Ion Energization and Escape on Mars and Venus

Mars and Venus do not have a global magnetic field and as a result solar wind interacts directly with their ionospheres and upper atmospheres. Neutral atoms ionized by solar UV, charge exchange and electron impact, are extracted and scavenged by solar wind providing a significant loss of planetary volatiles. There are different channels and routes through which the ionized planetary matter escapes from the planets. Processes of ion energization driven by direct solar wind forcing and their escape are intimately related. Forces responsible for ion energization in different channels are different and, correspondingly, the effectiveness of escape is also different. Classification of the energization processes and escape channels on Mars and Venus and also their variability with solar wind parameters is the main topic of our review. We will distinguish between classical pickup and ??mass-loaded?? pickup processes, energization in boundary layer and plasma sheet, polar winds on unmagnetized planets with magnetized ionospheres and enhanced escape flows from localized auroral regions in the regions filled by strong crustal magnetic fields.     

Effects of Low Energetic Neutral Atoms on Martian and Venusian Dayside Exospheric Temperature Estimations

The heating of the upper atmospheres and the formation of the ionospheres on Venus and Mars are mainly controlled by the solar X-ray and extreme ultraviolet (EUV) radiation (λ = 0.1–102.7 nm and can be characterized by the 10.7 cm solar radio flux). Previous estimations of the average Martian dayside exospheric temperature inferred from topside plasma scale heights, UV airglow and Lyman-α dayglow observations of up to ∼500 K imply a stronger dependence on solar activity than that found on Venus by the Pioneer Venus Orbiter (PVO) and Magellan spacecraft. However, this dependence appears to be inconsistent with exospheric temperatures (<250 K) inferred from aerobraking maneuvers of recent spacecraft like Mars Pathfinder, Mars Global Surveyor and Mars Odyssey during different solar activity periods and at different orbital locations of the planet. In a similar way, early Lyman-α dayglow and UV airglow observations by Venera 4, Mariner 5 and 10, and Venera 9–12 at Venus also suggested much higher exospheric temperatures of up to 1000 K as compared with the average dayside exospheric temperature of about 270 K inferred from neutral gas mass spectrometry data obtained by PVO. In order to compare Venus and Mars, we estimated the dayside exobase temperature of Venus by using electron density profiles obtained from the PVO radio science experiment during the solar cycle and found the Venusian temperature to vary between 250–300 K, being in reasonable agreement with the exospheric temperatures inferred from Magellan aerobraking data and PVO mass spectrometer measurements. The same method has been applied to Mars by studying the solar cycle variation of the ionospheric peak plasma density observed by Mars Global Surveyor during both solar minimum and maximum conditions, yielding a temperature range between 190–220 K. This result clearly indicates that the average Martian dayside temperature at the exobase does not exceed a value of about 240 K during high solar activity conditions and that the response of the upper atmosphere temperature on Mars to solar activity near the ionization maximum is essentially the same as on Venus. The reason for this discrepancy between exospheric temperature determinations from topside plasma scale heights and electron distributions near the ionospheric maximum seems to lie in the fact that thermal and photochemical equilibrium applies only at altitudes below 170 km, whereas topside scale heights are derived for much higher altitudes where they are modified by transport processes and where local thermodynamic equilibrium (LTE) conditions are violated. Moreover, from simulating the energy density distribution of photochemically produced moderately energetic H, C and O atoms, as well as CO molecules, we argue that exospheric temperatures inferred from Lyman-α dayglow and UV airglow observations result in too high values, because these particles, as well as energetic neutral atoms, transformed from solar wind protons into hydrogen atoms via charge exchange, may contribute to the observed planetary hot neutral gas coronae. Because the low exospheric temperatures inferred from neutral gas mass spectrometer and aerobraking data, as well as from CO⁺ ₂ UV doublet emissions near 180–260 nm obtained from the Mars Express SPICAM UV spectrograph suggest rather low heating efficiencies, some hitherto unidentified additional IR-cooling mechanism in the thermospheres of both Venus and Mars is likely to exist. An erratum to this article can be found at     

Planetary Magnetic Fields and Solar Forcing: Implications for Atmospheric Evolution

The solar wind and the solar XUV/EUV radiation constitute a permanent forcing of the upper atmosphere of the planets in our solar system, thereby affecting the habitability and chances for life to emerge on a planet. The forcing is essentially inversely proportional to the square of the distance to the Sun and, therefore, is most important for the innermost planets in our solar system—the Earth-like planets. The effect of these two forcing terms is to ionize, heat, chemically modify, and slowly erode the upper atmosphere throughout the lifetime of a planet. The closer to the Sun, the more efficient are these process. Atmospheric erosion is due to thermal and non-thermal escape. Gravity constitutes the major protection mechanism for thermal escape, while the non-thermal escape caused by the ionizing X-rays and EUV radiation and the solar wind require other means of protection. Ionospheric plasma energization and ion pickup represent two categories of non-thermal escape processes that may bring matter up to high velocities, well beyond escape velocity. These energization processes have now been studied by a number of plasma instruments orbiting Earth, Mars, and Venus for decades. Plasma measurement results therefore constitute the most useful empirical data basis for the subject under discussion. This does not imply that ionospheric plasma energization and ion pickup are the main processes for the atmospheric escape, but they remain processes that can be most easily tested against empirical data. Shielding the upper atmosphere of a planet against solar XUV, EUV, and solar wind forcing requires strong gravity and a strong intrinsic dipole magnetic field. For instance, the strong dipole magnetic field of the Earth provides a “magnetic umbrella”, fending of the solar wind at a distance of 10 Earth radii. Conversely, the lack of a strong intrinsic magnetic field at Mars and Venus means that the solar wind has more direct access to their topside atmosphere, the reason that Mars and Venus, planets lacking strong intrinsic magnetic fields, have so much less water than the Earth? Climatologic and atmospheric loss process over evolutionary timescales of planetary atmospheres can only be understood if one considers the fact that the radiation and plasma environment of the Sun has changed substantially with time. Standard stellar evolutionary models indicate that the Sun after its arrival at the Zero-Age Main Sequence (ZAMS) 4.5 Gyr ago had a total luminosity of ≈70% of the present Sun. This should have led to a much cooler Earth in the past, while geological and fossil evidence indicate otherwise. In addition, observations by various satellites and studies of solar proxies (Sun-like stars with different age) indicate that the young Sun was rotating more than 10 times its present rate and had correspondingly strong dynamo-driven high-energy emissions which resulted in strong X-ray and extreme ultraviolet (XUV) emissions, up to several 100 times stronger than the present Sun. Further, evidence of a much denser early solar wind and the mass loss rate of the young Sun can be determined from collision of ionized stellar winds of the solar proxies, with the partially ionized gas in the interstellar medium. Empirical correlations of stellar mass loss rates with X-ray surface flux values allows one to estimate the solar wind mass flux at earlier times, when the solar wind may have been more than 1000 times more massive. The main conclusions drawn on basis of the Sun-in-time-, and a time-dependent model of plasma energization/escape is that:

1. Solar forcing is effective in removing volatiles, primarily water, from planets,
2. planets orbiting close to the early Sun were subject to a heavy loss of water, the effect being most profound for Venus and Mars, and
3. a persistent planetary magnetic field, like the Earth’s dipole field, provides a shield against solar wind scavenging.

     

Imaging Plasma Density Structures in the Soft X-Rays Generated by Solar Wind Charge Exchange with Neutrals

Both heliophysics and planetary physics seek to understand the complex nature of the solar wind’s interaction with solar system obstacles like Earth’s magnetosphere, the ionospheres of Venus and Mars, and comets. Studies with this objective are frequently conducted with the help of single or multipoint in situ electromagnetic field and particle observations, guided by the predictions of both local and global numerical simulations, and placed in context by observations from far and extreme ultraviolet (FUV, EUV), hard X-ray, and energetic neutral atom imagers (ENA). Each proposed interaction mechanism (e.g., steady or transient magnetic reconnection, local or global magnetic reconnection, ion pick-up, or the Kelvin-Helmholtz instability) generates diagnostic plasma density structures. The significance of each mechanism to the overall interaction (as measured in terms of atmospheric/ionospheric loss at comets, Venus, and Mars or global magnetospheric/ionospheric convection at Earth) remains to be determined but can be evaluated on the basis of how often the density signatures that it generates are observed as a function of solar wind conditions. This paper reviews efforts to image the diagnostic plasma density structures in the soft (low energy, 0.1–2.0 keV) X-rays produced when high charge state solar wind ions exchange electrons with the exospheric neutrals surrounding solar system obstacles.The introduction notes that theory, local, and global simulations predict the characteristics of plasma boundaries such the bow shock and magnetopause (including location, density gradient, and motion) and regions such as the magnetosheath (including density and width) as a function of location, solar wind conditions, and the particular mechanism operating. In situ measurements confirm the existence of time- and spatial-dependent plasma density structures like the bow shock, magnetosheath, and magnetopause/ionopause at Venus, Mars, comets, and the Earth. However, in situ measurements rarely suffice to determine the global extent of these density structures or their global variation as a function of solar wind conditions, except in the form of empirical studies based on observations from many different times and solar wind conditions. Remote sensing observations provide global information about auroral ovals (FUV and hard X-ray), the terrestrial plasmasphere (EUV), and the terrestrial ring current (ENA). ENA instruments with low energy thresholds (\(\sim1~\mbox{keV}\)) have recently been used to obtain important information concerning the magnetosheaths of Venus, Mars, and the Earth. Recent technological developments make these magnetosheaths valuable potential targets for high-cadence wide-field-of-view soft X-ray imagers.Section 2 describes proposed dayside interaction mechanisms, including reconnection, the Kelvin-Helmholtz instability, and other processes in greater detail with an emphasis on the plasma density structures that they generate. It focuses upon the questions that remain as yet unanswered, such as the significance of each proposed interaction mode, which can be determined from its occurrence pattern as a function of location and solar wind conditions. Section 3 outlines the physics underlying the charge exchange generation of soft X-rays. Section 4 lists the background sources (helium focusing cone, planetary, and cosmic) of soft X-rays from which the charge exchange emissions generated by solar wind exchange must be distinguished. With the help of simulations employing state-of-the-art magnetohydrodynamic models for the solar wind-magnetosphere interaction, models for Earth’s exosphere, and knowledge concerning these background emissions, Sect. 5 demonstrates that boundaries and regions such as the bow shock, magnetosheath, magnetopause, and cusps can readily be identified in images of charge exchange emissions. Section 6 reviews observations by (generally narrow) field of view (FOV) astrophysical telescopes that confirm the presence of these emissions at the intensities predicted by the simulations. Section 7 describes the design of a notional wide FOV “lobster-eye” telescope capable of imaging the global interactions and shows how it might be used to extract information concerning the global interaction of the solar wind with solar system obstacles. The conclusion outlines prospects for missions employing such wide FOV imagers.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

The Hydrogen Exospheric Density Profile Measured with ASPERA-3/NPD

We have evaluated the Lyman-α limb emission from the exospheric hydrogen of Mars measured by the neutral particle detector of the ASPERA-3 instrument on Mars Express in 2004 at low solar activity (solar activity index = 42, F_10.7=100). We derive estimates for the hydrogen exobase density, n _H = 10¹⁰ m^?3, and for the apparent temperature, T > 600 K. We conclude that the limb emission measurement is dominated by a hydrogen component that is considerably hotter than the bulk temperature at the exobase. The derived values for the exosphere density and temperature are compared with similar measurements done by the Mariner space probes in the 1969. The values found with Mars Express and Mariner data are brought in a broader context of exosphere models including the possibility of having two hydrogen components in the Martian exosphere. The present observation of the Martian hydrogen exosphere is the first one at high altitudes during low solar activity, and shows that for low solar activity exospheric densities are not higher than for high solar activity.     

Asymmetries in Mars' Exosphere

Observations and simulations show that Mars' atmosphere has large seasonal variations. Total atmospheric density can have an order of magnitude latitudinal variation at exobase heights. By numerical simulations we show that these latitude variations in exobase parameters induce asymmetries in the hydrogen exosphere that propagate to large distances from the planet. We show that these asymmetries in the exosphere produce asymmetries in the fluxes of energetic neutral atoms (ENAs) and soft X-rays produced by charge exchange between the solar wind and exospheric hydrogen. This could be an explanation for asymmetries that have been observed in ENA and X-ray fluxes at Mars.     

The Magnetic Field Pile-up and Density Depletion in the Martian Magnetosheath: A Comparison with the Plasma Depletion Layer Upstream of the Earth's Magnetopause

Using magnetometer and electron observations from the Mars Global Surveyor (MGS) and the Wind spacecraft we show that the region of magnetic field pile-up and density decrease located between the Martian ionosphere and bow shock exhibit strong similarities with the plasma depletion layer (PDL) observed upstream of the Earth's magnetopause in the absence of magnetic reconnection when the magnetopause is a solid obstacle in the solar wind. A PDL is formed upstream of the terrestrial magnetopause when the magnetic field piles up against the obstacle and particles in the pile-up region are squeezed away from the high magnetic pressure region along the field lines as the flux tubes convect toward the magnetopause. We here discuss the possibility that at least part of the region of magnetic field pile-up and density depletion upstream of Mars may be formed by the same physical processes which generate the PDL upstream of the Earth's magnetopause. More complete ion, electron, and neutral measurements are needed to conclusively determine the relative importance of the plasma depletion process versus exospheric processes.     

Exospheres and Energetic Neutral Atoms of Mars, Venus and Titan

Our understanding of the upper atmosphere of unmagnetized bodies such as Mars, Venus and Titan has improved significantly in this decade. Recent observations by in situ and remote sensing instruments on board Mars Express, Venus Express and Cassini have revealed characteristics of the neutral upper atmospheres (exospheres) and of energetic neutral atoms (ENAs). The ENA environment in the vicinity of the bodies is by itself a significant study field, but ENAs are also used as a diagnostic tool for the exosphere and the interaction with the upstream plasmas. Synergy between theoretical and modeling work has also improved considerably. In this review, we summarize the recent progress of our understanding of the neutral environment in the vicinity of unmagnetized planets.     

Plasma Morphology at Mars. Aspera-3 Observations

A total of about of 400 orbits during the first year of the ASPERA-3 operation onboard the Mars Express spacecraft were analyzed to obtain a statistical pattern of the main plasma domains in the Martian space environment. The environment is controlled by the direct interaction between the solar wind and the planetary exosphere/ionosphere which results in the formation of the magnetospheric cavity. Ionospheric plasma was traced by the characteristic “spectral lines” of photoelectrons that make it possible to detect an ionospheric component even far from the planet. Plasma of solar wind and planetary origin was distinguished by the ion mass spectrometry. Several different regions, namely, boundary layer/mantle, plasma sheet, region with ionospheric photoelectrons, ray-like structures near the wake boundary were identified. Upstream parameters like solar wind ram pressure and the direction of the interplanetary electric field were inferred as proxy from the Mars Global Surveyor magnetic field data at a reference point of the magnetic pile up region in the northern dayside hemisphere. It is shown that morphology and dynamics of the main plasma domains and their boundaries are governed by these factors as well as by local crustal magnetizations which add complexity and variability to the plasma and magnetic field environment.     

Hybrid Simulations of Wave Propagation and Ion Cyclotron Heating in the Expanding Solar Wind

We present results from hybrid (particle ions, fluid electrons) simulations of the evolution of Alfvén waves close to the ion cyclotron frequency in the solar wind, which take into account the basic properties of the background solar wind flow, i.e., the spherical expansion and the consequent decrease in magnetic field and cyclotron frequency with increasing distance from the Sun. We follow the evolution of a plasma parcel in a frame of reference moving with the solar wind using a 1D expanding box hybrid model; use of the hybrid model yields a fully self-consistent treatment of the resonant cyclotron wave-particle interaction. This model is related to a previous MHD model (Velli et al. 1992), which allows the use of a simple Cartesian geometry with periodic boundary conditions. The use of stretched expanding coordinates in directions transverse to the mean radial solar wind flow naturally introduces an anisotropic damping effect on velocity and magnetic field. We present results for the case of a single circularly polarized Alfvén wave propagating radially outward. Initially, the wave is below the cyclotron frequency for both the alpha partcles and protons. As the wind expands, the wave frequency (as seen in the solar wind frame) decreases more slowly than the cyclotron frequencies and the wave comes into resonance. With only protons, heating occurs as the wave frequency approaches the proton cyclotron frequency. With both alphas and protons, the alphas, which come into resonance first, are observed to be preferentially heated and accelerated. This revised version was published online in June 2006 with corrections to the Cover Date.     

Ion Acceleration and Outflow from Mars and Venus: An Overview

Solar wind forcing of Mars and Venus results in outflow and escape of ionospheric ions. Observations show that the replenishment of ionospheric ions starts in the dayside at low altitudes (??300?C800 km), ions moving at a low velocity (5?C10 km/s) in the direction of the external/ magnetosheath flow. At high altitudes, in the inner magnetosheath and in the central tail, ions may be accelerated up to keV energies. However, the dominating energization and outflow process, applicable for the inner magnetosphere of Mars and Venus, leads to outflow at energies ??5?C20 eV. The aim of this overview is to analyze ion acceleration processes associated with the outflow and escape of ionospheric ions from Mars and Venus. Qualitatively, ion acceleration may be divided in two categories:

1. Modest ion acceleration, leading to bulk outflow and/or return flow (circulation).
2. Acceleration to well over escape velocity, up into the keV range.

In the first category we find a processes denoted ??planetary wind??, the result of e.g. ambipolar diffusion, wave enhanced planetary wind, and mass-loaded ion pickup. In the second category we find ion pickup, current sheet acceleration, wave acceleration, and parallel electric fields, the latter above Martian crustal magnetic field regions. Both categories involve mass loading. Highly mass-loaded ion energization may lead to a low-velocity bulk flow??A consequence of energy and momentum conservation. It is therefore not self-evident what group, or what processes are connected with the low-energy outflow of ionospheric ions from Mars. Experimental and theoretical findings on ionospheric ion acceleration and outflow from Mars and Venus are discussed in this report.     

Bow Shock and Upstream Phenomena at Mars

Mars Global Surveyor is the sixth spacecraft to return measurements of the Martian bow shock. The earlier missions were Mariner 4 (1964), Mars 2 and 3 (1972), Mars 5 (1975) and Phobos 2 (1989) (see reviews by Gringauz, 1981; Slavin and Holzer, 1982; Russell, 1985; Vaisberg, 1992a,b; Zakharov, 1992). Previous investigations of planetary bow shocks have established that their position, shape and jump conditions are functions of the upstream flow parameters and the nature of the solar wind — planet interaction (Spreiter and Stahara, 1980; Slavin et al., 1983; Russell, 1985). At Mars, however, the exact nature of the solar wind interaction was elusive due to the lack of low altitude plasma and magnetic field measurements (e.g., Axford, 1991). In fact our knowledge of the nature of the interaction of Mars with the solar wind was incomplete until the arrival of MGS and the acquisition of close-in magnetic field data (Acuña et al., 1998). As detailed by a series of review papers in this monograph, the Mars Global Surveyor (MGS) mission has now shown that the Mars environment is very complex with strong, highly structured crustal magnetic remnants in the southern hemisphere, while the northern hemisphere experiences the direct impingement of solar wind plasma. This review paper first presents a survey of the observations on the Martian bow shock and the upstream phenomena in the light of results from all the missions to date. It also discusses the kinetic properties of the Martian bow shock compared to the predictions of simulations studies. Then it examines the current status of understanding of these phenomena, including the possible sources of upstream low-frequency waves and the interpretations of localized disturbances in the upstream solar wind around Mars. Finally, it briefly discusses the open issues and questions that require further study.     

X-Rays From Mars

X-rays from Mars were first detected in July 2001 with the satellite Chandra. The main source of this radiation was fluorescent scattering of solar X-rays in its upper atmosphere. In addition, the presence of an extended X-ray halo was indicated, probably resulting from charge exchange interactions between highly charged heavy ions in the solar wind and neutrals in the Martian exosphere. The statistical significance of the X-ray halo, however, was very low. In November 2003, Mars was observed again in X-rays, this time with the satellite XMM-Newton. This observation, characterized by a considerably higher sensitivity, confirmed the presence of the X-ray halo and proved that charge exchange is indeed the origin of the emission. This was the first definite detection of charge exchange induced X-ray emission from the exosphere of another planet. Previously, this kind of emission had been detected from comets (which are largely exospheres) and from the terrestrial exosphere. Because charge exchange interactions between atmospheric constituents and solar wind ions are considered as an important nonthermal escape mechanism, probably responsible for a significant loss of the Martian atmosphere, X-ray observations may lead to a better understanding of the present state of the Martian atmosphere and its evolution. X-ray images of the Martian exosphere in specific emission lines exhibited a highly anisotropic morphology, varying with individual ions and ionization states. With its capability to trace the X-ray emission out to at least 8 Mars radii, XMM-Newton can explore exospheric regions far beyond those that have been observationally explored to date. Thus, X-ray observations provide a novel method for studying processes in the Martian exosphere on a global scale.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

The solar wind interaction with Venus

This paper assesses our current understanding of the solar wind interaction with Venus in light of developments since the last major reviews were published in 1983. Suggestions for making further progress in the area of solar wind interactions with planetary atmospheres and ionospheres are offered based on the available observations and techniques, and from the viewpoint of forthcoming missions to Mars.     

Infrared Spectroscopy of Solar-System Planets

Most of our knowledge regarding planetary atmospheric composition and structure has been achieved by remote sensing spectroscopy. Planetary spectra strongly differ from one planet to another. CO₂ signatures dominate on Mars, and even more on Venus (where the thermal component is detectable down to 1 μm on the dark side). Spectroscopic monitoring of Venus, Earth and Mars allows us to map temperature fields, wind fields, clouds, aerosols, surface mineralogy (in the case of the Earth and Mars), and to study the planets’ seasonal cycles. Spectra of giant planets are dominated by H₂, CH₄ and other hydrocarbons, NH₃, PH₃ and traces of other minor compounds like CO, H₂O and CO₂. Measurements of the atmospheric composition of giant planets have been used to constrain their formation scenario.     

Origin of planetary atmospheres

The near absence of noble gases on earth, other than those of radioactive origin, indicates that the earth was formed by the accumulation of planetesimals; this process systematically excluded all constituents that did not enter into the solid phase. The atmosphere and the ocean with many of its dissolved salts have arisen from gases emitted from the earth's interior, a process that continues today. The oxygen in the earth's atmosphere plus a greater quantity that has been removed from the atmosphere to oxidize geologic materials, has arisen mainly from a small excess of photosynthesis over decay of organic material. The atmospheres of Mars and Venus have probably arisen in a manner similar to the atmosphere on earth, by emission from the planetary interiors. However, they have not received any oxygen from photosynthesis and so are nearly oxygen free. Mars has very little water in its atmosphere, and this can be explained by its lower than freezing average surface temperature. Venus also has very little water, and this requires an ad hoc explanation; one possibility is that Venus was formed from much drier planetesimals than was the earth. Mercury and the moon are virtually without atmospheres. Although some gases may be emitted from their interiors, they are presumably rapidly lost by escape. Whatever atmosphere they possess is probably due to the neutralized solar wind that impinges upon them. The outer planets retained volatiles, including hydrogen and helium, to a much greater extent than did the terrestrial planets.     

The Induced Magnetospheres of Mars, Venus, and Titan

This article summarizes and aims at comparing the main features of the induced magnetospheres of Mars, Venus and Titan. All three objects form a well-defined induced magnetosphere (IM) and magnetotail as a consequence of the interaction of an external wind of plasma with the ionosphere and the exosphere of these objects. In all three, photoionization seems to be the most important ionization process. In all three, the IM displays a clear outer boundary characterized by an enhancement of magnetic field draping and massloading, along with a change in the plasma composition, a decrease in the plasma temperature, a deflection of the external flow, and, at least for Mars and Titan, an increase of the total density. Also, their magnetotail geometries follow the orientation of the upstream magnetic field and flow velocity under quasi-steady conditions. Exceptions to this are fossil fields observed at Titan and the near Mars regions where crustal fields dominate the magnetic topology. Magnetotails also concentrate the escaping plasma flux from these three objects and similar acceleration mechanisms are thought to be at work. In the case of Mars and Titan, global reconfiguration of the magnetic field topology (reconnection with the crustal sources and exits into Saturn??s magnetosheath, respectively) may lead to important losses of plasma. Finally, an ionospheric boundary related to local photoelectron signals may be, in the absence of other sources of pressure (crustal fields) a signature of the ultimate boundary to the external flow.