Positive ion composition and electron density in a combined auroral and NLC event

The positive ion composition and electron density were measured in the lower ionosphere above Kiruna in salvo A of CAMP (Cold Arctic Mesopause Project). The CAMP/P (S37/P) payload carrying a magnetic ion spectrometer, positive ion and electron probes, and propagation experiments was launched on 3 August 1982 2332 UT during extended Noctilucent Clouds (NLC) and auroral activities over Kiruna. The measured electron density was 5×10³cm^?3 at 80 km and 2.5×10⁵cm^?3 at 90 km. The increase of ion and electron densities in the D- and E-region during twilight was caused by precipitating auroral particles. The height distribution of the positive ions measured by the mass spectrometer in the mass range 19–280 amu is different from a winter flight with similar auroral conditions. Below 85.5 km proton hydrates H⁺(H₂O)₃ ? H⁺(H₂O)₈ were the dominant ions. The heaviest proton hydrates H⁺(H₂O)₇ and H⁺(H₂O)₈ were most abundant at 82–85.5 km, the altitude of visible NLC. Above 85.5 km O₂⁺ and NO⁺ became dominant. A small metal ion layer was observed between 90.5–93 km with a maximum ion density of 10% of the total positive ion density at 91 km altitude. The metal ion density disappeared within about a km below 90.5 km.     

Mass spectrometric measurements of stratospheric ions

Recent in situ measurements with balloon borne quadrupole mass spectrometers, between 20 and 45 km altitude, are reviewed and discussed.The major stratospheric positive ions observed are proton hydrates [H⁺(H₂O)_n] and non proton hydrates of the form H⁺X_m(H₂O)₂. The data analysis allows a derivation of the vertical mixing ratio profile of X (most probably CH₃CN), which is compared with recent model calculations. From negative ion composition data, showing the presence of NO₃^? and HSO₄^? cluster ions, the density of sulfuric acid in the stratosphere is deduced. The implications of these findings on our understanding of the sulfur chemistry is briefly treated.Finally some other aspects such as contamination, cluster break up and the use of stratospheric ion mass spectra for determination of thermochemical data and other minor constituents are discussed.     

Temporal and spatial variations observed in the ionospheric composition of Venus: Implications for empirical modelling

In situ measurements of the thermal ion composition of the ionosphere of Venus have been obtained for a period of two Venus years from the Bennett rf ion mass spectrometer on the Pioneer Venus Orbiter. Ion measurements within an altitude interval of 160 to 300 kilometers, corresponding to an overall latitude interval of about ?4° to 34°N, are assembled from the interval December 1978 to March 1980. This time interval corresponds to two revolutions of Venus about the Sun, designated as two “diurnal cycles”. The distributions of several ion species in this data base have been sorted to identify temporal and spatial variations, and to determine the feasibility of an analytical representation of the experimental results. The first results from the sorting of several prominent ions including O⁺, O₂⁺, and H⁺ and several minor ions including CO₂⁺, C⁺, and H₂⁺ reveal significant diurnal variations, with superimposed modulation associated with solar activity and solar wind variations. The diurnal variation consists of strong day to night contrast in the ion concentrations, with differences of one to two orders of magnitude, depending upon ion mass and altitude. The concentrations of O₂⁺, O⁺, CO₂⁺ and C⁺ peak throughout the dayside decreasing sharply at the terminators to nightside levels, lower by one to two orders of magnitude relative to the dayside. The diurnal variations of the light ions H⁺ and H₂⁺ peak during the night, exhibiting asymmetric nightside bulges favoring the pre-dawn sector, near 0400 solar hour angle. Superimposed upon the diurnal distributions are modulation signatures which correlate well with modulation in the F_10.7 index, indicating a strong influence of solar variability on the ion production and distribution. The influence of solar wind perturbations upon the ion distributions are also indicated, by a significant increase in the scatter of the observations with increasing altitude as higher altitudes, approaching 300 kilometers, are sampled. Together, these temporal and spatial variations make the task of modelling the ionosphere of Venus both very interesting and challenging.     

Mesospheric H2O and H2O2 densities inferred from in situ positive ion composition measurement

The measurements of positive ion composition in the high latitude D-region have revealed an excess of 34⁺ under distrubed conditions which has been interpreted as H₂O₂⁺. At the same altitude range near the transition height oxonium ions were measured as well. This paper presents a new model for the production and loss of oxonium ions with their production from H₂O₂⁺ + H₂O → H₃O⁺ + HO₂ and their loss by attachment of N₂ and/or CO₂. A reaction constant of 8.5×10^?28 (300/T)⁴ cm⁶s^?1 has been obtained for the three body attachment H₃O⁺ + CO₂ + M → H₃O⁺.CO₂ + M from the measured density profile of 63⁺ in flight 18.1020. Mesospheric H₂O and H₂O₂ densities are inferred from measurements of four high latitude ion compositions based on the oxonium model. The mixing ratios of hydrogen peroxide are up to two orders of magnitude higher compared to previous model calculations. In order to explain the missing production of odd hydrogen, we consider larger O(¹D) densities, surface reactions of O(³P) on particles, and cathalytic photodissociation of water vapor on aerosol particles.     

Model calculations of the dayside ionosphere of Venus

Model calculations of the dayside ionosphere of Venus are presented. The coupled continuity and momentum equations were solved for O₂⁺, O⁺, CO₂⁺, C⁺, N⁺, He⁺, and H⁺ density distributions, which are compared with measurements from the Pioneer Venus ion mass spectrometer. The agreement between the model results and the measurements is good for some species, such as O⁺, and rather poor for others, such as N⁺, indicating that our understanding of the dayside ion composition of Venus is incomplete. The coupled heat conduction equations for ions and electrons were solved and the calculated temperatures compared with Pioneer Venus measurements. It is shown that fluctuations in the magnetic field have a significant effect on the energy balance of the ionosphere.     

F-Region ion composition modeling

Measurements of the principal ion species of the F₁- and F₂- regions have been used to develop an empirical model of the ion composition for altitudes between 150 and 500 km. The species measured by the S3-1 satellite include N⁺, O⁺, N₂⁺, NO⁺ and O₂⁺. The data were obtained near the minimum of the solar cycle, thus limited information on the ionospheric variation with solar flux is available. However, the range of latitude, altitude, local time and geomagnetic activity does provide a useful basis for modeling the F-region. The ion composition measurements have been used to provide a model for relative ion composition which is compatible with the total ion density from the International Reference Ionosphere model.     

DEMETER and DMSP satellite observations of the disturbed H/O ratio caused by Earth’s seismic activity in the Sumatra area during December 2004

In the present paper, plasma probe data taken from DEMETER and DMSP-F15 satellites were used to study the ion density and temperature disturbances in the morning topside ionosphere, caused by seismic activity at low latitudes. French DEMETER (Detection of Electro-Magnetic Emissions Transmitted from Earthquake Regions) micro-satellite mission had been especially designed to provide global scale observations in the topside ionosphere over seismically active regions. Onboard the DEMETER satellite, the thermal plasma instrument called “Instrument Analyser de Plasma” (IAP) provides ion mass and densities, ion temperature, three component ion drift and ion density irregularities measurements. As a part of “Defense Meteorological Satellite Program”, DMSP-F15 satellite is on orbit operation since 1999. It provides ionospheric plasma diagnostics by means of the “Special Sensor-Ion, Electron and Scintillations” (SSIES-2) instrument. We examined few examples of possible seismic effects in the equatorial ionosphere, probably associated with seismic activity during December month in the area of Sumatra Island, including main shock of giant Sumatra event. It is found that the localized topside ionospheric disturbances appear close to the epicenters of certain earthquakes in the Sumatra region. In two cases, ion H⁺/O⁺ ratio rises more than one hour before the main shock, due to the O⁺ density decrease at the winter side of the geomagnetic equator, with longitudinally closest location to the epicenter of the earthquakes. These anomalous depletions in O⁺ density do exist in all cases of SSIES-2 data. Particularly for Sumatra main event, more than one hour after the main shock, we observe large-scale depletion in O⁺ density northward of the geomagnetic equator at winter side hemisphere. Associated with O⁺ depletion, ion temperature latitudinal profile around the geomagnetic equator shows enhanced asymmetry with minimum at the summer side and maximum in positive Ti deviation from mean value at the winter side. This disturbance lasted for more than three hours, later in time observed at the same place by IAP/DEMETER.     

Ion precipitation into the ionosphere during geomagnetic storms

This review presents numerous recent examples of interesting variations in the composition and intensity of the hot ion flux (10 eV - 15 keV/e) provided by the AUREOL-3 satellite as a function of latitude and local time during periods of magnetic activity. In particular, these results reveal that although H⁺ is the most abundant ion during magnetically quiet periods, the ion composition of hot plasma at ionospheric altitudes is quite variable, and depends strongly on magnetic activity; results obtained during main and recovery phases of several magnetic storms demonstrate clearly (below 15 keV/Q) the great importance of the low altitude ionospheric source (H⁺, O⁺, and to a lesser degree He⁺) particularly at low latitudes (L ～ 3 - 4) where the flux of O⁺ ions becomes very large and even dominates. The results of the AUREOL-3 ion spectrometers establish the fact that upflowing suprathermal ionospheric ions (E_i < 100 eV/e) appear over large regions of the auroral ionosphere, the polar caps, and the polar cusp, as well as in or at the boundary of the plasmasphere during magnetospheric substorms or magnetic storms, and may consequently contribute significantly to the plasma sheet and to the inner storm time ring current. Most of the properties of the storm time ring current found by the GEOS, SCATHA, and ISEE satellites apply to lower altitudes, although the role of the ionospheric and/or plasmaspheric source appears accentuated.     

Global comparison of the model results of GSM TIP with IRI for summer conditions

This paper presents the results of the numerical calculations thermosphere/ionosphere parameters which were executed with using of the Global Self-consistent Model of the Thermosphere, Ionosphere and Protonosphere (GSM TIP)and comparison of these results with empirically-based model IRI-2001. Model GSM TIP was developed in West Department of IZMIRAN and solves self-consistently the time-dependent, 3-D coupled equations of the momentum, energy and continuity for neutral particles (O₂, N₂, O), ions (O⁺, H⁺), molecular ions (M⁺) and electrons and largescale eletric field of the dynamo and magnetospheric origin in the range of height from 80 km to 15 Earth’s radii. The empirically derived IRI model describes the E and F regions of the ionosphere in terms of location, time, solar activity and season. Its output provides a global specification not only of N_e but also on the ion and electron temperatures and the ion composition. These two models represent a unique set of capabilities that reflect major differences in along with a substantial approaches of the first-principles model and global database model for the mapping ionosphere parameters. We focus on global distribution of the N_e, T_i, T_e and TEC for the one moment UT and fixed altitudes: 110 km, h_mF2, 300 km and 1000 km. The calculations were executed with using of GSM TIP and IRI models for August 1999, moderate solar activity and quiet geomagnetic conditions. Results present as the global differences between the IRI and GSM TIP models predictions. The discrepancies between model results are discussed.     

Nightside 135.6 nm emission enhancements of mid/low latitudes during geomagnetic storms as observed by the ionosphere PhotoMeter (IPM) on the Chinese meteorological satellite FY-3D

IPM has detected nightside 135.6 nm emission enhancements over a wide latitude range, from the sub-auroral latitudes to the equatorial regions during geomagnetic storms. Our work, presented in this paper, uses the data of IPM to understand these 135.6 nm emission enhancements during of geomagnetic storms and studies the variations of total electron content (TEC) and the F₂ layer peak electron density (NmF2) in the region of enhanced emissions. Middle and low latitude emission enhancements are presented during several medium storms in 2018. The variations of both the integrated electron content (IEC) derived from the nighttime OI 135.6 nm emission by IPM and TEC from the International GNSS Service (IGS) relative to the daily mean of magnetically quiet days of per each latitude bin (30°≦geographic latitude < 40°, 15°≦geographic latitude < 30°, 0°≦geographic latitude < 15°, ?15°≦geographic latitude < 0°, ?30°≦geographic latitude < -15°, ?40°≦geographic latitude < -30°) are investigated and show that on magnetically storm day, IEC by IPM always increases, while TEC from IGC may increase or decrease. Even if both increase, the increase of IEC is greater than that of TEC. From the comparison of IEC and TEC during magnetic storms, it can be seen that the enhancement of the nighttime 135.6 nm emissions is not entirely due to the ionospheric change. The time of IEC enhancements at each latitude bin is in good agreement, which mainly corresponds to the main phase time of the geomagnetic storm event and lasts until the recovery phase. The available ground-based ionosonde stations provide the values of NmF2 which match the 135.6 nm emissions measured by IPM in space and time. The variations of NmF2 squared can characterize the variations of the OI 135.6 nm emissions caused by O⁺ ions and electrons radiative recombination. The study results show that the OI 135.6 nm emission enhancements caused by O⁺ ions and electrons radiative recombination (where NmF2 squared increases) are obviously a contribution to the measured 135.6 nm emission enhancements by IPM. The contribution accounts for at least one of all contributions to the measured 135.6 nm emission enhancements by IPM. However, where the NmF2 squared provided by ionosonde decrease or change little (where the OI 135.6 nm emissions cause by O⁺ ions and electrons radiative recombination also decrease or change little), the emission enhancements measured by IPM at storm-time appear to come from the contributions of other mechanisms, such as energetic neutral atoms precipitation, or the mutual neutralization emission (O+ + O-→2O + h? (135.6 nm)) which also occupies a certain proportion in 135.6 nm airglow emission at night.     

Hybrid simulations of the O ion escape from Venus: Influence of the solar wind density and the IMF x component

As an initial effort to study the evolution of the Venus atmosphere, the influence of the solar wind density and the interplanetary magnetic field (IMF) x component (the x-axis points from Venus towards the Sun) on the O⁺ ion escape rate from Venus is investigated using a three-dimensional quasi-neutral hybrid (HYB-Venus) model. The HYB-Venus model is first applied to a case of the high-density (100 cm⁻³) solar wind interaction with Venus selected from the Pioneer Venus Orbiter observations to demonstrate its capability for the study. Two sets of simulations with a wide range of solar wind densities and different IMF x components are then performed. It is found that the O⁺ ion escape rate increases with increasing solar wind density. The O⁺ ion escape rate saturates when the solar wind density becomes high (above 100 cm⁻³). The results also suggest that the IMF x component enhances the O⁺ ion escape rate, given a fixed IMF component perpendicular to the x-axis. Finally, the results imply a higher ion loss rate for early-Venus, when solar conditions were dramatically different.     

Circulation of energetic ions of terrestrial origin in the magnetosphere

Energetic ion composition measurements have now been performed from earth orbiting satellites for more than a decade. As early as 1972 we knew that energetic (keV) ions of terrestrial origin represented a non-negligible component of the storm time ring current. We have now assembled a significant body of knowledge concerning energetic ion composition throughout much of the earth's magnetosphere. We know that terrestrial ions are a common component of the hot equatorial magnetospheric plasma in the ring current and the plasma sheet out to ? 23 R_E. During periods of enhanced geomagnetic activity this component may become dominant. There is also clear evidence that the terrestrial component (specifically O⁺) is strongly dependent on solar cycle. Terrestrial ion source, transport, and acceleration regions have been identified in the polar auroral region, over the polar caps, in the magnetospheric boundary layers, and within the magnetotail lobes and plasma sheet boundary layer. Combining our present knowledge of these various magnetospheric ion populations, it is concluded that the primary terrestrial ion circulation pattern associated with enhanced geomagnetic activity involves direct injection from the auroral ion acceleration region into the plasma sheet boundary layer and central plasma sheet. The observed terrestrial component of the magnetospheric boundary layer and magnetotail lobes are inadequate to provide the required influx. They may, however, contribute significantly to the maintenence of the plasma sheet terrestrial ion population, particularly during periods of reduced geomagnetic activity. It is further concluded, on the basis of the relative energy distributions of H⁺ and O⁺ in the plasma sheet, that O⁺ probably contributes significantly to the ring current population at energies inaccessible to present ion composition instrumentation (? 30 keV).     

Positive ion distributions in the morning auroral zone: Local acceleration and drift effects

We report on the typical structure of the large scale ion precipitation in the morning sector of the auroral zone and associated low frequency electromagnetic waves. Data obtained during near radial passes of the AUREOL-3 satellite point to a distinction between two main precipitation regions: 1) In the poleward part of the auroral zone the latitudinal variation of the average energy (or temperature) of the precipitated ions (mainly H⁺) indicate that they are adiabatically accelerated in the outer magnetosphere. This “high energy” (? 3 to > 20 keV) precipitation is usually associated with a low energy (E < 110 eV) upward flowing 0⁺ and H⁺ component, and 2) near the boundary between discrete and diffuse electron aurorae a drastic change in the ion characteristics is observed. The flux of energetic precipitated H⁺ ions is sharply reduced, which suggests the formation of an Alfvén layer. However, intense fluxes of precipitated H⁺, O⁺, and He⁺ ions with energies < 3 keV are observed equatorward of the Alfvén layer, in coincidence with the diffuse aurora and in association with quasi-monochromatic electromagnetic waves with frequencies around the proton gyrofrequency. As the characteristic convection and bounce times of the low energy upward flowing ion component are comparable (τ > 3 hours) we suggest that the precipitation of ionospheric ions inside the diffuse aurora results from convection and corotation of the ions accelerated to suprathermal energies at higher latitudes.     

Solar cycle effect on temporal and spatial variation of topside ion density measured by SROSS C2 and ROCSAT 1 over the Indian longitude sector

We investigated the diurnal, seasonal and latitudinal variations of ion density Ni over the Indian low and equatorial topside ionosphere within 17.5°S to 17.5°N magnetic latitudes by combining the data from SROSS C2 and ROCSAT 1 for the 9 year period from 1995 to 2003 during solar cycle 23. The diurnal maximum density is found in the local noon or in the afternoon hours and the minimum occurs in the pre sunrise hours. The density is higher during the equinoxes as compared to that in the June and December solstice. The local time spread of the daytime maximum ion density increases with increase in solar activity. A north south asymmetry with higher ion density over northern hemisphere in the June solstice and over southern hemisphere in December solstice has been observed in moderate and high solar activity years. The crest to crest distance increases with increase in solar flux. Ion density bears a nonlinear relationship with F_10.7 cm solar flux and EUV flux in general. The density increases linearly with solar flux up to ∼150 sfu (1 sfu = 10⁻²²Wm⁻²Hz⁻¹) and EUV flux up to ∼50 units (10⁹ photons cm⁻² s⁻¹). But beyond this the density saturates. Inverse saturation and linear relationship have been observed in some season or latitude also. Inter-comparison of the three solar activity indices F_10.7 cm flux, EUV flux and F_10.7P (= (F_10.7 + F_10.7A)/2, where F_10.7A is the 81 day running average value of F_10.7) shows that the ion density correlates better with F_10.7P and F_10.7 cm fluxes. The annual average daytime total ion density from 1995 to 2003 follows a hysteresis loop as the solar cycle reverses. The ion density at 500 km over the Indian longitude sector as obtained by the international reference ionosphere is in general lower than the measured densities during moderate and high solar activity years. In low solar activity years the model densities are equal or higher than measured densities. The IRI EIA peaks are symmetric (±10°) in equinox while densities are higher at 10°N in June solstice and at 10°S in the December solstice. The model density follows F_10.7 linearly up to about F_10.7 > ∼150 sfu and then saturates.     

Characterization of the low latitude plasma density irregularities observed using C/NOFS and SCINDA data

Complex electrodynamic processes over the low latitude region often result in post sunset plasma density irregularities which degrade satellite communication and navigation. In order to forecast the density irregularities, their occurrence time, duration and location need to be quantified. Data from the Communication/Navigation Outage Forecasting System (C/NOFS) satellite was used to characterize the low latitude ion density irregularities from 2011 to 2013. This was supported by ground based data from the SCIntillation Network Decision Aid (SCINDA) receivers at Makerere (Geographic coordinate 32.6°E, 0.3°N, and dip latitude ?9.3°N) and Nairobi (Geographic coordinate 36.8°E, ?1.3°N, and dip latitude ?10.8°N). The results show that irregularities in ion density have a daily pattern with peaks from 20:00 to 24:00 Local Time (LT). Scintillation activity at L band and VHF over East Africa peaked in 2011 and 2012 from 20:00 to 24:00 LT, though in many cases scintillation at VHF persisted longer than that at L band. A longitudinal pattern in ion density irregularity occurrence was observed with peaks over 135–180°E and 270–300°E. The likelihood of ion density irregularity occurrence decreased with increasing altitude. Analysis of C/NOFS zonal ion drift velocities showed that the largest nighttime and daytime drifts were in 270–300°E and 300–330°E longitude regions respectively. Zonal irregularity drift velocities over East Africa were for the first time estimated from L-band scintillation indices. The results show that the velocity of plasma density irregularities in 2011 and 2012 varied daily, and hourly in the range of 50–150 m s^?1. The zonal drift velocity estimates from the L-band scintillation indices had good positive correlation with the zonal drift velocities derived from VHF receivers by the spaced receiver technique.     

Quantitative determination of the outgassing water vapor concentrations surrounding space vehicles from ion mass spectrometer measurements

Outgassing from materials as well as deliberate gaseous and liquid releases create contaminant clouds around spacecraft that can degrade both instrumentation and measurements. This paper describes a new method for estimating outgassing water vapor concentrations around space vehicles. Water vapor ions measured in the course of a rocket experiment performed at Eglin AFB, Florida, on December 12, 1980 at 2311 UT are utilized to demonstrate the technique. The H₂O concentration near the payload's surface is calculated using the rate coefficient for the fast charge transfer process, O⁺ + H₂O + H₂O⁺ + O, the source of the observed water vapor ions. It is found that the measured H₂O⁺ ions were produced within 3–4 cm of the sampling plate's surface and that the average H₂O pressure over this distance was relatively constant on ascent at 8 × 10^?6 torr, within a factor two, implying a steady outgassing rate.     

Venus EUV measurements of hydrogen and helium from Venera 11 and Venera 12

Lyman α and 58.4 nm HeI radiations resonantly scattered were observed with EUV spectrophotometers flown on Venera 11 and Venera 12. The altitude distribution of hydrogen was derived by limb observations from 250 km (exobase level) to 50,000 km. In the inner exosphere (up to ? 2,000 km of altitude) the distribution can be described by a classical exospheric distribution with T_C = 275 ± 25 K and n = 4_?2⁺³ × 10⁴ atom. cm^?3 at 250 km. The integrated number density from 250 to 110 km (the level of CO₂ absorption) is 2.1 × 10¹² atom. cm^?2, a factor of 3 to 6 lower than that predicted by aeronomical models. This number density decreases from the morning side to the afternoon side, or alternately from equatorial to polar regions. Above 2,000 km a “hot” hydrogen population dominates, which can be simulated by T = 10³K and n = 10³ atom. cm^?3 at the exobase level.The optical thickness of helium above 141 km (the level of CO₂ absorption for 58.4 nm radiation) was determined to be τ_o = 3, corresponding to a density at 150 km of 1.6 × 10⁶ cm^?3. This is about 3 times less than what was obtained with the Bus Neutral Mass Spectrometer of Pioneer Venus, and about twice less than ONMS measurements, but is in agreement with earlier EUV measurement by Mariner 10 (2 ± 1 × 10⁶ cm^?3).