A neutral gas mass spectrometer to measure the chemical composition of the stratosphere

The Polar Balloon Atmospheric Composition Experiment (P-BACE) is a new generation of neutral gas mass spectrometer based on the time-of-flight principle. P-BACE is the scientific experiment on the Mars Environment Analog Platform (MEAP) flown successfully on a balloon mission in summer 2008. The MEAP mission was flown with a 334,000 m³ helium balloon in the stratosphere on a semicircular trajectory from northern Sweden around the North Pole to Canada using the summer northern hemispheric wind current. The atmospheric conditions at an atmospheric altitude of 35–40 km are remarkably similar to those on the surface of Mars and thus the balloon mission was an ideal testbed for our mass spectrometer P-BACE. Originally this instrument was designed for in situ measurements of the chemical composition of the Martian atmosphere.P-BACE has a unique mass range from 0 to 1000 amu/q with a mass resolution m/Δm (FWHM) > 1000, and the dynamic range is at least six orders of magnitude. During this experiment, the acquisition of one mass spectrum is a sum of 65,535 single spectra, recorded in a time frame of 66 s.The balloon mission lasted 5 days and had successfully demonstrated the functionality of the P-BACE instrument during flight conditions. We had recorded more than 4500 mass spectra. With little modifications, P-BACE can be used on a planetary mission for Mars, but for example also for Venus or Mercury, if placed on a satellite.     

Quantitative determination of the outgassing water vapor concentrations surrounding space vehicles from ion mass spectrometer measurements

Outgassing from materials as well as deliberate gaseous and liquid releases create contaminant clouds around spacecraft that can degrade both instrumentation and measurements. This paper describes a new method for estimating outgassing water vapor concentrations around space vehicles. Water vapor ions measured in the course of a rocket experiment performed at Eglin AFB, Florida, on December 12, 1980 at 2311 UT are utilized to demonstrate the technique. The H₂O concentration near the payload's surface is calculated using the rate coefficient for the fast charge transfer process, O⁺ + H₂O + H₂O⁺ + O, the source of the observed water vapor ions. It is found that the measured H₂O⁺ ions were produced within 3–4 cm of the sampling plate's surface and that the average H₂O pressure over this distance was relatively constant on ascent at 8 × 10^?6 torr, within a factor two, implying a steady outgassing rate.     

Titan's atmosphere composition: certainties and speculations.

Firm results concerning the thermal structure, the composition, the seasonal effects of the atmosphere of Titan, as well as the superotation of its stratosphere are reviewed. The nature of the surface of the satellite, the possible presence of argon in the atmosphere and the structure and composition of clouds and aerosols are, among other topics, still speculative. The implications of the observed deuterium enrichment on the origin of ices in the outer part of the nebula are controversial.     

Radiation measurements aboard NASA ER-2 high altitude aircraft with the Liulin-4J portable spectrometer.

The risks to aircrew health posed by prolonged exposure to low levels of ionizing radiation at aircraft altitudes have recently received renewed attention. Civil and military aircraft currently on the drawing board are expected to operate at higher altitudes (>12 km) and fly longer ranges than do existing aircraft, thereby exposing their crews to higher levels of ionizing radiation, for longer periods of time. We are currently carrying out dosimetric measurements of the ionizing radiation environment at approximately 20 km altitude using portable Si detectors aboard NASA's two ER-2 high altitude research aircraft. The instruments, Liulin-4J, have been extensively calibrated at several particle accelerators. With these instruments, we can measure not only absorbed dose, but also variation of the absorbed dose as a function of time. We report radiation dose measurements as function of time, altitude, and latitude for several ER-2 missions.     

Partial pressures and nature of products. Application to the photolysis of PH3 and NH3 in the atmosphere of Jupiter and Saturn.

The photolysis of mixtures of gases containing NH3 or PH3 presents important differences mainly due to the strength of the X-H bond. On some examples, these differences are evidenced and the consequences for mixtures of gases containing these two compounds are shown: the photolysis of ammonia and ethylene mainly gives ethyl-, butyl- and hexylamine whereas the photolysis of phosphine and ethylene leads to ethyl- and vinylphosphine. When gaseous mixtures of NH3, PH3 and ethylene are photolyzed together, the presence of phosphine dramatically decreases the formation of nitrogen derivatives. The relevance of such lab studies to the atmospheres of Jupiter and Saturn is discussed.     

Satellite measurements of atmospheric composition

Since 1978 a number of satellite borne sensors have been used to measure the composition of the earth's atmosphere. These include the LIMS and SAMS instruments on the Nimbus 7 satellite (launched in October 1978), the SAGE instrument on the AEM2 satellite (launched in february 1979) and various instruments on the SME spacecraft (launched October 1981). For many species, these have provided the first abundance measurements with high spatial and temporal resolution and with global coverage. In this paper the composition measurements that have become available from these programs will be reviewed. The paper will then describe some recent studies that have made use of the new data. As it is the exclusive subject of another invited paper, ozone will not be discussed in in any detail.     

Models of Venus neutral upper atmosphere: Structure and composition

Models of the Venus neutral upper atmosphere, based on both in-situ and remote sensing measurements, are provided for the height interval from 100 to 3,500 km. The general approach in model formulation was to divide the atmosphere into three regions: 100 to 150 km, 150 to 250 km, and 250 to 3,500 km. Boundary conditions at 150 km are consistent with both drag and mass spectrometer measurements. A paramount consideration was to keep the models simple enough to be used conveniently. Available observations are reviewed. Tables are provided for density, temperature, composition (CO₂, O, CO, He, N, N₂, and H), derived quantities, and day-to-day variability as a function of solar zenith angle on the day- and nightsides.Estimates are made of other species, including O₂ and D. Other tables provide corrections for solar activity effects on temperature, composition, and density. For the exosphere, information is provided on the vertical distribution of normal thermal components (H, O, C, and He) as well as the hot components (H, N, C, O) on the day- and nightsides.     

Long-term (50 years) measurements of cosmic ray fluxes in the atmosphere

Since the middle of 1957 till present time the group of researchers of P.N. Lebedev Physical Institute of the Russian Academy of Sciences has carried out the regular balloon borne measurements of charged particle fluxes in the atmosphere. The measurements are performed at polar (northern and southern) and middle latitudes and cover the interval of heights from the ground level up to 30–35 km. Standard detectors of particles (gas-discharged counters) have been used. More than 80,000 measurements of cosmic ray fluxes in the atmosphere have been performed to the present time. In the data analysis the geomagnetic field and the Earth’s atmosphere are used as cosmic ray spectrometers.     

Observations with the SMM gamma-ray spectrometer

The Gamma Ray Spectrometer on the SMM satellite has observed solar cosmic energetic photon transients since 17 February 1980. Using the data available through 1981, new results have been obtained on ion acceleration phenomena in solar flares. It now is evident that both ion and electron acceleration can take place impulsively, simultaneously or within seconds of one another. That the impulsive acceleration process can produce ions with energies as high as GeV/nucleon is directly shown by observations of neutrons at the Earth with energies of several hundred MeV. These two facts and the relative timing of hard X-ray emissions provide new constraints on solar flare particle acceleration theory. New flare spectra have also been observed showing new nuclear γ-ray lines not previously observed from ²⁴Mg, ²⁰Ne and ⁵⁶Fe as well as from other elements. These spectral observations provide new information on the relative abundances of the accelerated and target nuclei. Following a review of the solar data and implications for flare theories we will also give a brief review of the results obtained on nonsolar γ-ray bursts. Most such bursts have photon spectra extending to MeV energies but with little, if any, evidence for spectral features.     

Radiation analysis for manned missions to the Jupiter system.

An analysis for manned missions targeted to the Jovian system has been performed in the framework of the NASA RASC (Revolutionary Aerospace Systems Concepts) program on Human Exploration beyond Mars. The missions were targeted to the Jupiter satellite Callisto. The mission analysis has been divided into three main phases, namely the interplanetary cruise, the Jupiter orbital insertion, and the surface landing and exploration phases. The interplanetary phase is based on departure from the Earth-Moon L1 point. Interplanetary trajectories based on the use of different propulsion systems have been considered, with resulting overall cruise phase duration varying between two and five years. The Jupiter-approach and the orbital insertion trajectories are considered in detail, with the spacecraft crossing the Jupiter radiation belts and staying around the landing target. In the surface exploration phase the stay on the Callisto surface is considered. The satellite surface composition has been modeled based on the most recent results from the GALILEO spacecraft. In the transport computations the surface backscattering has been duly taken into account. Particle transport has been performed with the HZETRN heavy ion code for hadrons and with an in-house developed transport code for electrons and bremsstrahlung photons. The obtained doses have been compared to dose exposure limits.     

Eddy mixing and composition variations of earth's upper atmosphere

Solar radiation intensity variations lead to eddy diffusion coefficient variations and are closely connected with variations of both neutral atmosphere constituents in which only eddy mixing (helium) plays a determining part and those in which photochemical processes (atomic oxygen) are also significant. A possible mechanism of the semiannual density variation occurrence in the Earth's upper atmosphere is obtained.     

Cratering records of the satellites of Jupiter and Saturn

The surfaces of most of the satellites of Jupiter and Saturn show marks of large-meteoroid impacts produced over much of solar system history and partly stemming from the early post-accretional heavy bombardment. An analysis of the crater size distributions shows that (i) crater densities on the most ancient terrains are comparable to those found on the lunar highlands, (ii) crater size distributions differ somewhat from those in the inner solar system but exhibit striking similarities in shape, (iii) the crater size distributions on all terrain types from oldest to youngest are very similar, i. e. the underlying impactor size distribution does not seem to have changed over time, (iv) there is no obvious difference in crater densities between apex and antapex parts of the satellites, (v) the cratering record can better be explained by impacts from bodies in planetocentric orbits rather than by bodies in heliocentric orbits.     

Force balance in the magnetospheres of Jupiter and Saturn

Spacecraft measurements of the plasma populations and magnetic fields near Jupiter and Saturn have revealed that large magnetospheres surround both planets. Magnetic field measurements have indicated closed field line topologies in the dayside magnetospheres of both planets while plasma instruments have shown these regions to be populated by both hot and cold plasma components convected azimuthally in the sense of planetary rotation. By using published data from the Voyager Plasma Science (PLS), Low Energy Charged Particle (LECP), and Magnetometer (MAG) instruments, it is possible to investigate the validity of the time stationary MHD momentum equation in the middle magnetospheres of Jupiter and Saturn. At Saturn, the hot plasma population is negligible in the dynamic sense and the centrifugal force of the cold rotating plasma appears to balance the Lorentz force. At Jupiter, the centrifugal force balances ～25% of the Lorentz force. The remaining inward Lorentz force is balanced by pressure gradients in the hot, high-β plasma of the Jovian magnetodisk.     

LDEF: Chemical and isotopic measurements of micrometeoroids by SIMS

Described is a passive experiment for LDEF (Long Duration Exposure Facility) to measure the chemical and isotopic composition of interplanetary dust particles >10⁻¹⁰g for most of the major elements expected to be present. The detector consists of Ge targets covered with a metallized plastic film. During impact micrometeoroid vapor and melt are deposited on the underside of the foil which can be analyzed be secondary ion mass spectroscopy (SIMS) after the return of LDEF. Additional information on projectile mass, velocity and density can be obtained from the study of the penetration hole and the impact crater. Criteria for the choice of materials are given and first results of impact simulation experiments are reported which demonstrate the viability of the basic concept and show that isotopic data can be obtained from the deposits.     

Observations of the Galilean satellites of Jupiter from Earth orbit

In April 1972 OAO-2 obtained broadband filter measurements of the Galilean satellites from 2100 to 4300 Å. All four bodies were shown to have low albedos declining towards shorter wavelengths, thus constraining the proportions of their surfaces that could be covered by reflective frosts. Although the vast data return from Voyager spacecraft has for the first time permitted a detailed comparison of Galilean satellites with terrestrial planets, it has not removed the need for continuing long time-base observations of the former. Since January 1978, IUE has repeatedly obtained Galilean spectra within the range 1150 to 3200 Å. Observations of Io have placed an upper limit on the global abundance of SO₂ in its atmosphere. Spectral variations with phase have allowed spatial mapping of surface reflectance in the case of Io, and may enable volcanic activity to be monitored.     

Hydrogen cyanide polymers from the impact of comet P/Shoemaker-Levy 9 on Jupiter.

Hydrogen cyanide polymers--heterogeneous solids ranging in color from yellow to orange to brown to black--may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orange-brown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to alpha-amino acids. Other polymers and multimers with ladder structures derived from HCN would also be present and might well be the source of the many nitrogen heterocycles, adenine included, detected by thermochemolytic analysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter could therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized from freshly formed HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.