Water Reservoirs in Small Planetary Bodies: Meteorites,Asteroids, and Comets

Asteroids and comets are the remnants of the swarm of planetesimals from which the planets ultimately formed, and they retain records of processes that operated prior to and during planet formation. They are also likely the sources of most of the water and other volatiles accreted by Earth. In this review, we discuss the nature and probable origins of asteroids and comets based on data from remote observations, in situ measurements by spacecraft, and laboratory analyses of meteorites derived from asteroids. The asteroidal parent bodies of meteorites formed \(\leq 4\) Ma after Solar System formation while there was still a gas disk present. It seems increasingly likely that the parent bodies of meteorites spectroscopically linked with the E-, S-, M- and V-type asteroids formed sunward of Jupiter’s orbit, while those associated with C- and, possibly, D-type asteroids formed further out, beyond Jupiter but probably not beyond Saturn’s orbit. Comets formed further from the Sun than any of the meteorite parent bodies, and retain much higher abundances of interstellar material. CI and CM group meteorites are probably related to the most common C-type asteroids, and based on isotopic evidence they, rather than comets, are the most likely sources of the H and N accreted by the terrestrial planets. However, comets may have been major sources of the noble gases accreted by Earth and Venus. Possible constraints that these observations can place on models of giant planet formation and migration are explored.     

Cometary and interstellar dust grains: Analysis by ion microprobe mass spectrometry and other techniques

A survey of microanalytical measurements on interplanetary dust particles (IDPs) and interstellar dust grains from primitive meteorites is presented. Ion microprobe mass spectrometry with its capability to determine isotopic compositions of many elements on a m spatial scale has played a special role. Examples are measurements of H, N, and O isotopes and refrectory trace elements in IDPs, and C, N, Mg, and Si isotopes in interstellar silicon carbide grains, and C and N isotopes as well as H, N, Al and Si concentrations in interstellar graphite grams. Possible future instrumental developments are also outlined.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.     

Organic constituents of the carbonaceous chondrites

From a brief discussion of forms of meteorite carbon it is concluded that almost all the carbon in the carbonaceous chondrites is present as organic matter. Attempts to extract and identify this organic matter are then reviewed. It is shown that only 25 per cent has been extracted and only about 5 per cent chemically characterized. Of this 5 per cent most is a complex mixture of hydroxylated aromatic acids together with various hydrocarbons of the paraffin, naphthene and aromatic series. Small amounts of amino acids, sugars and fatty acids also are present. The possible chemical nature of the major fraction is discussed. It is suggested to be a mixture of high-molecular weight aromatic and hydrocarbon polymers.Possible sources of contamination of the meteorites are described and evidence indicating a general lack of organic contaminants is presented. It is concluded that most of the organic constituents are indigenous to the meteorites and are extra terrestial in origin. Synthetic processes for the compounds are mentioned and it is concluded that the organic material is probably of abiogenic origin.A brief review on studies of organized elements contained within the meteorites is presented. Difficulties of identification are discussed and photographs of some micro-structures of several carbonaceous chondrites are presented. No final conclusion about the nature of these objects is possible, but some appear to be various indigenous organic and mineral structures, while others are terrestrial contaminants.Contribution from the Chemistry Section, Space Science Division of Jet Propulsion Laboratory.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

Interstellar Reservoirs of Cometary Matter

We review the evidence for the products of interstellar chemistry in volatile cometary matter. We compare the organic inventory of star-forming cores with that measured in various comets and point out the similarities and differences. The conditions necessary to fractionate interstellar molecules in the heavier isotopes of H, C, O and N are summarised and compared to the measured fractionation ratios in cometary ices. We give a list of future measurements that would shed further light on the putative connection between cometary and interstellar molecules.     

Formation and Processing of Organics in the Early Solar System

Until pristine samples can be returned from cometary nuclei, primitive meteorites represent our best source of information about organic chemistry in the early solar system. However, this material has been affected by secondary processing on asteroidal parent bodies which probably did not affect the material now present in cometary nuclei. Production of meteoritic organic matter apparently involved the following sequence of events: Molecule formation by a variety of reaction pathways in dense interstellar clouds; Condensation of those molecules onto refractory interstellar grains; Irradiation of organic-rich interstellar-grain mantles producing a range of molecular fragments and free radicals; Inclusion of those interstellar grains into the protosolar nebula with probable heating of at least some grain mantles during passage through the shock wave bounding the solar accretion disc; Agglomeration of residual interstellar grains and locally produced nebular condensates into asteroid-sized planetesimals; Heating of planetesimals by decay of extinct radionuclides; Melting of ice to produce liquid water within asteroidal bodies; Reaction of interstellar molecules, fragments and radicals with each other and with the aqueous environment, possibly catalysed by mineral grains; Loss of water and other volatiles to space yielding a partially hydrated lithology containing a complex suite of organic molecules; Heating of some of this organic matter to generate a kerogen-like complex; Mixing of heated and unheated material to yield the meteoritic material now observed. Properties of meteoritic organic matter believed to be consistent with this scenario include: Systematic decrease of abundance with increasing C number in homologous series of characterisable molecules; Complete structural diversity within homologous series; Predominance of branched-chain isomers; Considerable isotopic variability among characterisable molecules and within kerogen-like material; Substantial deuterium enrichment in all organic fractions; Some fractions significantly enriched in nitrogen-15; Modest excesses of L-enantiomers in some racemisation-resistant molecules but no general enantiomeric preference. Despite much speculation about the possible role of Fischer-Tropsch catalytic hydrogenation of CO in production of organic molecules in the solar nebula, no convincing evidence for such material has been found in meteorites. A similarity between some meteoritic organics and those produced by Miller-Urey discharge synthesis may reflect involvement of common intermediates rather than the operation of electric discharges in the early solar system. Meteoritic organic matter constitutes a useful, but not exact, guide to what we shall find with in situ analytical and sample-return missions to cometary nuclei. This revised version was published online in June 2006 with corrections to the Cover Date.     

Perspectives on the Comet-Asteroid-Meteorite Link

We discuss the possibility that CI and CM carbonaceous chondrites are fragments of extinct cometary nuclei. Theoretical and observational work suggests that comets evolve into asteroids, and several extinct cometary nuclei are now suspected to be among the near Earth object population. This population is the most likely source of meteorites and consequently, we may expect that some meteorites are from extinct comets in this population. The mineralogy and chemistry of CI and CM chondrites is consistent with the view that they originate from asteroidal objects of carbonaceous spectral classes, and these objects in turn may have a cometary origin. We do not suggest that CI or CM chondrites are directly delivered by active comets during perihelion passage or that these chondrites come from cometary debris in meteor streams. Instead, we summarize arguments suggesting that CI and CM chondrites represent fragments of cometary nuclei which evolved into near Earth asteroids after losing their volatiles. This revised version was published online in June 2006 with corrections to the Cover Date.     

Primordial matter in the outer solar system: A study of its chemical composition from remote spectroscopic analysis

Our knowledge of the primordial matter from the objects of the outer solar system has made a considerable progress over the past years, in spite of the lack of any in situ measurements of these objects at the present time. The recent progress of ground-based instrumentation and the launch of the two Voyager fly-by missions have provided a huge amount of new informations about the origin and the evolution of the primitive Solar System objects.The most significant discoveries concerning the atmospheres of the Giant Planets can be summarized as follows: (1) there does not seem to be any differentiation in the internal structure of Jupiter during the planet's history; thus, the H₂/He ratio measured on Jupiter seems to be representative of the H/He ratio of the Primordial Nebula; (2) there is some evidence for a helium differentiation, relative to hydrogen, in Saturn's interior; (3) there seems to be a carbon enrichment on both Jupiter and Saturn by a factor about 2; this result is consistent with a model in which the planetary core is formed first, and the atmosphere accreted by this core in a second stage; (4) the D/H ratio measured on Jupiter should be representative of the D/H value in the Primordial Nebula, 4.5 billion years ago; this value is 2 to 5 times larger than the mean value measured in the local interstellar medium now; (5) Titan's atmosphere is dominated by nitrogen and contains traces of organic and prebiotic molecules (HCN, C₂N₂, HC₃N); the chemical composition of Titan's atmosphere could be favorable for the early stages of life development.The small bodies of the Solar System — asteroïds and comets — are still very poorly known. However they contain a key information about the physical and chemical properties of dust in the Primordial Nebula and the interstellar medium. With the launch of expected fly-by missions towards Comet Halley and, possibly, towards asteroïds, we may hope to know a new development of our understanding of these objects, comparable to the progress we have known on the Giant Planets over the past ten years.     

Origin,age, and composition of meteorites

This paper attempts to bring together and evaluate all significant evidence on the origin of meteorites.The iron meteorites seem to have formed at low pressures. Laboratory evidence shows that the absence of a Widmanstätten pattern in meteorites with > 16% Ni cannot be attributed to high pressures, but to supercooling or an unusually fast cooling rate for these meteorites, which prevented the development of a pattern. The presence of tridymite in the Steinbach siderophyre provides further, direct proof that the Widmanstätten pattern can form at pressures less than 3 kb. Neither diamond, nor cliftonite, nor cohenite are reliable pressure indicators in meteorites. Diamonds were formed by shock while cliftonite may have been derived from a cubic carbide such as Fe₄C. Cohenite is apparently stabilized by kinetic rather than thermodynamic factors. Several lines of evidence suggest that the irons come from more than one parent body, perhaps as many as four.The frequency of pallasites is perfectly consistent with an origin in the transition zone between core and mantle of the parent body. Hybrid meteorites such as Brenham are not necessarily derived from the metal-silicate interface, but probably resulted from dendrite growth in the solidifying melt.Ordinary chondrites definitely are equilibrium assemblages rather than chance conglomerates. According to the best available evidence, Prior's rules seem to be valid. The metal particles in chondrites differentiated into kamacite and taenite in their present location, rather than in a remote earlier environment. Trace element abundances in ordinary and carbonaceous chondrites suggest that these meteorites accreted from two types of matter: an undepleted fraction that separated from its complement of gases at low temperatures, and a depleted fraction that lost its gases at high temperatures. These two fractions of primitive meteoritic matter are tentatively identified with the matrix and chondrules-plus-metal, respectively. New restrictive limits are placed on the iron-silicate fractionation in chondrites. No direct evolutionary path exists that connects the currently accepted solar abundances of Fe and Ni and the observed Fe/Si and Ni/Si ratios in chondrites. Apparently the solar abundance of iron is in error. The iron-silicate fractionation seems to have occurred while chondritic matter was in a more strongly reduced state than its present one.The U-He and K-Ar ages of hypersthene chondrites are systematically shorter than those of bronzite chondrites. Short ages are correlated with shock effects, and it seems that the hypersthene chondrites suffered reheating and partial-to-complete outgassing 0.4 AE ago. The cosmic-ray exposure ages of all classes of meteorites cluster distinctly, indicating that the meteorites were produced in a few discrete major collisions rather than by a quasi-continuum of smaller ones. The dates of the principal breakups are: irons, 0.6 and 0.9 AE; aubrites, 45 m.y.; bronzite chondrites, 4 m.y.; hypersthene chondrites, 0.025, 3, 7–13, and 16–31 m.y. All four clusters of hypersthene chondrites show evidence of severe outgassing 0.4 AE ago, which implies that most or all hypersthene chondrites come from the same parent body.As already noted by Signer and Suess, two distinct types of primordial gas occur in meteorites. Differentiated meteorites always contain unfractionated gas, while relatively undifferentiated meteorites contain fractionated gas. The former component is invariably associated with shock effects, and seems to have been derived from the solar wind. The latter component is correlated with other volatiles and seems to be a truly primitive constituent of meteoritic matter. Isotopic anomalies in the fractionated gas suggest that meteoritic matter was irradiated with 10¹⁷ protons/cm² at a very early stage of its history.There is very little doubt that most, if not all, meteorites come from the asteroid belt rather than from the moon. The orbits and geocentric velocities of stony meteorites resemble those of the Apollo asteroids (most of which are former members of the asteroid belt that have strayed into terrestrial space), but disagree strongly with the calculated orbits and velocities for lunar ejecta. Öpik's conclusions about the difficulty of accelerating lunar debris to escape velocity represent a further argument against a lunar origin of stony meteorites.The most likely parent bodies of the meteorites are the 34 asteroids which cross the orbit of Mars. Collisional debris from these objects will remain in Mars-crossing orbits, and perturbations by Mars will inject some fraction of this material into terrestrial space. Most of the Mars asteroids, comprising 98% of the mass and 92% of the cross-section, belong to three Hirayama families (Phocaea, Desiderata, and Aethra), and an additional, previously unrecognized family. These families were apparently produced by disruption of parent asteroids ca. 104, 105, and 46 km in diameter. The size distribution and light curves of asteroids indicate that the larger asteroids are original accretions, rather than collision fragments. There is no reason to believe that the meteorites ever resided in bodies larger than Ceres (d = 770 km).Various theories on the origin of the meteorites are critically reviewed in the light of the preceding evidence. Wood's theory, which postulates a high-temperature and a low-temperature variety of primordial matter, is in best accord with the evidence. Apparently the asteroids accreted from varying proportions of these two types of material, and were then heated by extinct radioactivity produced in the early irradiation.     

Cosmic-ray acceleration and transport,and diffuse galactic γ-ray emission

Cosmic-ray acceleration and transport is considered from the point of view of application to diffuse galactic -ray sources. As an introduction we review several source models, in particular supernovae exploding inside or near large interstellar clouds. The complex problem of cosmic ray transport in random electromagnetic fields is reduced to three cases which should be sufficient for practical purposes. As far as diffusive acceleration is concerned, apart from reviewing the basic physical principles, we point out the relation between shock acceleration and 2nd order Fermi acceleration, and the relative importance of the two processes around interstellar shock waves. For -ray source models the interaction of cosmic rays with dense clouds assumes great importance. Past discussions had been confined to static interactions of clouds with the ambient medium in the sense that no large scale mass motions in the ambient interstellar medium were considered. The well-known result then is that down to some tens of MeV or less, cosmic-ray nucleons should freely penetrate molecular clouds of typical masses and sizes. The self-exclusion of very low energy nucleons however may affect electron transport with consequences for the Bremsstrahlung -luminosity of such clouds.In this paper we consider also the dynamical interaction of dense clouds with a surrounding hot interstellar medium. Through cloud evaporation and accretion there exist mass flows in the cloud surroundings. We argue that in the case of (small) cloud evaporation the galactic cosmic rays will be essentially excluded from the clouds. The dynamic effects of cosmic rays on the flow should be minor in this case. For the opposite case of gas accretion onto (large) clouds, cosmic-ray effects on the flow will in general be large, limiting the cosmic-ray compression inside the cloud to dynamic pressure equilibrium. This should have a number of interesting and new consequences for -ray astronomy. A first, qualitative discussion is given in the last section.Proceedings of the XVIII General Assembly of the IAU: Galactic Astrophysics and Gamma-Ray Astronomy, held at Patras, Greece, 19 August 1982.     

The Composition of Interstellar Molecular Clouds

We consider four aspects of interstellar chemistry for comparison with comets: molecular abundances in general, relative abundances of isomers (specifically, HCN and HNC), ortho/para ratios for molecules, and isotopic fractionation, particularly for the ratio hydrogen/deuterium. Since the environment in which the solar system formed is not well constrained, we consider both isolated dark clouds where low mass stars may form and the "hot cores" that are the sites of high mass star formation. Attention is concentrated on the gas phase, since the grains are considered elsewhere in this volume. This revised version was published online in June 2006 with corrections to the Cover Date.     

The carbonaceous chondrites

The carbonaceous chondrites are a group of stony meteorites characterized by the presence of an appreciable amount of carbonaceous material other than free carbon (diamond and graphite). They have been divided into three subgroups known respectively as Type I, Type II, and Type III. Analyses of Type I meteorites show about 3–5% of carbon and 20% of combined water; they consist largely of hydrated magnesium-iron silicate, magnetite, and magnesium sulfate, contain no chondrules, and have a density about 2.2. Analyses of Type II meteorites show about 2–3% of carbon and 10–15% of combined water; they consist of a groundmass of hydrated magnesium-iron silicate enclosing chondrules of olivine and pyroxene which are almost iron-free, and have a density of 2.6–2.9. Analyses of Type III meteorites show about 0.5–2% of carbon and 2% combined water; they consist largely of olivine (often variable in composition, but averaging 30–40 mole per cent Fe₂SiO₄), with accessory pigeonite and sulfide minerals, and have a density about 3.4.The carbonaceous material and combined water in these meteorites are clearly of extraterrestrial origin, but their significance is not well understood. A biological origin has been claimed for some of the organic compounds on the basis of their composition, but this claim is the subject of considerable dispute. Microscopic objects with regular outline (organized elements) have been recognized in some of these meteorites; some investigators have claimed these to be extraterrestrial fossils, others have ascribed them to terrestrial contamination or considered them to be crystals or crystal aggregates of non-biological origin.     

X-Ray and extreme ultraviolet emissions from comets

There is significant progress in the observations, theory, and understanding of the x-ray and EUV emissions from comets since their discovery in 1996. That discovery was so puzzling because comets appear to be more efficient emitters of x-rays than the Moon by a factor of 80000. The detected emissions are general properties of comets and have been currently detected and analyzed in thirteen comets from five orbiting observatories. The observational studies before 2000 were based on x-ray cameras and low resolution (E/E1.5–3) instruments and focused on the morphology of x-rays, their correlations with gas and dust productions in comets and with the solar x-rays and the solar wind. Even those observations made it possible to choose uniquely charge exchange between the solar wind heavy ions and cometary neutrals as the main excitation process. The recently published spectra are of much better quality and result in the identification of the emissions of the multiply charged ions of O, C, Ne, Mg, and Si which are brought to comets by the solar wind. The observed spectra have been used to study the solar wind composition and its variations. Theoretical analyses of x-ray and EUV photon excitation in comets by charge exchange, scattering of the solar photons by attogram dust particles, energetic electron impact and bremsstrahlung, collisions between cometary and interplanetary dust, and solar x-ray scattering and fluorescence in comets have been made. These analyses confirm charge exchange as the main excitation mechanism, which is responsible for more than 90% of the observed emission, while each of the other processes is limited to a few percent or less. The theory of charge exchange and different methods of calculation for charge exchange are considered. Laboratory studies of charge exchange relevant to the conditions in comets are reviewed. Total and state-selective cross sections of charge exchange measured in the laboratory are tabulated. Simulations of synthetic spectra of charge exchange in comets are discussed. X-ray and EUV emissions from comets are related to different disciplines and fields such as cometary physics, fundamental physics, x-rays spectroscopy, and space physics.     

Ptolemy – an Instrument to Measure Stable Isotopic Ratios of Key Volatiles on a Cometary Nucleus

A fundamental goal of cometary studies is to determine the exact relationship between these bodies and the Solar System – the question(s) can be summarised as follows: did comets originate during the same events that spawned the Sun and planets, are they more primitive bodies that record a pre-solar history, or are they interstellar materials collected in relatively more recent times? Now, whatever the origin of comets, it is entirely possible that they could, in part, contain interstellar or pre-solar components – indeed, it seems rather likely in light of the fact that primitive meteorites contain such entities. These particular components are likely to be refractory (dust, macromolecular organic complexes, etc.). Of more relevance to the issues above are the volatile constituents, which make up the bulk of a comet's mass. Since these materials, by their very nature, volatilise during perihelion passage of a comet they can, in some instances, be detected and measured spectroscopically. Perhaps the most useful species for isotopic investigations are C₂, HCN and CN. Unfortunately, spectroscopic measurements can only currently be made with accuracies of ±10 to ±20%. As such it is very often not practical to conclude anything further than the fact that isotopic measurements are compatible with ‘`solar’' values, which tends to imply an origin from the margins of the solar accretion disk. But there is another problem with the spectroscopic measurements – since these are made on gaseous species in the coma (and relatively minor species at that) it is impossible to be certain that these represent the true nuclear values. In other words, if the processes of sublimation, active jetting, and photochemistry in the coma impart isotopic fractionation, the spectroscopic measurements could give a false impression of the true isotope ratios. What is required is an experiment capable of measuring isotopic ratios at the very surface of a comet. Herein we describe the Ptolemy instrument, which is included on the Philae lander as part of the Rosetta mission to 67P/Churyumov-Gerasimenko. The major objective of Ptolemy is a detailed appraisal of the nature and isotopic compositions of all materials present at the surface of a comet.     

The interpretations of ultraviolet observations of comets

Summary Ultraviolet observations of comets from above the Earth's atmosphere have provided excellent new results and improved older ground based observations (OH) by an order of magnitude. Satellites are especially suitable because long integration times and observations during extended time intervals are possible.The existing cometary L observations have confirmed the relatively high overall gas production rates on the order of 10³⁰ molecule s^–1. The results strongly support the concept of an icy conglomerate solid cometary nucleus. Additional observations of hydroxyl and oxygen favor water to be one of the most abundant molecules in comets. The observations are in agreement with the predominent role of water in the evaporation process of the nuclear ices but are not proof in themselves.Water did not outnumber other consitutents by orders of magnitude in comets Bennett and Kohoutek. At least in these comets, carbon-containing molecules were possibly as numerous as water. Determination of the carbon scale length is necessary for a more quantitative statement.A hydrogen velocity of 7–9 km s^–1 was observed in comet Bennett as well as in comet Kohoutek for a variety of heliocentric distances and varying production rates. Determinations of the outflow velocity from L isophotes agree with line profile observations of L and H. Hydroxyl may constitute the main source for the hydrogen atoms with v _H - 8 km s^–1. The decay process, however, leading to this particular velocity is not yet known. Possibly a large portion of the OH radicals do not decay into hydrogen atoms or at least not into slow ones. If the high velocity component of 20 km s^–1 or more comprises a larger amount (up to 50%), most of the quoted hydrogen production rates must be revised upward.The intrinsic cometary brightness is only a very crude indicator of a comet's actual gas production rate as shown by comparison of comets Bennett and TSK. Comets can be successfully used as (extra ecliptic) space probes to measure interplanetary quantities, e.g., the curvature of the extended hydrogen clouds can be used for the absolute determination of the solar emission independent of instrumental calibration. Generally time dependent hydrogen density models must be used for the interpretation. The strength of the ultraviolet L emission favors its measurement as a standard procedure for the observation of comets (possibly together with OH (3090 Å)). These observations provide the most accurate results on the total cometary gas production rate and its variation with heliocentric distance.Dedicated to Professor L. Biermann in recognition of his inspiring guidance.On leave of absence from Max-Planck-Institut für Physik und Astrophysik, Munich.     

An ISO View on Interstellar and Cometary Ice Chemistry

The ISO-SWS instrument offering a large wavelength coverage and a resolution well adapted to the solid phase has changed our knowledge of the physical-chemical properties of ices in space. The discovery of many new ice features was reported and the comparison with dedicated laboratory experiments allowed the determination of more accurate abundances of major ice components. The presence of CO₂ ice has recently been confirmed with the SWS (Short Wavelength Spectrometer) as a dominant ice component of interstellar grain mantles. The bending mode of CO₂ ice shows a particular triple-peak structure which provides first evidence for extensive ice segregation in the line-of-sight toward massive protostars. A comparison of interstellar and cometary ices using recent ISO data and ground-based measurements has revealed important similarities but also indicated that comets contain, beside pristine interstellar material, admixtures of processed material. The investigation of molecules in interstellar clouds is essential to reveal the link between dust in the interstellar medium and in the Solar System. This revised version was published online in June 2006 with corrections to the Cover Date.     

The extraterrestrial UV-background and the nearby interstellar medium

Recent measurements of the extraterrestrial UV- and EUV-radiation, and the various theoretical approaches used in explaining the measured features of these radiations are reviewed. Whereas the structures and intensities of extraterrestrial EUV-radiation are essentially undetermined up to now, the observations of the extraterrestrial UV-sky give a clear indication of the existence of neutral interstellar hydrogen within the solar system.The effects of solar radiation pressure, and of temporal variations and spatial asymmetries in the solar radiations, on the structure of the extraterrestrial L sky are investigated in detail, and the various attempts to derive interstellar parameters from the interpretation of the measured L intensities are discussed.From these discussions the local interstellar medium is established as a tenuous hot intercloud H i-medium. The amount of its relative motion against the solar system cannot be reliably fixed. Further activities concerning the measurement of extraterrestrial UV- and EUV-radiation features are suggested that may be highly valuable in clarifying the outstanding problems.     

Evolution of Interstellar Ices

Infrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Ices in molecular clouds are dominated by the very simple molecules H₂O, CH₃OH, NH₃, CO, CO₂, and probably H₂CO and H₂. More complex species including nitriles, ketones, and esters are also present, but at lower concentrations. The evidence for these, as well as the abundant, carbon-rich, interstellar, polycyclic aromatic hydrocarbons (PAHs) is reviewed. Other possible contributors to the interstellar/pre-cometary ice composition include accretion of gas-phase molecules and in situ photochemical processing. By virtue of their low abundance, accretion of simple gas-phase species is shown to be the least important of the processes considered in determining ice composition. On the other hand, photochemical processing does play an important role in driving dust evolution and the composition of minor species. Ultraviolet photolysis of realistic laboratory analogs readily produces H₂, H₂CO, CO₂, CO, CH₄, HCO, and the moderately complex organic molecules: CH₃CH₂OH (ethanol), HC(=O)NH₂ (formamide), CH₃C(=O)NH₂ (acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C₆H₁₂N₄), as well as more complex species including amides, ketones, and polyoxymethylenes (POMs). Inclusion of PAHs in the ices produces many species similar to those found in meteorites including aromatic alcohols, quinones and ethers. Photon assisted PAH-ice deuterium exchange also occurs. All of these species are readily formed and are therefore likely cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Relations between ISM inside and outside the heliosphere

Thanks to remarkable new tools, such as the Goddard High Resolution Spectrograph (GHRS) on board the HST and the EUVE spectrometer on the interstellar side, and Ulysses particle detectors on the heliospheric side, it is possible now to begin to compare abundances and physical properties of the interstellar matter outside the heliosphere (from absorption features in the stellar spectra), and inside the heliosphere (from in situ or remote detection of the interstellar neutrals or their derivatives, the pick-up ions or the Anomalous Cosmic Rays detected by the two Voyager spacecraft).Ground-based and UV spectra of nearby stars show that the Sun is located between two volumes of gas of different heliocentric velocities V and temperatures T (see also Linsky et al, this issue). One of these clouds has the same velocity (V= 25.6 km s^–1 from = 255 and =8) and temperature (6700 K) as the heliospheric helium of interstellar origin probed by Ulysses, and is certainly surrounding our star (and then the Local Interstellar Cloud or LIC). This Identification allows comparisons between interstellar constituents on both sides of the heliospheric interface.Ly-alpha background data (absorption cell and recent HST-GHRS spectra) suggest that the heliospheric neutral H velocity is smaller by 5–6 km s^–1 than the local cloud velocity, and therefore that H is decelerated at its entrance into the heliosphere, in agreement with interaction models between the heliosphere and the ISM which include the coupling with the plasma. This is in favor of a non negligible electron density (at least 0.05 cm³). There are other indications of a rather large ionization of the ambient ISM, such as the ionization equilibrium of interstellar magnesium and of sodium. However the resulting range for the plasma density is still broad.The heliospheric neutral hydrogen number density (0.08–0.16 cm^–3) is now less precisely determined than the helium density (0.013–0.017 cm^–3, see Gloeckler, Witte et al, Mobius, this issue). The comparison between the neutral hydrogen to neutral helium ratios in the ISM (recent EUVE findings) and in the heliosphere, suggests that 15 to 70% of H does not enter the heliosphere. The comparison between the interstellar oxygen relative abundance (with respect to H and He) in the ISM and the heliospheric abundance deduced from pick-up ions is also in favor of some filtration, and thus of a non-negligible ionization.For a significant ISM plasma density, one expects a Hydrogen wall to be present as an intermediate state of the interstellar H around the interface between inside and outside. Since 1993, the two UVS instruments on board Voyager 1 and 2 indeed reveal clearly the existence of an additional Ly-alpha emission, probably due to a combination of light from the compressed H wall, and from a galactic source. On the other hand, the decelerated and heated neutral hydrogen of this H wall has recently been detected in absorption in the spectra of nearby stars (see Linsky, this issue).