Composition of the Venus atmosphere below 100 km altitude

Our current knowledge on the composition of the Venus atmosphere in the altitude range from the surface to 100 km is compiled. Gases that have been measured, and whose mixing ratios are assumed to be constant with altitude, are CO₂, N₂, He, Ne, Ar, and Kr. Gases that have been identified in the lower and/or middle atmosphere, but whose mixing ratios may depend on altitude, latitude and/or local time, are CO, H₂O, HCl, HF, and SO₂. Conflicting data or only upper limits exist on some important trace gases, such as O₂, H₂, and Cl₂. The latter two are key constituents in the photochemistry of the middle atmosphere of Venus. The chapter concludes with a listing of the isotopic abundances of elements measured in the Venus atmosphere.     

吉林陨石稀有气体的分布特征及其热历史的初步探讨

吉林陨石的宇成和放射成因稀有气体存在大幅度的变化.宇成3He、20, 21, 22Ne和38Ar_c之间彼此近似线性相关, 放射成因4He和40Ar之间近似线性相关.放射成因4He、40Ar与作为陨星深度标尺的宇成60Co间近似线性相关, 但与作为吉林陨石母体深度标尺的21Ne之间不存在线性相关.上述事实表明:4He和40Ar在吉林陨石中的分布是不均匀的, 在吉林母体中的分布是不规则的, 而在吉林流星中, 由表面至中心呈现递增的倾向.我们试图用吉林陨石母体与小行星间的碰撞效应解释用4He和40Ar的上述独特分布特征.      

Mass spectrometry in the stratosphere

During the last few years a gas expansion system, combined with a mass spectrometer has been developed and successfully flown in the stratosphere. Neutral gas particles are formed into a molecular beam which traverses the ion source of the mass spectrometer without wall interactions. Vertical profiles of constituents such as H₂O, CO₂ and O₃ have been measured in the altitude range of 20 to 40 km during balloon descents. Isotopes of major atmospheric gases (N₂, O₂, Ar) provided in-flight calibration standards.Before each flight the mass spectrometer system was calibrated in the laboratory for many gases of interest, including ozone. Mixing ratios of ozone determined from recent flights have accuracies of better than 5%. The sensitivity of the system was sufficiently high to detect, in addition, the heavy isotope of ozone at mass 50. A pronounced enhancement of heavy ozone in the upper stratosphere has been found. The mass spectrometer system provides the unique opportunity to perform in the stratospherein-situ measurements combined with isotopic studies.     

我国某些球粒陨石及中铁陨石稀有气体的同位素丰度

本文测定了剑阁球粒陨石、岩庄球粒陨石、亳县球粒陨石及渭源中铁陨石和新近降落的东乌珠穆沁中铁陨石的稀有气体同位素丰度，根据He、Ne及Ar的测定结果计算宇宙射线暴露年龄，剑阁、岩庄及亳县球粒陨石的宇宙射线暴露年龄分别为5．8Ma、2．5Ma及38．0Ma，东乌珠穆沁及渭源中铁陨石分别为172Ma及17Ma．     

Neutral upper atmospheres of Venus and Mars

Numerous measurements of the neutral upper atmosphere above 100 km have been made from spacecraft over Venus and over Mars. The Venus exospheric temperatures are unexpectedly low (less than 300°K near noon and less than 130°K near midnight). These very low temperatures may be partially caused by collisional excitation of CO₂ vibrational states by atomic oxygen and partially by eddy cooling. The Venus atmosphere is unexpectedly insensitive to solar EUV variability. On the other hand, the Martian dayside exospheric temperature varies from 150°K to 400°K over the 11-year solar cycle, where CO₂ 15-μm cooling may be less effective because of lower atomic oxygen mixing ratios. On Venus, temperature increases with altitude on the dayside (thermosphere), but decreases with altitude from 100 to 150 km on the nightside (cryosphere). However, dayside Martian temperatures near solar minimum for maximum planet-sun distance and low solar activity are essentially isothermal from 40 km to 200 km. During high solar activity, the thermospheric temperatures of Mars sharply increase. The Venus neutral upper atmosphere contains CO₂, O, CO, C, N₂, N, He, H, D and hot nonthermal H, O, C, and N, while the dayside Mars neutral upper atmosphere contains CO₂, O, O₂, CO, C, N₂, He, H, and Ar. There is evidence on Venus for inhibited day-to-night transport as well as superrotation of the upper atmosphere. Both atmospheres have substantial wave activity. Various theoretical models used to interpret the planetary atmospheric data are discussed.     

Production of hydrocarbons and nitriles by electrical processes in Titan's atmosphere.

Although lightning has not been observed in Titan's atmosphere, the presence of methane rain in the troposphere suggests the possibility of electrical activity in the form of corona and/or lightning discharges. Here we examine the chemical effects of these electrical processes on a Titan simulated atmosphere composed of CH4 in N2 at various mixing ratios. Corona discharges were simulated in two different experimental arrays. For the detection of reactive intermediates we used a mass spectrometer to study the main positive ions arising by bombarding low-energy electrons from a hot filament into low-pressure methane. The final stable products, generated by applying a high voltage in a coaxial reactor with either positive or negative polarity, were separated and detected by gas chromatography-Fourier transform infrared spectroscopy and electron impact mass spectrometry (GC-FTIR-MS). Lightning discharges were simulated by a hot and dense plasma generated by a Nd-YAG laser and the final products were separated and detected by GC-FTIR-MS. Corona discharges produce linear and branched hydrocarbons as well as nitriles whereas lightning discharges generate mainly unsaturated hydrocarbons and nitriles. Lightning discharges are about 2 orders of magnitude more efficient in product formation than corona discharges.     

Mars ultraviolet imaging spectrometer experiment on the PLANET-B mission

An ultraviolet imaging spectrometer (UVS) has been developed for the PLANET-B spacecraft. The UVS instrument is composed of a grating spectrometer (UVS-G) and a D/H absorption cell photometer (UVS-P). The UVS-G is a flat-field type spectrometer measuring optical emissions in the FUV and MUV range between 115 nm and 310 nm with a spectral resolution of 2 – 3 nm. The UVS-P is a photometer detecting hydrogen (H) and deuterium (D) Lyman α emissions separately by an absorption cell technique. Scientific targets of the UVS experiment are the investigation of (1) hydrogen and oxygen coronas around Mars, (2) the D/H ratio in the upper atmosphere, (3) dayglow, (4) aurora and nightglow, (5) dust, clouds and ozone, and (6) the surface composition of Phobos and Deimos.     

Models of Venus neutral upper atmosphere: Structure and composition

Models of the Venus neutral upper atmosphere, based on both in-situ and remote sensing measurements, are provided for the height interval from 100 to 3,500 km. The general approach in model formulation was to divide the atmosphere into three regions: 100 to 150 km, 150 to 250 km, and 250 to 3,500 km. Boundary conditions at 150 km are consistent with both drag and mass spectrometer measurements. A paramount consideration was to keep the models simple enough to be used conveniently. Available observations are reviewed. Tables are provided for density, temperature, composition (CO₂, O, CO, He, N, N₂, and H), derived quantities, and day-to-day variability as a function of solar zenith angle on the day- and nightsides.Estimates are made of other species, including O₂ and D. Other tables provide corrections for solar activity effects on temperature, composition, and density. For the exosphere, information is provided on the vertical distribution of normal thermal components (H, O, C, and He) as well as the hot components (H, N, C, O) on the day- and nightsides.     

Atmosphere behavior in gas-closed mouse-algal systems: An experimental and modelling study

Concepts of biologically-based regenerative life support systems anticipate the use of photosynthetic organisms for air revitalization. However, mismatches in the rates of production and uptake of oxygen or carbon dioxide between the crew and the plants will lead to an accumulation or depletion of these gases beyond tolerable limits. One method for correcting these atmospheric changes is to use physicochemical devices. This would conflict with the constraint of minimal size and weight imposed upon the successful development of a competitive bioregenerative system. An alternate control strategy is based upon reducing the gas exchange mismatch by manipulation of those environmental parameters known to affect plant or algae gas exchange ratios. We have initiated a research program using a dual approach of mathematical modelling and laboratory experimentation aimed at examining the gas exchange characteristics of artificial animal/plant systems closed to the ambient atmosphere. Our goal is to develop control techniques and management strategies for maintaining the atmospheric levels of carbon dioxide and oxygen at physiological levels. A mathematical model simulating the atmospheric behavior in these systems has been developed and an experimental gas-closed system has been constructed. These will be described and preliminary results will be presented.     

微等离子体转化二氧化碳发射光谱诊断

火星大气层的主要成分为二氧化碳，如果能够利用低温等离子体方法高效分解二氧化碳，使其转化为氧气和一氧化碳加以利用，可以大幅降低航天员生命保障相关载荷长途运输的成本，进一步提高生命保障能力。低温等离子体放电过程中会产生大量活性组分，可以在数百度温度下实现二氧化碳的高效解离，是具有很大潜力的二氧化碳解离与转化方式。设计了一种尺度在亚毫米级、功率输入为数瓦的直流微槽等离子体反应器，可以在较低气体温度下实现二氧化碳分解。测量了反应器电流、功率等放电参数，采用发射光谱确定了体系中激发态组分，分析了激发态粒子谱线强度随输入电压、稀释气体比例等反应器工作参数变化，利用氮气分子振转谱带测量了等离子体放电区振动温度和气体温度。研究表明，添加氩、氦、氮气均可以增强二氧化碳的分解，添加氦气可以促进二氧化碳的电离过程。稀释气体激发态因具有高能量，可以通过潘宁解离通道增强二氧化碳分解。氦组分激发态的能量高于二氧化碳电离能，可以促进二氧化碳的电离反应。微等离子体内存在强烈的振动 平动非平衡现象：振动温度约为4400~4800K，而气体温度仅为450 ~600K，表明可以通过合理的放电和结构设计，定向将能量注入到振动态，从而进一步促进二氧化碳的振动解离。     

Double strand breaks in the DNA of Bacillus subtilis cells irradiated by heavy ions.

Cells of Bacillus subtilis strain TKJ 8431 in stationary phase were irradiated with X-rays (150 kV at DLR) or heavy ions (Ne, Ar, Pb with residual energies between 3 and 15 MeV/u at GSI). The action cross section for the formation of double strand breaks in the DNA of the irradiated cells follows a similar dependence on mass and energy of the ions as has been found for various biological endpoints, e.g. inactivation, mutagenesis and repair efficacy.     

HCN formation under electron impact: experimental studies and application to Neptune's atmosphere.

Laboratory experiments simulating organic synthesis in Neptune's atmosphere have been performed. We have submitted to a spark discharge gaseous mixtures containing 9 mbar of molecular nitrogen and 3 mbar of methane (the p(N2)/p(CH4) ratio is compatible with upper limits in Neptune's stratosphere) with varying quantities of molecular hydrogen. The spark discharge is used to model the energetic electrons produced by the impact of cosmic rays on the high atmosphere of Neptune. HCN is synthesized in the described experimental conditions, even with a low mixing ratio of molecular nitrogen. Studying the variation of HCN production with the initial composition of the gas mixture and extrapolating to high mixing ratio of molecular hydrogen allows to estimate HCN production in Neptune's atmosphere. The computed HCN production flux is 7x10(7) m-2 s-1, which is two orders of magnitude lower than the value predicted by chemical models for an internal source of N atoms. The major uncertainty in our extrapolation is the energetic distribution of electrons, implicitly assumed comparable in the discharge and in Neptune's atmosphere. We note that this distribution is also a source of uncertainty in chemical models. The chemical mechanism responsible for the local formation of HCN in the stratosphere probably occurs in the reactor too. We propose a simple characterization of the spark discharge. We thus link the molecular nitrogen dissociation cross section by electron impact to the measured parameters of the experiments (current, voltage, initial partial pressures) and to the resulting HCN partial pressures. However, other laboratory experiments with larger hydrogen pressures, requiring a more powerful electric source, have to be performed to yield a value of the cross section.     

Comparative neutral composition instrumentation and new results

Composition and gas density measurement at all altitudes in the atmospheres of earth and other planets are made by mass spectrometers. Because of the impartiality and large dynamic range they are particularly favored for exploratory missions. Measurements of trace constituents, inert gases and height profiles, especially below clouds, are objectives where mass spectrometry is most useful. Significant advances have been made in recent years in development of light weight automated instruments. Experiments conducted in rarified atmospheres have been more successful or results were less controversial than in attempts to analyze high pressure atmospheres. Gas sampling and conditioning techniques are highly specific because of measurement environments and engineering constraints on the mission, and are usually the most critical elements in the experiment. Chemical sample enrichment and scrubbing for noble gas enhancement are additional sample conditioning techniques now employed. Dynamic range of more than 10⁸ is achievable. Reliable measurements of complex organic or chemically active trace constituents with mixing ratios of less than 10^?9 still require significant instrument development particularly where weight, power and sampling time are severely restricted. Adaptation of familiar and proven laboratory techniques for flight instruments is usually not straightforward and practical.     

Analysis of the ROSAT pointed observation of the hot DA white dwarf HS1234+4811

The ROSAT data of the hot DA white dwarf HS1234+4811 were analyzed in the framework of three different assumptions for the structure of the white dwarf's atmosphere. It could be excluded that the star has a homogeneously mixed photosphere consisting of helium and hydrogen only, but from ROSAT observations alone it is not possible to decide if the object has a stratified atmosphere with an ultrathin hydrogen layer (M_H ≈ 7 · 10⁻¹⁴M) on top of the He envelope or if heavier elements are responsible for the absorption in the soft X-ray region.     

Longitudinal distribution of thermospheric densities and ionization rates in the upper atmosphere of Mars at mid-latitude using MGS ACC data

The Accelerometer Experiment (ACC) onboard Mars Global Surveyor (MGS) measured 1600 density profiles in the upper atmosphere of Mars during aerobraking. These measurements reveal large-scale and small-scale structure in the thermosphere of Mars. Here, the measurements of mass density for 115 orbits (#P0670–P0789) from November 1 to 30, 1998, under spring equinox and medium solar activity conditions (average F_10.7 ∼ 137) during phase 2 of the aerobraking in the thermosphere of Mars at different altitudes and longitudes are presented for northern mid-latitude (17–42°N) in the dayside atmosphere using ACC onboard MGS. From these mass densities, the neutral densities of different gases are derived from their mixing ratios. Using these neutral densities, the longitudinal distribution of photoionization rates and photoelectron impact ionization rates are calculated at wavelength range 1–102.57 nm due to EUV and soft X-ray radiation under photochemical controlled region using Analytical Yield Spectrum approach (AYS). These conditions are appropriate for MGS Phase 2 aerobraking period from which the accelerometer data is used. Under the photochemical equilibrium condition, the electron density near the peak varies as the square root of the total peak ionization rate. Using this fact, an attempt is being made to estimate the mean primary and secondary peak electron density by averaging the longitudinal variations of total peak ionization rates in the northern mid-latitude (17–42°N) ionosphere of Mars, as there is no radio science measurement at this latitude region by MGS.     

Space observations of trace gases for climate studies

The paper considers the importance of trace gases in modulating the fluxes of solar and terrestrial radiation in the Earth's atmosphere, and the influence of these effects on the long-term climate. Present and future capabilities for observing and monitoring trace gases from spacecraft are surveyed.     

High resolution measurements of nightside ion troughs at venus: Evidence of electrodynamic perturbations

The Bennett rf ion mass spectrometer (OIMS) on the Pioneer Venus Orbiter was particularly designed to provide variable temporal resolution for measurements of thermal ion composition and density. An Explore-Adapt mode is used to obtain priority for measurement of most prominent ion species, and in a 2/16 configuration, the two dominant ions within the available range of 16 species are selectively sampled at the highest rate of 0.2 sec/sample. The high resolution measurements are combined with independent observations from the magnetic field (OMAG), neutral mass spectrometer (ONMS), and electron temperature (OETP) experiments to investigate sharply structured troughs in the low altitude nightside ion concentrations. The results indicate a close correlation between the structure in the ion distributions and the structured configuration of the magnetic field which is draped about the planet. In the regions of the ion depletions, sharp fluctuations in electron temperature and anomalous increases in the density of neutral gases indicate that the ion depletion may be associated either with dynamic perturbation in the ion and neutral flows, and/or local joule heating. The configuration of the ion flow/magnetic field draping and consequent electric fields for these events must be analyzed in detail to understand the relationships.     

Trace constituents measurements deduced from spectrometric observations on-board spacelab

The observation of infrared absorption lines by means of a grille spectrometer on board Spacelab 1 allows the determination of Co₂ and CO in the low thermosphere and in the middle atmosphere. Equal abundances of CO and CO₂ are found at 115 ± 5 km altitude. CO₂ is observed to depart from its homospheric volume mixing ratio near 100 km, dropping by a factor of 10,15 km higher. The CO largest number density is observed near 70 km altitude, close to the H Lyman alpha photoproduction peak.The analysis of one run dedicated to the observation of water vapor shows a middle atmospheric mixing ratio of this species within the limits : 3 to 8 ppmv up to 70 km altitude, with the indication of an increase from 30 to 50 km altitude. The H₂O mixing ratio drops very rapidly above 70 km.The comparison of the results from strong and weak H₂O and CO₂ lines shows the need to refine the line profile model.     

Experimental simulation of early Martian volcanic lightning.

A mixture of possible Martian volcanic gases were reproduced and irradiated by a high-energy infrared laser to reproduce the effects of lightning on the production of prebiotic molecules. The analysis of products were performed by a gas chromatograph interfaced in parallel with a FTIR-detector and a quadrupole mass spectrometer equipped with an electron impact and chemical ionization modes. The main products identified were hydrocarbons and an uncharacterized yellow film deposit. Preliminary results indicate the presence of hydrogen cyanide among the resultant compounds.