共查询到18条相似文献,搜索用时 78 毫秒
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采用低压化学气相沉积法( LPCVD)在炭纤维表面制备了SiC涂层,借助扫描电镜、X射线衍射仪和拉曼光谱仪对不同沉积位置SiC涂层的微观形貌和晶体结构进行了表征。 SEM结果表明,沿气流方向,涂层表面逐渐致密和均匀;SiC涂层为多层结构,这种多层结构的形成可能是由于反应中产生的HCl气体吸附在表面反应活性点,从而通过活性点的阻塞机制来阻止SiC晶粒的生长。 XRD结果表明,制备的涂层中存在自由碳,各位置处的SiC晶体在(111)晶面存在择优取向,且沿气流方向(111)晶面的取向性逐渐减弱,(220)和(311)晶面的取向性逐渐增加。拉曼光谱低段频谱(200~600 cm-1)的出现表明CVD涂层中存在一定的缺陷。 相似文献
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根据化学气相沉积(CVD)工艺制备SiC陶瓷涂层的工艺特点和典型异形构件的结构特点,建立了异形构件表面化学气相沉积SiC涂层的数学模型。利用该模型,对CVD法在典型异形表面制备SiC涂层进行了数值计算和分析。计算结果显示,带有斜面的构件对CVD SiC沉积过程有显著影响,在反应器大小允许的情况下,构件放置时,斜面与水平面的夹角越小越好,并尽可能将构件长的一面与水平面平行,这样有利于沉积的涂层均匀。此外,对于带有台阶的构件来说,正放的构件表面浓度大于倒放的构件,而浓度梯度则小于倒放的构件。因此,在实际应用中,应尽量使台阶部分放在气流的下游。上述研究结果对CVD工艺制备SiC涂层的优化具有一定的指导意义。 相似文献
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为减小静止轨道高频率、大口径微波天线热变形,提高天线的指向精度,对国内外天线主反射材料和热控方案进行了分析,发现其材料较一致选用碳纤维蒙皮/碳纤维蜂窝夹层,主反表面涂覆合适吸发比的真空沉积铝(VDA)/Al2O3(SiOx)涂层,一方面保证天线电性能对反射率大于99.8%的需求,另一方面使天线整面在轨温度梯度和波动较小。建立口径5m天线的热仿真模型,分析了三种不同吸发比涂层的天线在不同典型工况下的温度场分布,结果表明采用涂层吸发比0.2/0.2的主反热变形较小。以碳纤维材料为基体,用真空蒸镀沉积的方法在其表面镀制不同厚度的银层和二氧化硅层,制备出吸发比约0.2/0.2的VDA/SiO2热控涂层,可用于形状较复杂的曲面,且涂层的发射率随保护层厚度可调,显著提高了热控设计的灵活性。 相似文献
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为解决铝合金表面液相等离子体电解氧化(PEO)涂层(Y2O3-ZnO-Al2O3)导电性差而导致的静电效应,对其进行表面改性处理。采用原子层沉积(ALD)技术在铝合金表面PEO涂层原位沉积铝掺杂氧化锌(AZO)导电薄膜以提高PEO涂层的导电性。对AZO改性PEO涂层的相组成和表面微观结构进行分析;对不同沉积温度下所得复合涂层的电阻率、载流子浓度和迁移率,以及沉积前后的热控性能、耐腐蚀性进行测量分析。结果表明:AZO导电薄膜均质连续致密地沉积在PEO涂层表面;当沉积温度为150 ℃时,AZO@Y2O3-ZnO-Al2O3复合涂层的电阻率为1.15×10-4 Ω·cm,载流子浓度为1.8×1020 cm-3,太阳吸收比为0.409,发射率为0.892,且抗电化学腐蚀性能良好,能够满足航天器热控涂层在空间环境应用的技术要求。 相似文献
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确定了栅格翼防热涂层结构和制备工艺。涂层结构为:“等离子喷涂铝包镍涂层+等离子喷涂氧化铝涂层+高温耐热胶层”,涂层的制备工艺包括吹砂、底层喷涂、氧化铝喷涂。介绍了高温耐热胶的研制过程和栅格翼防热涂层经受发动机喷流试验的情况。 相似文献
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Ir–Zr co-deposition coatings with 71 at% Zr were deposited on graphite by double glow plasma at 1073–1123 K. The structure and composition of the coatings were confirmed by FE-SEM, XRD, XPS and EDS. The hardness and the elastic modulus of the coatings were estimated by nanoindentation instrument. The adhesion strength between the coating and the substrate was evaluated by a scratch tester. The results showed that the coating was composed of nanocrystalline grains with a size of 80–90 nm compared with 0.5 μm for the pure Ir coating. The fine grains of the coatings might be attributed to the additional Zr element. New phases IrZr and ZrC were formed due to the high content of Zr and high deposition temperature. The hardness and elastic modulus of the coatings were about 7.5 GPa and 388 GPa, respectively. The adhesive force between the coating and the substrate was about 10 N. 相似文献
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界面改性对混杂基C/SiC复合材料性能的影响 总被引:1,自引:0,他引:1
通过界面设计与实验研究,对C/SiC材料进行C/SiC/C多层涂层界面处理,实现了保护纤维和提高复合材料韧性及调节机械性能的多重目的.同时还研究了界面涂层前后纤维表面处理对复合材料性能的影响,结果表明,对增强体进行界面涂层处理和"酸处理",适当强化弱界面,起到了提高复合材料高温强度保留率和增韧的目的,酸处理+CVD-C/SiC/C界面涂层的C/SiC 复合材料的高温强度保留率达到90%;进行了C/SiC/C界面涂层的C/SiC 复合材料的断裂韧性高达20.72 MPa·m1/2,较未进行界面涂层的C/SiC 复合材料的断裂韧性提高了31.8%. 相似文献
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Four layers, S1-S4, containing sand-sized spherical particles formed as a result of large meteorite impacts, occur in 3.47-3.24 Ga rocks of the Barberton Greenstone Belt, South Africa. Ir levels in S3 and S4 locally equal or exceed chondritic values but in other sections are at or only slightly above background. Most spherules are inferred to have formed by condensation of impact-produced rock vapor clouds, although some may represent ballistically ejected liquid droplets. Extreme Ir abundances and heterogeneity may reflect element fractionation during spherule formation, hydraulic fractionation during deposition, and/or diagenetic and metasomatic processes. Deposition of S1, S2, and S3 was widely influenced by waves and/or currents interpreted to represent impact-generated tsunamis, and S1 and S2 show multiple graded layers indicating the passage of two or more wave trains. These tsunamis may have promoted mixing within a globally stratified ocean, enriching surface waters in nutrients for biological communities. S2 and S3 mark the transition from the 300-million-year-long Onverwacht stage of predominantly basaltic and komatiitic volcanism to the late orogenic stage of greenstone belt evolution, suggesting that regional and possibly global tectonic reorganization resulted from these large impacts. These beds provide the oldest known direct record of terrestrial impacts and an opportunity to explore their influence on early life, crust, ocean, and atmosphere. The apparent presence of impact clusters at 3.26-3.24 Ga and approximately 2.65-2.5 Ga suggests either spikes in impact rates during the Archean or that the entire Archean was characterized by terrestrial impact rates above those currently estimated from the lunar cratering record. 相似文献