Origin,age, and composition of meteorites

This paper attempts to bring together and evaluate all significant evidence on the origin of meteorites.The iron meteorites seem to have formed at low pressures. Laboratory evidence shows that the absence of a Widmanstätten pattern in meteorites with > 16% Ni cannot be attributed to high pressures, but to supercooling or an unusually fast cooling rate for these meteorites, which prevented the development of a pattern. The presence of tridymite in the Steinbach siderophyre provides further, direct proof that the Widmanstätten pattern can form at pressures less than 3 kb. Neither diamond, nor cliftonite, nor cohenite are reliable pressure indicators in meteorites. Diamonds were formed by shock while cliftonite may have been derived from a cubic carbide such as Fe₄C. Cohenite is apparently stabilized by kinetic rather than thermodynamic factors. Several lines of evidence suggest that the irons come from more than one parent body, perhaps as many as four.The frequency of pallasites is perfectly consistent with an origin in the transition zone between core and mantle of the parent body. Hybrid meteorites such as Brenham are not necessarily derived from the metal-silicate interface, but probably resulted from dendrite growth in the solidifying melt.Ordinary chondrites definitely are equilibrium assemblages rather than chance conglomerates. According to the best available evidence, Prior's rules seem to be valid. The metal particles in chondrites differentiated into kamacite and taenite in their present location, rather than in a remote earlier environment. Trace element abundances in ordinary and carbonaceous chondrites suggest that these meteorites accreted from two types of matter: an undepleted fraction that separated from its complement of gases at low temperatures, and a depleted fraction that lost its gases at high temperatures. These two fractions of primitive meteoritic matter are tentatively identified with the matrix and chondrules-plus-metal, respectively. New restrictive limits are placed on the iron-silicate fractionation in chondrites. No direct evolutionary path exists that connects the currently accepted solar abundances of Fe and Ni and the observed Fe/Si and Ni/Si ratios in chondrites. Apparently the solar abundance of iron is in error. The iron-silicate fractionation seems to have occurred while chondritic matter was in a more strongly reduced state than its present one.The U-He and K-Ar ages of hypersthene chondrites are systematically shorter than those of bronzite chondrites. Short ages are correlated with shock effects, and it seems that the hypersthene chondrites suffered reheating and partial-to-complete outgassing 0.4 AE ago. The cosmic-ray exposure ages of all classes of meteorites cluster distinctly, indicating that the meteorites were produced in a few discrete major collisions rather than by a quasi-continuum of smaller ones. The dates of the principal breakups are: irons, 0.6 and 0.9 AE; aubrites, 45 m.y.; bronzite chondrites, 4 m.y.; hypersthene chondrites, 0.025, 3, 7–13, and 16–31 m.y. All four clusters of hypersthene chondrites show evidence of severe outgassing 0.4 AE ago, which implies that most or all hypersthene chondrites come from the same parent body.As already noted by Signer and Suess, two distinct types of primordial gas occur in meteorites. Differentiated meteorites always contain unfractionated gas, while relatively undifferentiated meteorites contain fractionated gas. The former component is invariably associated with shock effects, and seems to have been derived from the solar wind. The latter component is correlated with other volatiles and seems to be a truly primitive constituent of meteoritic matter. Isotopic anomalies in the fractionated gas suggest that meteoritic matter was irradiated with 10¹⁷ protons/cm² at a very early stage of its history.There is very little doubt that most, if not all, meteorites come from the asteroid belt rather than from the moon. The orbits and geocentric velocities of stony meteorites resemble those of the Apollo asteroids (most of which are former members of the asteroid belt that have strayed into terrestrial space), but disagree strongly with the calculated orbits and velocities for lunar ejecta. Öpik's conclusions about the difficulty of accelerating lunar debris to escape velocity represent a further argument against a lunar origin of stony meteorites.The most likely parent bodies of the meteorites are the 34 asteroids which cross the orbit of Mars. Collisional debris from these objects will remain in Mars-crossing orbits, and perturbations by Mars will inject some fraction of this material into terrestrial space. Most of the Mars asteroids, comprising 98% of the mass and 92% of the cross-section, belong to three Hirayama families (Phocaea, Desiderata, and Aethra), and an additional, previously unrecognized family. These families were apparently produced by disruption of parent asteroids ca. 104, 105, and 46 km in diameter. The size distribution and light curves of asteroids indicate that the larger asteroids are original accretions, rather than collision fragments. There is no reason to believe that the meteorites ever resided in bodies larger than Ceres (d = 770 km).Various theories on the origin of the meteorites are critically reviewed in the light of the preceding evidence. Wood's theory, which postulates a high-temperature and a low-temperature variety of primordial matter, is in best accord with the evidence. Apparently the asteroids accreted from varying proportions of these two types of material, and were then heated by extinct radioactivity produced in the early irradiation.     

Water Reservoirs in Small Planetary Bodies: Meteorites,Asteroids, and Comets

Asteroids and comets are the remnants of the swarm of planetesimals from which the planets ultimately formed, and they retain records of processes that operated prior to and during planet formation. They are also likely the sources of most of the water and other volatiles accreted by Earth. In this review, we discuss the nature and probable origins of asteroids and comets based on data from remote observations, in situ measurements by spacecraft, and laboratory analyses of meteorites derived from asteroids. The asteroidal parent bodies of meteorites formed \(\leq 4\) Ma after Solar System formation while there was still a gas disk present. It seems increasingly likely that the parent bodies of meteorites spectroscopically linked with the E-, S-, M- and V-type asteroids formed sunward of Jupiter’s orbit, while those associated with C- and, possibly, D-type asteroids formed further out, beyond Jupiter but probably not beyond Saturn’s orbit. Comets formed further from the Sun than any of the meteorite parent bodies, and retain much higher abundances of interstellar material. CI and CM group meteorites are probably related to the most common C-type asteroids, and based on isotopic evidence they, rather than comets, are the most likely sources of the H and N accreted by the terrestrial planets. However, comets may have been major sources of the noble gases accreted by Earth and Venus. Possible constraints that these observations can place on models of giant planet formation and migration are explored.     

Paleomagnetic Records of Meteorites and Early Planetesimal Differentiation

The large-scale compositional structures of planets are primarily established during early global differentiation. Advances in analytical geochemistry, the increasing diversity of extraterrestrial samples, and new paleomagnetic data are driving major changes in our understanding of the nature and timing of these early melting processes. In particular, paleomagnetic studies of chondritic and small-body achondritic meteorites have revealed a diversity of magnetic field records. New, more sensitive and highly automated paleomagnetic instrumentation and an improved understanding of meteorite magnetic properties and the effects of shock, weathering, and other secondary processes are permitting primary and secondary magnetization components to be distinguished with increasing confidence. New constraints on the post-accretional histories of meteorite parent bodies now suggest that, contrary to early expectations, few if any meteorites have been definitively shown to retain records of early solar and protoplanetary nebula magnetic fields. However, recent studies of pristine samples coupled with new theoretical insights into the possibility of dynamo generation on small bodies indicate that some meteorites retain records of internally generated fields. These results indicate that some planetesimals formed metallic cores and early dynamos within just a few million years of solar system formation.     

Solar cosmic rays

The first observations of solar cosmic rays were made simultaneously by many investigators at worldwide cosmic-ray stations in the periods of powerful chromospheric flares on February 28 and March 7, 1942. The discovery of these and the investigation of cosmic-ray solar-daily variations with maximum time near noon led some authors (Richtmyer and Teller, 1948; Alfvén, 1949, 1950) to a model of apparent cosmic-ray solar origin. We present here the results of the properties of solar cosmic rays from ground events (experimental and theoretical investigations). We also discuss important information from solar experimental data relating to these ground events observed in September and October 1989 and May 1990. Some experimental evidence of acceleration processes in associated phenomena with flares and long-term (solar cycle) variation of the average flux of solar cosmic rays is discussed as also cornal and interplanetary propagation, and that in the terrestrial magnetosphere. Note that the energy spectrum of solar cosmic rays varied very strongly from one flare to another. What are the causes of these phenomena? What is the nature of chemical and isotopic contents of solar cosmic rays? How can its changes occur in the energy spectrum and chemical contents of solar cosmic rays in the process of propagation? Is it possible to recalculate these parameters to the source? What makes solar cosmic rays rich in heavy nucleus and³He? The important data about electrons, positrons, gamma-quanta and neutrons from flares will be discussed in a subsequent paper (Dorman and Venkatesan, 1992). The question is: What main acceleration mechanism of solar flare and associated phenomena are reliable? These problems are connected with the more general problem on solar flare origin and its energetics. In Dorman and Venkatesan (1993) we will consider these problems as well as the problem of prediction of radiation hazard from solar cosmic rays (not only in space, but also in the Earth's atmosphere too).     

The Solar Noble Gas Record in Lunar Samples and Meteorites

Lunar soil and certain meteorites contain noble gases trapped from the solar wind at various times in the past. The progress in the last decade to decipher these precious archives of solar history is reviewed. The samples appear to contain two solar noble gas components with different isotopic composition. The solar wind component resides very close to grain surfaces and its isotopic composition is identical to that of present-day solar wind. Experimental evidence seems by now overwhelming that somewhat deeper inside the grains there exists a second, isotopically heavier component. To explain the origin of this component remains a challenge, because it is much too abundant to be readily reconciled with the known present day flux of solar particles with energies above those of the solar wind. The isotopic composition of solar wind noble gases may have changed slightly over the past few Ga, but such a change is not firmly established. The upper limit of ~5% per Ga for a secular increase of the 3He/4He ratio sets stringent limits on the amount of He that may have been brought from the solar interior to the surface (cf. Bochsler, 1992). Relative abundances of He, Ne, and Ar in present-day solar wind are the same as the long term average recorded in metallic Fe grains in meteorites within error limits of some 15-20%. Xe, and to a lesser extent Kr, are enriched in the solar wind similar to elements with a first ionisation potential < 10 eV, although Kr and Xe have higher FIPs. This can be explained if the ionisation time governs the FIP effect (Geiss and Bochsler, 1986). This revised version was published online in June 2006 with corrections to the Cover Date.     

Kinetics of gas-Grain Reactions in the Solar Nebula

Thermochemical equilibrium calculations predict gas phase, gas-grain, and solid phase reactions as a function of pressure and temperature in the solar nebula. However, chemical reactions proceed at different rates, which generally decrease exponentially with decreasing temperature. At sufficiently low temperatures (which vary depending on the specific reaction) there may not have been enough time for the predicted equilibrium chemistry to have taken place before the local environment cooled significantly or before the gaseous solar nebula was dispersed. As a consequence, some of the high temperature chemistry established in sufficiently hot regions of the solar nebula may be quenched or frozen in without the production of predicted low temperature phases. Experimental studies and theoretical models of three exemplary low temperature reactions, the formation of troilite (FeS), magnetite (Fe₃O₄), and hydrous silicates, have been done to quantify these ideas. A comparison of the chemical reaction rates with the estimated nebular lifetime of 0.1-10 million years indicates that troilite formation proceeded to completion in the solar nebula. Magnetite formation was much slower and only thin magnetite rims could have formed on metal grains. Hydrous silicate formation is predicted to be even slower, and hydrous silicates in meteorites and interplanetary dust particles probably formed later on the parent bodies of these objects, instead of in the solar nebula. This revised version was published online in June 2006 with corrections to the Cover Date.     

Solar cosmic ray phenomena

This review attempts to present an integrated view of the several types of solar cosmic ray phenomena. The relevant large and small scale properties of the interplanetary medium are first surveyed, and their use in the development of a quantitative understanding of the cosmic ray propagation processes summarised. Solar cosmic ray events, in general, are classified into two phenomenological categories: (a) prompt events, and (b) delayed events. The properties of both classes of events are summarised. The properties considered are the frequency of occurrence, dependence on parent flare position, the time profile, energy spectra, anisotropies, particle species, velocity dispersions, etc. A single model is presented to explain the various species of delayed event. Thus the halo and core events, energetic storm particle events, EDP events and proton recurrent regions are suggested to be essentially of common origin. The association of flare particle events with electromagnetic phenomena, including optical, X-ray and microwave emissions is summarised. The conditions in a sunspot group, and solar flare that are considered to be conducive to cosmic ray acceleration processes are discussed. Considerable discussion is devoted to physical processes occurring near the Sun. Near Sun particle storage, and diffusion, and secondary injection processes that are triggered by a far distant solar flare are reviewed. In order to explain the considerable differences between aspects of the prompt and delayed events, we propose selective diffusion processes that only occur at early times in a solar flare. The type IV radio emissions at metric wave-lengths are suggested to yield direct evidence for the storage processes that are necessary to explain the properties of the delayed events, and also as yielding direct evidence of secondary injection processes. We conclude by briefly summarising the ionospheric effects of the solar cosmic radiation.     

On the Differences in Composition between Solar Energetic Particles and Solar Wind

Although the average composition of solar energetic particles (SEPs) and the bulk solar wind are similar in a number of ways, there are key differences which imply that solar wind is not the principal seed population for SEPs accelerated by coronal mass ejection (CME) driven shocks. This paper reviews these composition differences and considers the composition of other possible seed populations, including coronal material, impulsive flare material, and interplanetary CME material.     

Reservoir for Comet Material: Circumstellar Grains

Primitive meteorites and interplanetary dust particles contain small quantities of dust grains with highly anomalous isotopic compositions. These grains formed in the winds of evolved stars and in the ejecta of stellar explosions, i.e., they represent a sample of circumstellar grains that can be analyzed with high precision in the laboratory. Such studies have provided a wealth of information on stellar evolution and nucleosynthesis, Galactic chemical evolution, grain growth in stellar environments, interstellar chemistry, and the inventory of stars that contributed dust to the Solar System. Among the identified circumstellar grains in primitive solar system matter are diamond, graphite, silicon carbide, silicon nitride, oxides, and silicates. Circumstellar grains have also been found in cometary matter. To date the available information on circumstellar grains in comets is limited, but extended studies of matter returned by the Stardust mission may help to overcome the existing gaps.     

The streaming of solar flare particles and plasma in interplanetary space

A review is given of the features of solar particle emissions which cause various terrestrial disturbances. Three types of corpuscular emissions, namely, solar cosmic rays, energetic storm protons and plasma clouds, are associated with intense solar flares. Outward streaming of the solar wind and of beams of enhanced activity originate from the quiescent solar corona. It is shown that these solar particles propagate through interplanetary space, being modulated in a systematic way by existing magnetic fields. Time variations of solar flare particle flux, and their energy spectrum, are discussed.     

Relativistic electron events in interplanetary space

This review is concerned with relativistic electron events observed in interplanetary space. The different types of event are identified and illustrated. The relationships between solar X-ray and radio emissions and relativistic electrons are examined, and the relevance of the observations to solar flare acceleration models is discussed. A statistical analysis of electron spectra, the electron/proton ratio and propagation from the flare site to the Earth is presented. A model is outlined which can account for the release of electrons from the Sun in a manner consistent with observations of energetic solar particles and electromagnetic solar radiation.The literature survey for this review was concluded in May 1973.     

Coronal disturbances and their terrestrial effects

Coronal disturbances lead to geomagnetic storms, proton showers, auroras and a wide variety of other phenomena at Earth. Yet, attempts to link interplanetary and terrestrial phenomena to specific varieties of coronal disturbances have achieved only limited success. Here, several recent approaches to prediction of interplanetary consequences of coronal disturbances are reviewed. The relationships of shocks and energetic particles to coronal transients, of proton events to γ-ray bursts, of proton events to microwave bursts, of geomagnetic storms to filament eruptions and of solar wind speed increases to the flare site magnetic field direction are explored. A new phenomenon, transient coronal holes, is discussed. These voids in the corona appear astride the long decay enhancements (LDE's) of 2–50 Å X-ray emission that follow Hα filament eruptions. The transient holes are similar to long-lived coronal holes, which are the sources of high speed solar wind streams. There is some evidence that transient coronal holes are associated with transient solar wind speed increases.     

Interplanetary scintillation of radio sources during August 1972

The observations of interplanetary scintillation of radio sources in early August 1972 are reviewed. Three-site measurements of solar wind speed were made at University of California, San Diego (73.8 MHz) and at Nagoya University, Toyokawa (69.3 MHz). Single-site measurements of scintillation index were made at Mullard Radio Astronomy Observatory, Cambridge (81.5 MHz) and at University of Adelaide (111.5 MHz). The enhancements in solar wind speed and scintillation index associated with three shock waves were detected. The extent in both longitude and latitude of the shock wave associated with the solar flare on 7 August, the anisotropic expansion of shock waves and the detection of the corotating high-speed streams are main results deduced from the observations.     

Fields and plasmas in the outer solar system

The most significant information about fields and plasmas in the outer solar system, based on observations by Pioneer 10 and 11 investigations, is reviewed. The characteristic evolution of solar wind streams beyond 1 AU has been observed. The region within which the velocity increases continuously near 1 AU is replaced at larger distances by a thick interaction region with abrupt jumps in the solar wind speed at the leading and trailing edges. These abrupt increases, accompanied by corresponding jumps in the field magnitude and in the solar wind density and temperature, consist typically of a forward and a reverse shock. The existence of two distinct corotating regions, separated by sharp boundaries, is a characteristic feature of the interplanetary medium in the outer solar system. Within the interaction regions, compression effects are dominant and the field strength, plasma density, plasma temperature and the level of fluctuations are enhanced. Within the intervening quiet regions, rarefaction effects dominate and the field magnitude, solar wind density and fluctuation level are very low. These changes in the structure of interplanetary space have significant consequences for the many energetic particles propagating through the medium. The interaction regions control the access to the inner solar system of relativistic electrons from Jupiter's magnetosphere. The interaction regions and shocks appear to be associated with an acceleration of solar protons to MeV energies. Flare-generated shocks are observed to be propagating through the outer solar system with constant speed, implying that the previously recognized deceleration of flare shocks takes place principally near the Sun. Radial gradients in the solar wind and interplanetary field parameters have been determined. The solar wind speed is nearly constant between 1 and 5 AU with only a slight deceleration of 30 km s⁺¹ on the average. The proton flux follows an r ⁺² dependence reasonably well, however, the proton density shows a larger departure from this dependence. The proton temperature decreases steadily from 1 to 5 AU and the solar wind protons are slightly hotter than anticipated for an adiabatic expansion. The radial component of the interplanetary field falls off like r ⁺² and, on the average, the magnitude and spiral angle also agree reasonably well with theory. However, there is evidence, principally within quiet regions, of a significant departure of the azimuthal field component and the field magnitude from simple theoretical models. Pioneer 11 has obtained information up to heliographic latitudes of 16°. Observations of the interplanetary sector structure show that the polarity of the field becomes gradually more positive, corresponding to outward-directed fields at the Sun, and at the highest latitudes the sector structure disappears. These results confirm a prior suspicion that magnetic sectors are associated with an interplanetary current sheet surrounding the Sun which is inclined slightly to the solar equator.Proceedings of the Symposium on Solar Terrestrial Physics held in Innsbruck, May–June 1978.     

Dust Near The Sun

We review the current knowledge and understanding of dust in the inner solar system. The major sources of the dust population in the inner solar system are comets and asteroids, but the relative contributions of these sources are not quantified. The production processes inward from 1 AU are: Poynting-Robertson deceleration of particles outside of 1 AU, fragmentation into dust due to particle-particle collisions, and direct dust production from comets. The loss processes are: dust collisional fragmentation, sublimation, radiation pressure acceleration, sputtering, and rotational bursting. These loss processes as well as dust surface processes release dust compounds in the ambient interplanetary medium. Between 1 and 0.1 AU the dust number densities and fluxes can be described by inward extrapolation of 1 AU measurements, assuming radial dependences that describe particles in close to circular orbits. Observations have confirmed the general accuracy of these assumptions for regions within 30° latitude of the ecliptic plane. The dust densities are considerably lower above the solar poles but Lorentz forces can lift particles of sizes < 5 μm to high latitudes and produce a random distribution of small grains that varies with the solar magnetic field. Also long-period comets are a source of out-of-ecliptic particles. Under present conditions no prominent dust ring exists near the Sun. We discuss the recent observations of sungrazing comets. Future in-situ experiments should measure the complex dynamics of small dust particles, identify the contribution of cometary dust to the inner-solar-system dust cloud, and determine dust interactions in the ambient interplanetary medium. The combination of in-situ dust measurements with particle and field measurements is recommended.     

Interplanetary shock waves generated by solar flares

Recent observational and theoretical studies of interplanetary shock waves associated with solar flares are reviewed. An attempt is made to outline the framework for the genesis, life and demise of these shocks. Thus, suggestions are made regarding their birth within the flare generation process, MHD wave propagation through the chromosphere and inner corona, and maturity to fully-developed coronal shock waves. Their subsequent propagation into the ambient interplanetary medium and disturbing effects within the solar wind are discussed within the context of theoretical and phenomenological models. The latter — based essentially on observations — are useful for a limited interpretation of shock geometric and kinematic characteristics. The former — upon which ultimate physical understanding depends — are used for clarification and classification of the shocks and their consequences within the solar wind. Classification of limiting cases of blast-produced shocks (as in an explosion) or longer lasting ejecta (or piston-driven shocks) will hopefully be combined with the study of the flare process itself.The theoretical approach, in spite of its contribution to clarification of various concepts, contains some fundamental limitations and requires further study. Numerical simulations, for example, depend upon a non-unique set of multi-parameter initial conditions at or near the Sun. Additionally, the subtle but important influence of magnetic fields upon energy transport processes within the solar wind has not been considered in the numerical simulation approach. Similarity solutions are limited to geometrical symmetries and have not exploited their potential beyond the special cases of the blast and the constant-velocity, piston-driven shock waves. These continuum fluid studies will probably require augmentation or even replacement by plasma kinetic theory in special situations when observations indicate the presence of anomalous transport processes. Presently, for example, efforts are directed toward identification of detailed shock structures (as in the case of Earth's bow shock) and of the disturbed solar wind (such as the piston).Further progress is expected with extensive in situ and remote monitoring of the solar wind over a wide range of heliographic radii, longitudes and latitudes.This paper is a revised and updated version of an invited review originally presented at the IUGG XV General Assembly, Moscow, U.S.S.R., 2–14 August 1971.     

GeV Particle Acceleration in Solar Flares and Ground Level Enhancement (GLE) Events

Ground Level Enhancement (GLE) events represent the most energetic class of solar energetic particle (SEP) events, requiring acceleration processes to boost ?1?GeV ions in order to produce showers of secondary particles in the Earth’s atmosphere with sufficient intensity to be detected by ground-level neutron monitors, above the background of cosmic rays. Although the association of GLE events with both solar flares and coronal mass ejections (CMEs) is undisputed, the question arises about the location of the responsible acceleration site: coronal flare reconnection sites, coronal CME shocks, or interplanetary shocks? To investigate the first possibility we explore the timing of GLE events with respect to hard X-ray production in solar flares, considering the height and magnetic topology of flares, the role of extended acceleration, and particle trapping. We find that 50% (6 out of 12) of recent (non-occulted) GLE events are accelerated during the impulsive flare phase, while the remaining half are accelerated significantly later. It appears that the prompt GLE component, which is observed in virtually all GLE events according to a recent study by Vashenyuk et al. (Astrophys. Space Sci. Trans. 7(4):459–463, 2011), is consistent with a flare origin in the lower corona, while the delayed gradual GLE component can be produced by both, either by extended acceleration and/or trapping in flare sites, or by particles accelerated in coronal and interplanetary shocks.     

The interplanetary medium and its interaction with the Earth's magnetosphere

This paper reviews the principal results of direct measurements of the plasma and magnetic field by spacecraft close to the Earth (within the heliocentric distance range 0.7–1.5 AU). The paper gives an interpretation of the results for periods of decrease, minimum and increase of the solar activity. The following problems are discussed: the interplanetary plasma (chemical composition, density, solar wind flow speed, temperature, temporal and spatial variation of these parameters), the interplanetary magnetic field (intensity, direction, fluctuations and its origin), some derived parameters characterizing the physical condition of the interplanetary medium; the quasi-stationary sector structure and its connection with solar and terrestrial phenomena; the magnetohydrodynamic discontinuities in the interplanetary medium (tangential discontinuities and collisionless shock waves); the solar magnetoplasma interaction with the geomagnetic field (the collisionless bow shock wave, the magnetosheath, the magnetopause, the Earth's magnetic tail, the internal magnetosphere characteristics), the connection between the geomagnetic activity and the interplanetary medium and magnetosphere parameters; peculiarities in behaviour of the interplanetary medium and magnetosphere during geomagnetic storms; energetic aspects of the geomagnetic storms.     

Non-relativistic solar electrons

This review summarizes both the direct spacecraft observations of non-relativistic solar electrons, and observations of the X-ray and radio emission generated by these particles at the Sun and in the interplanetary medium. These observations bear on three physical processes basic to energetic particle phenomena: (1) the acceleration of particles in tenuous plasmas; (2) the propagation of energetic charged particles in a disordered magnetic field, and (3) the interaction of energetic charged particles with tenuous plasmas to produce electromagnetic radiation. Because these electrons are frequently accelerated and emitted by the Sun, mostly in small and relatively simple flares, it is possible to define a detailed physical picture of these processes.In many small solar flares non-relativistic electrons accelerated during flash phase constitute the bulk of the total flare energy. Thus the basic flare mechanism in these flares essentially converts the available flare energy into fast electrons. Non-relativistic electrons exhibit a wide variety of propagation modes in the interplanetary medium, ranging from diffusive to essentially scatter-free. This variability in the propagation may be explained in terms of the distribution of interplanetary magnetic field fluctuations. Type III solar radio burst emission is generated by these electrons as they travel out to 1 AU and beyond. Recent in situ observations of these electrons at 1 AU, accompanied by simultaneous observations of the low frequency radio emission generated by them at 1 AU provide quantitative information on the plasma processes involved in the generation of type III bursts.     

Formation and Processing of Organics in the Early Solar System

Until pristine samples can be returned from cometary nuclei, primitive meteorites represent our best source of information about organic chemistry in the early solar system. However, this material has been affected by secondary processing on asteroidal parent bodies which probably did not affect the material now present in cometary nuclei. Production of meteoritic organic matter apparently involved the following sequence of events: Molecule formation by a variety of reaction pathways in dense interstellar clouds; Condensation of those molecules onto refractory interstellar grains; Irradiation of organic-rich interstellar-grain mantles producing a range of molecular fragments and free radicals; Inclusion of those interstellar grains into the protosolar nebula with probable heating of at least some grain mantles during passage through the shock wave bounding the solar accretion disc; Agglomeration of residual interstellar grains and locally produced nebular condensates into asteroid-sized planetesimals; Heating of planetesimals by decay of extinct radionuclides; Melting of ice to produce liquid water within asteroidal bodies; Reaction of interstellar molecules, fragments and radicals with each other and with the aqueous environment, possibly catalysed by mineral grains; Loss of water and other volatiles to space yielding a partially hydrated lithology containing a complex suite of organic molecules; Heating of some of this organic matter to generate a kerogen-like complex; Mixing of heated and unheated material to yield the meteoritic material now observed. Properties of meteoritic organic matter believed to be consistent with this scenario include: Systematic decrease of abundance with increasing C number in homologous series of characterisable molecules; Complete structural diversity within homologous series; Predominance of branched-chain isomers; Considerable isotopic variability among characterisable molecules and within kerogen-like material; Substantial deuterium enrichment in all organic fractions; Some fractions significantly enriched in nitrogen-15; Modest excesses of L-enantiomers in some racemisation-resistant molecules but no general enantiomeric preference. Despite much speculation about the possible role of Fischer-Tropsch catalytic hydrogenation of CO in production of organic molecules in the solar nebula, no convincing evidence for such material has been found in meteorites. A similarity between some meteoritic organics and those produced by Miller-Urey discharge synthesis may reflect involvement of common intermediates rather than the operation of electric discharges in the early solar system. Meteoritic organic matter constitutes a useful, but not exact, guide to what we shall find with in situ analytical and sample-return missions to cometary nuclei. This revised version was published online in June 2006 with corrections to the Cover Date.