. As a result, the summer and winter PC indices are consistent with one another under ordinary conditions. Discrepancies between the summer and winter PC indices arising in the course of magnetospheric substorms are analyzed in this paper. It is argued that the channel of enhanced conductivity, formed in the auroral oval owing to intense auroral particle precipitation, strongly improves the conditions for closure of the Region 1 field-aligned currents in the winter dark polar region but only trivially affects the conditions of the Region 1 FAC closure in the summer sunlit ionosphere. Since the coefficients describing the relationship between E_KL and the polar cap magnetic activity were derived for statistically justified (i.e., mean) conditions, their application to such abnormal situation, as intense field-aligned currents in the winter dark polar region, leads to overestimation of the winter PC index. The summer and winter PC indices level off as soon as the intense auroral particle precipitation terminates and the auroral ionosphere in the winter and summer polar caps returns to the ordinary (statistically justified) state.     

Thermally evolved gas analysis (TEGA) of hyperarid soils doped with microorganisms from the Atacama Desert in southern Peru: Implications for the Phoenix mission

TEGA, one of several instruments on board of the Phoenix Lander, performed differential scanning calorimetry and evolved gas analysis of soil samples and ice, collected from the surface and subsurface at a northern landing site on Mars. TEGA is a combination of a high temperature furnace and a mass spectrometer (MS) that was used to analyze samples delivered to the instrument via a robotic arm. The samples were heated at a programmed ramp rate up to 1000 °C. The power required for heating can be carefully and continuously monitored (scanning calorimetry). The evolved gases generated during the process can be analyzed with the evolved gas analyzer (a magnetic sector mass spectrometer) in order to determine the composition of gases released as a function of temperature. Our laboratory has developed a sample characterization method using a pyrolyzer integrated to a quadrupole mass spectrometer to support the interpretations of TEGA data. Here we examine the evolved gas properties of six types of hyperarid soils from the Pampas de La Joya in southern Peru (a possible analog to Mars), to which we have added with microorganisms (Salmonella typhimurium, Micrococcus luteus, and Candida albicans) in order to investigate the effect of the soil matrix on the TEGA response. Between 20 and 40 mg of soil, with or without ∼5 mg of lyophilized microorganism biomass (dry weight), were placed in the pyrolyzer and heated from room temperature to 1200 °C in 1 h at a heating rate of 20 °C/min. The volatiles released were transferred to a MS using helium as a carrier gas. The quadrupole MS was ran in scan mode from 10 to 200 m/z. In addition, ∼20 mg of each microorganism without a soil matrix were analyzed. As expected, there were significant differences in the gases released from microorganism samples with or without a soil matrix, under similar heating conditions. Furthermore, samples from the most arid environments had significant differences compared with less arid soils. Organic carbon released in the form of CO₂ (ion 44 m/z) from microorganisms evolved at temperatures of ∼326.0 ± 19.5 °C, showing characteristic patterns for each one. Others ions such as 41, 78 and 91 m/z were also found. Interestingly, during the thermal process, the release of CO₂ increased and ions previously found disappeared, demonstrating a high-oxidant activity in the soil matrix when it was subjected to high temperature. Finally, samples of soil show CO₂ evolved up to 650 °C consistent with thermal decomposition of carbonates. These results indicate that organics mixed with these hyperarid soils are oxidized to CO₂. Our results suggest the existence of at least two types of oxidants in these soils, a thermolabile oxidant which is highly oxidative and other thermostable oxidant which has a minor oxidative activity and that survives the heat-treatment. Furthermore, we find that the interaction of biomass added to soil samples gives a different set of breakdown gases than organics resident in the soil. The nature of oxidant(s) present in the soils from Pampas de La Joya is still unknown.     

Aspects related to variability of radiative cooling by NO in lower thermosphere,TEC and O/N2 correlation,and diffusion of NO into mesosphere during the Halloween storms

Nitric Oxide is a very important trace species which plays a significant role acting as a natural thermostat in Earth’s thermosphere during strong geomagnetic activity. In this paper, we present various aspects related to the variation in the NO Infrared radiative flux (IRF) exiting the thermosphere by utilizing the TIMED/SABER (Thermosphere Ionosphere Mesosphere Energetics and Dynamics/ Sounding of the Atmosphere using Broadband Emission Radiometry) observational data during the Halloween storm which occurred in late October 2003. The Halloween storm comprised of three intense-geomagnetic storms. The variability of NO infrared flux during these storm events and its connection to the strength of the geomagnetic storms were found to be different in contrast to similar super storms. The connection between the quantum of energy outflux from the upper atmosphere into space in terms of NO IRF and the duration of storms is established. The NO radiative cooling, and the closely correlated depletion in O/N₂ ratio are controlled by the Joule heating intensity (proxied by AE-index). The collisional excitation rate of NO, calculated using the modelled datasets of WACCM-X (Whole Atmosphere Community Climate Model with thermosphere and ionosphere extension), correlates well with the observed pattern of radiative emission by NO. Observational datasets from TIMED/GUVI (Global Ultra-Violet Imager) and MIT Haystack observatory madrigal GNSS (Global navigation satellite system) total electron content (TEC) database shows that the TEC and O/N₂ enhancement in low-mid northern hemispheric latitudes are mainly controlled by the z-component of Interplanetary magnetic field (IMF-B_z). The penetration of eastward electric field during the storm events is found to be responsible for the overall enhancement of TEC. The contribution of enhanced day-side TEC in observed variation of O/N₂ ratio by GUVI is also reported. It is also seen that during substorms related events the night-time polar region experiences more cooling due to NO than the daytime polar region. The connections between the mid- and low-latitude enhancement in NO IRF with the propagation of LSTIDs (Large-scale traveling ionospheric disturbances) in combination with the O/N₂ variability, and the altitudinal variation in NO flux with the progression of the storm is also investigated. This study presents the evidence on the role of diffusion processes in the large scale enhancement of NO in the mesospheric altitudes.     

Longitudinal distribution of thermospheric densities and ionization rates in the upper atmosphere of Mars at mid-latitude using MGS ACC data

The Accelerometer Experiment (ACC) onboard Mars Global Surveyor (MGS) measured 1600 density profiles in the upper atmosphere of Mars during aerobraking. These measurements reveal large-scale and small-scale structure in the thermosphere of Mars. Here, the measurements of mass density for 115 orbits (#P0670–P0789) from November 1 to 30, 1998, under spring equinox and medium solar activity conditions (average F_10.7 ∼ 137) during phase 2 of the aerobraking in the thermosphere of Mars at different altitudes and longitudes are presented for northern mid-latitude (17–42°N) in the dayside atmosphere using ACC onboard MGS. From these mass densities, the neutral densities of different gases are derived from their mixing ratios. Using these neutral densities, the longitudinal distribution of photoionization rates and photoelectron impact ionization rates are calculated at wavelength range 1–102.57 nm due to EUV and soft X-ray radiation under photochemical controlled region using Analytical Yield Spectrum approach (AYS). These conditions are appropriate for MGS Phase 2 aerobraking period from which the accelerometer data is used. Under the photochemical equilibrium condition, the electron density near the peak varies as the square root of the total peak ionization rate. Using this fact, an attempt is being made to estimate the mean primary and secondary peak electron density by averaging the longitudinal variations of total peak ionization rates in the northern mid-latitude (17–42°N) ionosphere of Mars, as there is no radio science measurement at this latitude region by MGS.