Infrared Spectroscopy of Solar-System Planets

Most of our knowledge regarding planetary atmospheric composition and structure has been achieved by remote sensing spectroscopy. Planetary spectra strongly differ from one planet to another. CO₂ signatures dominate on Mars, and even more on Venus (where the thermal component is detectable down to 1 μm on the dark side). Spectroscopic monitoring of Venus, Earth and Mars allows us to map temperature fields, wind fields, clouds, aerosols, surface mineralogy (in the case of the Earth and Mars), and to study the planets’ seasonal cycles. Spectra of giant planets are dominated by H₂, CH₄ and other hydrocarbons, NH₃, PH₃ and traces of other minor compounds like CO, H₂O and CO₂. Measurements of the atmospheric composition of giant planets have been used to constrain their formation scenario.     

Water Reservoirs in Small Planetary Bodies: Meteorites,Asteroids, and Comets

Asteroids and comets are the remnants of the swarm of planetesimals from which the planets ultimately formed, and they retain records of processes that operated prior to and during planet formation. They are also likely the sources of most of the water and other volatiles accreted by Earth. In this review, we discuss the nature and probable origins of asteroids and comets based on data from remote observations, in situ measurements by spacecraft, and laboratory analyses of meteorites derived from asteroids. The asteroidal parent bodies of meteorites formed \(\leq 4\) Ma after Solar System formation while there was still a gas disk present. It seems increasingly likely that the parent bodies of meteorites spectroscopically linked with the E-, S-, M- and V-type asteroids formed sunward of Jupiter’s orbit, while those associated with C- and, possibly, D-type asteroids formed further out, beyond Jupiter but probably not beyond Saturn’s orbit. Comets formed further from the Sun than any of the meteorite parent bodies, and retain much higher abundances of interstellar material. CI and CM group meteorites are probably related to the most common C-type asteroids, and based on isotopic evidence they, rather than comets, are the most likely sources of the H and N accreted by the terrestrial planets. However, comets may have been major sources of the noble gases accreted by Earth and Venus. Possible constraints that these observations can place on models of giant planet formation and migration are explored.     

Below One Earth: The Detection, Formation, and Properties of Subterrestrial Worlds

The Solar System includes two planets—Mercury and Mars—significantly less massive than Earth, and all evidence indicates that planets of similar size orbit many stars. In fact, one of the first exoplanets to be discovered is a lunar-mass planet around a millisecond pulsar. Novel classes of exoplanets have inspired new ideas about planet formation and evolution, and these “sub-Earths” should be no exception: they include planets with masses between Mars and Venus for which there are no Solar System analogs. Advances in astronomical instrumentation and recent space missions have opened the sub-Earth frontier for exploration: the Kepler mission has discovered dozens of confirmed or candidate sub-Earths transiting their host stars. It can detect Mars-size planets around its smallest stellar targets, as well as exomoons of comparable size. Although the application of the Doppler method is currently limited by instrument stability, future spectrographs may detect equivalent planets orbiting close to nearby bright stars. Future space-based microlensing missions should be able to probe the sub-Earth population on much wider orbits. A census of sub-Earths will complete the reconnaissance of the exoplanet mass spectrum and test predictions of planet formation models, including whether low-mass M dwarf stars preferentially host the smallest planets. The properties of sub-Earths may reflect their low gravity, diverse origins, and environment, but they will be elusive: Observations of eclipsing systems by the James Webb Space Telescope may give us our first clues to the properties of these small worlds.     

Atmospheric Escape and Evolution of Terrestrial Planets and Satellites

The origin and evolution of Venus’, Earth’s, Mars’ and Titan’s atmospheres are discussed from the time when the active young Sun arrived at the Zero-Age-Main-Sequence. We show that the high EUV flux of the young Sun, depending on the thermospheric composition, the amount of IR-coolers and the mass and size of the planet, could have been responsible that hydrostatic equilibrium was not always maintained and hydrodynamic flow and expansion of the upper atmosphere resulting in adiabatic cooling of the exobase temperature could develop. Furthermore, thermal and various nonthermal atmospheric escape processes influenced the evolution and isotope fractionation of the atmospheres and water inventories of the terrestrial planets and Saturn’s large satellite Titan efficiently.     

Micromission spacecraft: a low-cost, high-capability platform for space science missions

The Ball Micromission Spacecraft (MSC) is a multi-purpose platform capable of supporting science missions at distances from the Sun ranging from 0.7 to 1.7 AU. In the baseline scenario, MSC is launched as a secondary payload on an Ariane 5 rocket from Kourou, French Guiana, to GTO using the Ariane 5 structure for auxiliary payloads (ASAP5). The maximum launch wet mass is 242 Kg and can include up to 45 Kg of payload depending on AV needs. The on-board propulsion system is used for maneuvering in the Earth-Moon system and injecting the spacecraft into its final orbit or trajectory. For Mars missions, MSC enables orbiting Mars for science payloads and/or communications and navigation assets, or for precision Mars fly-bys to drop up to six probes. The micromissions spacecraft bus can be used for science targets other than Mars, including the Moon, Earth, Venus, Earth-Sun Lagrange points, or other small bodies. This paper summarizes the current spacecraft concept and describes the multimission spacecraft bus implementation in more detail.     

Planetary Magnetic Fields and Solar Forcing: Implications for Atmospheric Evolution

The solar wind and the solar XUV/EUV radiation constitute a permanent forcing of the upper atmosphere of the planets in our solar system, thereby affecting the habitability and chances for life to emerge on a planet. The forcing is essentially inversely proportional to the square of the distance to the Sun and, therefore, is most important for the innermost planets in our solar system—the Earth-like planets. The effect of these two forcing terms is to ionize, heat, chemically modify, and slowly erode the upper atmosphere throughout the lifetime of a planet. The closer to the Sun, the more efficient are these process. Atmospheric erosion is due to thermal and non-thermal escape. Gravity constitutes the major protection mechanism for thermal escape, while the non-thermal escape caused by the ionizing X-rays and EUV radiation and the solar wind require other means of protection. Ionospheric plasma energization and ion pickup represent two categories of non-thermal escape processes that may bring matter up to high velocities, well beyond escape velocity. These energization processes have now been studied by a number of plasma instruments orbiting Earth, Mars, and Venus for decades. Plasma measurement results therefore constitute the most useful empirical data basis for the subject under discussion. This does not imply that ionospheric plasma energization and ion pickup are the main processes for the atmospheric escape, but they remain processes that can be most easily tested against empirical data. Shielding the upper atmosphere of a planet against solar XUV, EUV, and solar wind forcing requires strong gravity and a strong intrinsic dipole magnetic field. For instance, the strong dipole magnetic field of the Earth provides a “magnetic umbrella”, fending of the solar wind at a distance of 10 Earth radii. Conversely, the lack of a strong intrinsic magnetic field at Mars and Venus means that the solar wind has more direct access to their topside atmosphere, the reason that Mars and Venus, planets lacking strong intrinsic magnetic fields, have so much less water than the Earth? Climatologic and atmospheric loss process over evolutionary timescales of planetary atmospheres can only be understood if one considers the fact that the radiation and plasma environment of the Sun has changed substantially with time. Standard stellar evolutionary models indicate that the Sun after its arrival at the Zero-Age Main Sequence (ZAMS) 4.5 Gyr ago had a total luminosity of ≈70% of the present Sun. This should have led to a much cooler Earth in the past, while geological and fossil evidence indicate otherwise. In addition, observations by various satellites and studies of solar proxies (Sun-like stars with different age) indicate that the young Sun was rotating more than 10 times its present rate and had correspondingly strong dynamo-driven high-energy emissions which resulted in strong X-ray and extreme ultraviolet (XUV) emissions, up to several 100 times stronger than the present Sun. Further, evidence of a much denser early solar wind and the mass loss rate of the young Sun can be determined from collision of ionized stellar winds of the solar proxies, with the partially ionized gas in the interstellar medium. Empirical correlations of stellar mass loss rates with X-ray surface flux values allows one to estimate the solar wind mass flux at earlier times, when the solar wind may have been more than 1000 times more massive. The main conclusions drawn on basis of the Sun-in-time-, and a time-dependent model of plasma energization/escape is that:

1. Solar forcing is effective in removing volatiles, primarily water, from planets,
2. planets orbiting close to the early Sun were subject to a heavy loss of water, the effect being most profound for Venus and Mars, and
3. a persistent planetary magnetic field, like the Earth’s dipole field, provides a shield against solar wind scavenging.

     

Venus Atmospheric Thermal Structure and Radiative Balance

From the discovery that Venus has an atmosphere during the 1761 transit by M. Lomonosov to the current exploration of the planet by the Akatsuki orbiter, we continue to learn about the planet’s extreme climate and weather. This chapter attempts to provide a comprehensive but by no means exhaustive review of the results of the atmospheric thermal structure and radiative balance since the earlier works published in Venus and Venus II books from recent spacecraft and Earth based investigations and summarizes the gaps in our current knowledge. There have been no in-situ measurements of the deep Venus atmosphere since the flights of the two VeGa balloons and landers in 1985 (Sagdeev et al., Science 231:1411–1414, 1986). Thus, most of the new information about the atmospheric thermal structure has come from different remote sensing (Earth based and spacecraft) techniques using occultations (solar infrared, stellar ultraviolet and orbiter radio occultations), spectroscopy and microwave, short wave and thermal infrared emissions. The results are restricted to altitudes higher than about 40 km, except for one investigation of the near surface static stability inferred by Meadows and Crisp (J. Geophys. Res. 101:4595–4622, 1996) from 1 \(\upmu\)m observations from Earth. Little information about the lower atmospheric structure is possible below about 40 km altitude from radio occultations due to large bending angles. The gaps in our knowledge include spectral albedo variations over time, vertical variation of the bulk composition of the atmosphere (mean molecular weight), the identity, properties and abundances of absorbers of incident solar radiation in the clouds. The causes of opacity variations in the nightside cloud cover and vertical gradients in the deep atmosphere bulk composition and its impact on static stability are also in need of critical studies. The knowledge gaps and questions about Venus and its atmosphere provide the incentive for obtaining the necessary measurements to understand the planet, which can provide some clues to learn about terrestrial exoplanets.     

The IMF pile-up regions near the Earth and Venus: lessons for the solar wind - Mars interaction

The Mars Global Surveyor mission has revealed that localized crustal paleomagnetic anomalies are a common feature of the Southern Hemisphere of Mars. The magnetometer measured small-scale magnetic fields associated with many individual magnetic anomalies have magnitudes ranging from hundreds to thousands nT at altitude above 120 km. That makes Mars globally different from both Venus and Earth. The data collected by Lunar Prospector near the Moon were interpreted as evidence that above regions of inferred strong surface magnetic fields on the Moon the SW flow is deflected, and a small-scale mini-magnetosphere exists under some circumstances. With a factor of 100 stronger magnetic fields at Mars and a lower SW dynamic pressure, those conditions offer the opportunity for a larger size of small `magnetospheres' which can be formed by the crustal magnetic fields. Outside the regions of the magnetic anomalies, the SW/Mars interaction is Venus-like. Thus, at Mars the distinguishing feature of the magnetic field pile-up boundary most likely varies from Venus-like to Earth-like above the crustal magnetic field regions. The observational data regarding the IMF pile-up regions near Venus and the Earth are initially reviewed. As long as the SW/Mars interaction remains like that at Venus, the IMF penetrates deep into the Martian ionosphere under the `overpressure' conditions. Results of numerical simulations and theoretical expectations regarding the temporal evolution of the IMF inside the Venus ionosphere and appearance of superthermal electrons are also reviewed and assessed.     

Solar Variability and Climate Impact on Terrestrial Planets

Some possible factors of climate changes and of long term climate evolution are discussed with regard of the three terrestrial planets, Earth, Venus and Mars. Two positive feedback mechanisms involving liquid water, i.e., the albedo mechanism and the greenhouse effect of water vapour, are described. These feedback mechanisms respond to small external forcings, such as resulting from solar or astronomical constants variability, which might thus result in large influences on climatic changes on Earth. On Venus, reactions of the atmosphere with surface minerals play an important role in the climate system, but the involved time scales are much larger. On Mars, climate is changing through variations of the polar axis inclination over time scales of ～10⁵–10⁶ years. Growing evidence also exists that a major climatic change happened on Mars some 3.5 to 3.8 Gigayears ago, leading to the disappearance of liquid water on the planet surface by eliminating most of the CO₂ atmosphere greenhouse power. This change might be due to a large surge of the solar wind, or to atmospheric erosion by large bodies impacts. Indeed, except for their thermospheric temperature response, there is currently little evidence for an effect of long-term solar variability on the climate of Venus and Mars. This fact is possibly due to the absence of liquid water on these terrestrial planets.     

HF-W Chronometry and Inner Solar System Accretion Rates

Models for the mechanisms of accretion of the terrestrial planets are re-examined using the experimental technique of high-precision isotope ratio mass spectrometry of tungsten (W). The decay of ¹⁸²Hf to ¹⁸²W (via ¹⁸²Ta) provides a new kind of radiometric chronometer of planet formation processes. Hafnium and W, the parent and daughter trace elements, are highly refractory; however, Hf is lithophile and strongly partitioned into the silicate portion of a planet, whereas W is moderately siderophile and preferentially partitioned into a coexisting metallic phase. More than 90% of terrestrial W has gone into the Earth's core during its formation. The residual silicate portion, the Earth's primitive mantle, has a Hf/W ratio in the range 10−40, an order of magnitude higher than chondritic (∼1.3). Tungsten isotopic data for the Earth and the Moon suggest that we can date a major event of planet formation: The Moon formed about 50 Myrs after the start of the solar system, providing strong support for the Giant Impact Theory of lunar origin. Recent simulations of this event imply that the Earth was probably only half formed at the time. From this we can deduce the planetary accretion rate. Tungsten isotope data for Mars provide evidence of a much shorter accretion interval, perhaps as little as 10 Myrs, but the rates for the Earth over the same time interval could have been comparable. The large W isotopic heterogeneities on Mars could only have been produced within the first 30 Myrs of the solar system. Large-scale mixing, e.g. from convective overturn, as is thought to drive the Earth's plates, must be absent from Mars. Limitations of the method such as 1) cosmogenic ¹⁸²Ta effects on lunar samples, 2) incomplete mixing of debris to cause W isotope heterogeneity on the Moon, and 3) initial ¹⁸²Hf/¹⁸⁰Hf heterogeneities of the early solar system are critically discussed. This revised version was published online in June 2006 with corrections to the Cover Date.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Are There Chemical Gradients in the Inner Solar System?

The solar system is apparently stratified with regard to the contents of volatile constituents, as judged from the rocky, volatile-poor inner solar system planets and meteorites and the huge volatile-rich outer planets. However, beyond this gross structure there is no evidence for a systematic increase of the volatiles' abundances with distance from the Sun. Although meteorites show comparatively large differences in volatile element contents they also differ in many other respects, such as Mg/Si-ratios, bulk Fe and refractory element contents. These variations reflect variations in the nebular environment from which meteorites formed. The various conditions of meteorite formation cannot, however, be related in a simple way to heliocentric distances. There are also no systematic variations in the chemistry of the inner planets Mercury, Venus, Earth, Moon, Mars, and including the fourth largest asteroid Vesta, that could be interpreted as a relationship between volatility and composition. Although Mars (as judged from the composition of Martian meteorites) is more oxidized and contains more volatile elements than Earth, this trend cannot be extrapolated to the dry volatile poor Vesta (sampled by HED meteorites) in the asteroid belt. If the Earth-Mars trend reflects global inner solar system gradients then Vesta must have formed inside Earth's orbit and moved out later to its present location. The quality of Mercury and Venus composition data is not sufficient to allow reliable extrapolation to distances closer to the Sun. Recent nebula models predict small temperature gradients in the inner solar system supporting the view that no large variations in volatile element contents of inner solar system materials are expected. This revised version was published online in June 2006 with corrections to the Cover Date.     

Thermal Evolution and Magnetic Field Generation in Terrestrial Planets and Satellites

Of the terrestrial planets, Earth and Mercury have self-sustained fields while Mars and Venus do not. Magnetic field data recorded at Ganymede have been interpreted as evidence of a self-generated magnetic field. The other icy Galilean satellites have magnetic fields induced in their subsurface oceans while Io and the Saturnian satellite Titan apparently are lacking magnetic fields of internal origin altogether. Parts of the lunar crust are remanently magnetized as are parts of the crust of Mars. While it is widely accepted that the magnetization of the Martian crust has been caused by an early magnetic field, for the Moon alternative explanations link the magnetization to plasma generated by large impacts. The necessary conditions for a dynamo in the terrestrial planets and satellites are the existence of an iron-rich core that is undergoing intense fluid motion. It is widely accepted that the fluid motion is caused by convection driven either by thermal buoyancy or by chemical buoyancy or by both. The chemical buoyancy is released upon the growth of an inner core. The latter requires a light alloying element in the core that is enriched in the outer core as the solid inner core grows. In most models, the light alloying element is assumed to be sulfur, but other elements such as, e.g., oxygen, silicon, and hydrogen are possible. The existence of cores in the terrestrial planets is either proven beyond reasonable doubt (Earth, Mars, and Mercury) or the case for a core is compelling as for Venus and the Moon. The Galilean satellites Io and Ganymede are likely to have cores judging from Galileo radio tracking data of the gravity fields of these satellites. The case is less clear cut for Europa. Callisto is widely taken as undifferentiated or only partially differentiated, thereby lacking an iron-rich core. Whether or not Titan has a core is not known at the present time. The terrestrial planets that do have magnetic fields either have a well-established inner core with known radius and density such as Earth or are widely agreed to have an inner core such as Mercury. The absence of an inner core in Venus, Mars, and the Moon (terrestrial bodies that lack fields) is not as well established although considered likely. The composition of the Martian core may be close to the Fe–FeS eutectic which would prevent an inner core to grow as long as the core has not cooled to temperatures around 1500 Kelvin. Venus may be on the verge of growing an inner core in which case a chemical dynamo may begin to operate in the geologically near future. The remanent magnetization of the Martian and the lunar crust is evidence for a dynamo in Mars’ and possibly the Moon’s early evolution and suggests that powerful thermally driven dynamos are possible. Both the thermally and the chemically driven dynamo require that the core is cooled at a sufficient rate by the mantle. For the thermally driven dynamo, the heat flow from the core into the mantle must by larger than the heat conducted along the core adiabat to allow a convecting core. This threshold is a few mW?m^?2 for small planets such as Mercury, Ganymede, and the Moon but can be as large as a few tens mW?m^?2 for Earth and Venus. The buoyancy for both dynamos must be sufficiently strong to overcome Ohmic dissipation. On Earth, plate tectonics and mantle convection cool the core efficiently. Stagnant lid convection on Mars and Venus are less efficient to cool the core but it is possible and has been suggested that Mars had plate tectonics in its early evolution and that Venus has experienced episodic resurfacing and mantle turnover. Both may have had profound implications for the evolution of the cores of these planets. It is even possible that inner cores started to grow in Mars and Venus but that the growth was frustrated as the mantles heated following the cessation of plate tectonics and resurfacing. The generation of Ganymede’s magnetic field is widely debated. Models range from magneto-hydrodynamic convection in which case the field will not be self-sustained to chemical and thermally-driven dynamos. The wide range of possible compositions for Ganymede’s core allows models with a completely liquid near eutectic Fe–FeS composition as well as models with Fe inner cores or cores in with iron snowfall.     

The Delivery of Water During Terrestrial Planet Formation

The planetary building blocks that formed in the terrestrial planet region were likely very dry, yet water is comparatively abundant on Earth. Here we review the various mechanisms proposed for the origin of water on the terrestrial planets. Various in-situ mechanisms have been suggested, which allow for the incorporation of water into the local planetesimals in the terrestrial planet region or into the planets themselves from local sources, although all of those mechanisms have difficulties. Comets have also been proposed as a source, although there may be problems fitting isotopic constraints, and the delivery efficiency is very low, such that it may be difficult to deliver even a single Earth ocean of water this way. The most promising route for water delivery is the accretion of material from beyond the snow line, similar to carbonaceous chondrites, that is scattered into the terrestrial planet region as the planets are growing. Two main scenarios are discussed in detail. First is the classical scenario in which the giant planets begin roughly in their final locations and the disk of planetesimals and embryos in the terrestrial planet region extends all the way into the outer asteroid belt region. Second is the Grand Tack scenario, where early inward and outward migration of the giant planets implants material from beyond the snow line into the asteroid belt and terrestrial planet region, where it can be accreted by the growing planets. Sufficient water is delivered to the terrestrial planets in both scenarios. While the Grand Tack scenario provides a better fit to most constraints, namely the small mass of Mars, planets may form too fast in the nominal case discussed here. This discrepancy may be reduced as a wider range of initial conditions is explored. Finally, we discuss several more recent models that may have important implications for water delivery to the terrestrial planets.     

Effects of Low Energetic Neutral Atoms on Martian and Venusian Dayside Exospheric Temperature Estimations

The heating of the upper atmospheres and the formation of the ionospheres on Venus and Mars are mainly controlled by the solar X-ray and extreme ultraviolet (EUV) radiation (λ = 0.1–102.7 nm and can be characterized by the 10.7 cm solar radio flux). Previous estimations of the average Martian dayside exospheric temperature inferred from topside plasma scale heights, UV airglow and Lyman-α dayglow observations of up to ∼500 K imply a stronger dependence on solar activity than that found on Venus by the Pioneer Venus Orbiter (PVO) and Magellan spacecraft. However, this dependence appears to be inconsistent with exospheric temperatures (<250 K) inferred from aerobraking maneuvers of recent spacecraft like Mars Pathfinder, Mars Global Surveyor and Mars Odyssey during different solar activity periods and at different orbital locations of the planet. In a similar way, early Lyman-α dayglow and UV airglow observations by Venera 4, Mariner 5 and 10, and Venera 9–12 at Venus also suggested much higher exospheric temperatures of up to 1000 K as compared with the average dayside exospheric temperature of about 270 K inferred from neutral gas mass spectrometry data obtained by PVO. In order to compare Venus and Mars, we estimated the dayside exobase temperature of Venus by using electron density profiles obtained from the PVO radio science experiment during the solar cycle and found the Venusian temperature to vary between 250–300 K, being in reasonable agreement with the exospheric temperatures inferred from Magellan aerobraking data and PVO mass spectrometer measurements. The same method has been applied to Mars by studying the solar cycle variation of the ionospheric peak plasma density observed by Mars Global Surveyor during both solar minimum and maximum conditions, yielding a temperature range between 190–220 K. This result clearly indicates that the average Martian dayside temperature at the exobase does not exceed a value of about 240 K during high solar activity conditions and that the response of the upper atmosphere temperature on Mars to solar activity near the ionization maximum is essentially the same as on Venus. The reason for this discrepancy between exospheric temperature determinations from topside plasma scale heights and electron distributions near the ionospheric maximum seems to lie in the fact that thermal and photochemical equilibrium applies only at altitudes below 170 km, whereas topside scale heights are derived for much higher altitudes where they are modified by transport processes and where local thermodynamic equilibrium (LTE) conditions are violated. Moreover, from simulating the energy density distribution of photochemically produced moderately energetic H, C and O atoms, as well as CO molecules, we argue that exospheric temperatures inferred from Lyman-α dayglow and UV airglow observations result in too high values, because these particles, as well as energetic neutral atoms, transformed from solar wind protons into hydrogen atoms via charge exchange, may contribute to the observed planetary hot neutral gas coronae. Because the low exospheric temperatures inferred from neutral gas mass spectrometer and aerobraking data, as well as from CO⁺ ₂ UV doublet emissions near 180–260 nm obtained from the Mars Express SPICAM UV spectrograph suggest rather low heating efficiencies, some hitherto unidentified additional IR-cooling mechanism in the thermospheres of both Venus and Mars is likely to exist. An erratum to this article can be found at     

Ion Acceleration and Outflow from Mars and Venus: An Overview

Solar wind forcing of Mars and Venus results in outflow and escape of ionospheric ions. Observations show that the replenishment of ionospheric ions starts in the dayside at low altitudes (??300?C800 km), ions moving at a low velocity (5?C10 km/s) in the direction of the external/ magnetosheath flow. At high altitudes, in the inner magnetosheath and in the central tail, ions may be accelerated up to keV energies. However, the dominating energization and outflow process, applicable for the inner magnetosphere of Mars and Venus, leads to outflow at energies ??5?C20 eV. The aim of this overview is to analyze ion acceleration processes associated with the outflow and escape of ionospheric ions from Mars and Venus. Qualitatively, ion acceleration may be divided in two categories:

1. Modest ion acceleration, leading to bulk outflow and/or return flow (circulation).
2. Acceleration to well over escape velocity, up into the keV range.

In the first category we find a processes denoted ??planetary wind??, the result of e.g. ambipolar diffusion, wave enhanced planetary wind, and mass-loaded ion pickup. In the second category we find ion pickup, current sheet acceleration, wave acceleration, and parallel electric fields, the latter above Martian crustal magnetic field regions. Both categories involve mass loading. Highly mass-loaded ion energization may lead to a low-velocity bulk flow??A consequence of energy and momentum conservation. It is therefore not self-evident what group, or what processes are connected with the low-energy outflow of ionospheric ions from Mars. Experimental and theoretical findings on ionospheric ion acceleration and outflow from Mars and Venus are discussed in this report.     

Venus: The Atmosphere,Climate, Surface,Interior and Near-Space Environment of an Earth-Like Planet

This is a review of current knowledge about Earth’s nearest planetary neighbour and near twin, Venus. Such knowledge has recently been extended by the European Venus Express and the Japanese Akatsuki spacecraft in orbit around the planet; these missions and their achievements are concisely described in the first part of the review, along with a summary of previous Venus observations. The scientific discussions which follow are divided into three main sections: on the surface and interior; the atmosphere and climate; and the thermosphere, exosphere and magnetosphere. These reports are intended to provide an overview for the general reader, and also an introduction to the more detailed topical surveys in the following articles in this issue, where full references to original material may be found.     

Morphological Biosignatures in Early Terrestrial and Extraterrestrial Materials

Biosignatures in early terrestrial rocks are highly relevant in the search for traces of life on Mars because the early geological environments of the two planets were, in many respects, similar and, thus, the potential habitats for early life forms were similar. However, the identification and interpretation of biosignatures in ancient terrestrial rocks has proven contentious over the last few years. Recently, new investigations using very detailed field studies combined with highly sophisticated analytical techniques have begun to document a large range of biosignatures in Early Archaean rocks. Early life on Earth was diversified, widespread and relatively evolved, but its traces are generally, but not always, small and subtle. In this contribution I use a few examples of morphological biosignatures from the Early-Mid Archaean to demonstrate their variety in terms of size and type: macroscopic stromatolites from the 3.443 Ga Strelley Pool Chert, Pilbara; a meso-microscopic microbial mat from the 3.333 Ga Josefsdal Chert, Barberton; microscopic microbial colonies and a biofilm from the 3.446 Ga Kitty’s Gap Chert, Pilbara; and microscopic microbial corrosion pits in the glassy rinds of 3.22–3.48 Ga pillow lavas from Barberton. Some macroscopic and microscopic structures may be identifiable in an in situ robotic mission to Mars and in situ methods of organic molecule detection may be able to reveal organic traces of life. However, it is concluded that it will probably be necessary to return suitably chosen Martian rocks to Earth for the reliable identification of signs of life, since multiple observational and analytical methods will be necessary, especially if Martian life is significantly different from terrestrial life.     

Origin of planetary atmospheres

The near absence of noble gases on earth, other than those of radioactive origin, indicates that the earth was formed by the accumulation of planetesimals; this process systematically excluded all constituents that did not enter into the solid phase. The atmosphere and the ocean with many of its dissolved salts have arisen from gases emitted from the earth's interior, a process that continues today. The oxygen in the earth's atmosphere plus a greater quantity that has been removed from the atmosphere to oxidize geologic materials, has arisen mainly from a small excess of photosynthesis over decay of organic material. The atmospheres of Mars and Venus have probably arisen in a manner similar to the atmosphere on earth, by emission from the planetary interiors. However, they have not received any oxygen from photosynthesis and so are nearly oxygen free. Mars has very little water in its atmosphere, and this can be explained by its lower than freezing average surface temperature. Venus also has very little water, and this requires an ad hoc explanation; one possibility is that Venus was formed from much drier planetesimals than was the earth. Mercury and the moon are virtually without atmospheres. Although some gases may be emitted from their interiors, they are presumably rapidly lost by escape. Whatever atmosphere they possess is probably due to the neutralized solar wind that impinges upon them. The outer planets retained volatiles, including hydrogen and helium, to a much greater extent than did the terrestrial planets.     

An Oxygen Isotope Mixing Model for the Accretion and Composition of Rocky Planets

The oxygen isotope systematics in planetary and nebular matter are used to constrain the types of nebular material accreted to form a planet. The basic assumption of this model is that the mean oxygen isotopic composition of a planet is determined by the weighted mean oxygen isotopic composition of nebular matter accreted by the planet. Chondrites are taken as representatives of nebular matter. The chemical composition (which determines core size, mantle oxidation state, density, moment of inertia) of a planet results from the weighted mean compositions of the accreted nebular material, once the mass fractions of the different types of accreting matter are known. Here some results for Earth, Moon, Mars, and Vesta are discussed. The model implies that loss of volatile elements, such as alkalis and halogens, occurs during accretion and early planetary differentiation (e. g., by catastrophic impacts). The possible depletion mechanisms of moderately volatile elements are discussed. This revised version was published online in June 2006 with corrections to the Cover Date.