Towards validation of SCIAMACHY lunar occultation NO2 vertical profiles

Vertical profiles of stratospheric nitrogen dioxide (NO₂) have been retrieved from moderate resolution lunar occultation transmission spectra measured by Scanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) on board the European Environmental Satellite (ENVISAT). These measurements were taken over the high southern latitude of 50°–90° during the period of 2003–2005. To assess the accuracy of the retrieved NO₂ profiles, the SCIAMACHY nighttime NO₂ profiles were compared with NO₂ profiles retrieved from sunrise solar occultation spectra measured by the Halogen Occultation Experiment (HALOE) and the Stratospheric Aerosol and Gas Experiments II (SAGE II) using a photochemical correction model. The validation results show good agreement of SCIAMACHY lunar occultation NO₂ with scaled HALOE and SAGE II profiles. The relative mean differences (rmd) with scaled HALOE profiles are within −13% to +5% and standard deviations (rms) of the relative differences are within 3–19% between 25 and 38 km. The rmd and rms with scaled SAGE II NO₂ profiles are in the range of −9 to +7 and 10–17% respectively between 22 and 39 km.     

Comparison of OClO nadir measurements from SCIAMACHY and GOME

The scanning imaging absorption spectrometer for atmospheric chartography was launched successfully onboard ENVISAT on March 1, 2002. It observes the solar radiation transmitted and backscattered from the atmosphere and reflected from the ground in nadir, limb and occultation viewing modes. Chlorine dioxide (OClO), an important indicator for stratospheric chlorine activation, can be measured in the UV spectral range by differential optical absorption spectroscopy (DOAS).

First results of the DOAS retrieval of OClO slant column densities from the SCIAMACHY nadir measurements are presented and compared to measurements of the global ozone monitoring experiment (GOME), which has successfully measured OClO since 1995. While SCIAMACHY operates in the same orbit, it measures ≈30 min earlier than GOME and has an increased spatial resolution (30 × 60 km² compared to 40 × 320 km² for GOME).     

X-ray spectroscopy and variability of AGN detected in the 2 Ms Chandra Deep Field-North Survey

We investigate the nature of the faint X-ray source population through X-ray spectroscopy and variability analyses of 136 active galactic nuclei (AGN) detected in the 2 Ms Chandra Deep Field-North Survey with >200 background-subtracted 0.5–8.0 keV counts [F_{0.5–8.0 keV} = (1.4−200) × 10⁻¹⁵ erg cm⁻² s⁻¹]. Our preliminary spectral analyses yield median spectral parameters of Γ = 1.61 and intrinsic N_H = 6.2 × 10²¹ cm⁻² (z = 1 assumed when no redshift available) when the AGN spectra are fitted with a simple absorbed power-law model. However, considerable spectral complexity is apparent (e.g., reflection, partial covering) and must be taken into account to model the data accurately. Moreover, the choice of spectral model (i.e., free vs. fixed photon index) has a pronounced effect on the derived JVH distribution and, to a lesser extent, the X-ray luminosity distribution. We also find that among the 136 AGN, 10 (≈7%) show significant Fe K emission-line features with equivalent widths in the range 0.1–1.3 keV. Two of these emission-line AGN could potentially be Compton thick (i.e., Γ < 1.0 and large Fe K equivalent width). Finally, we find that 81 (≈60%) of the 136 AGN show signs of variability, and that this fraction increases significantly (≈80–90%) when better photon statistics are available.     

A new non-LTE retrieval method for atmospheric parameters from mipas-envisat emission spectra

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is a high-resolution limb sounder on board the European polar platform ENVISAT, scheduled to be launched in 2001. A large number of atmospheric trace gases relevant to stratospheric ozone chemistry and global change are expected to be retrieved from the IR spectra covering a wide spectral range. While operational data analysis under responsibility of the European Space Agency is limited to conditions of local thermodynamic equilibrium (LTE), the analysis of limb radiances affected by non-LTE is left to scientific institutions. In this paper we present an innovative non-LTE retrieval method as part of the MIPAS semi-operational data processor developed at the Institut für Meteorologie und Klimaforschung (IMK). The new approach enables the treatment of vibrational, rotational, and spin non-LTE as well as a dependence of the non-LTE state distribution on the retrieval target quantities. In a case study, the method has been tested for its application to the non-LTE analysis of 5.3 μm MIPAS radiances. The fundamental ro-vibrational band of nitric oxide emitting at 5.3 μm shows strong non-LTE effects arising from vibrational excitation of stratospheric NO and superposed thermospheric non-LTE emissions. A conventional non-LTE retrieval approach using ab initio vibrational temperatures of NO cannot be applied due to rotational and spin non-LTE in the thermosphere, and the dependence of stratospheric vibrational temperatures on the NO abundance itself. The ability of the developed non-LTE inversion tool to retrieve stratospheric NO abundances is demonstrated by retrieval simulations. The further application of this method to the simultaneous retrieval of NO and kinetic temperature in the thermosphere and the retrieval of important non-LTE process parameters has also been tested.     

Near infrared studies of the massive X-ray binary 2S 0114+65

We present near-infrared spectroscopy of the massive X-ray binary 2S 0114+650. These observations covering the spectral range 1.08–2.35 μm span the region where Paschen and Brackett series recombination lines of hydrogen are expected to be seen, namely, Paβ , Brγ and Br 10–17 lines. The absence of any of these lines in emission supports earlier inferences that the optical component in 2S 0114+650 is unlikely to be a Be star but rather a B type supergiant. Near-IR photometry gives J = 8.78, H = 8.53 and K = 7.96; these values show marginal variations from earlier reported measurements.     

SLX 1746-311 in outburst

We report on RXTE-PCA observations of SLX 1746-311 during a 100 day outburst in April 2003. We present the 3–20 keV PCA energy spectra of the source and study evolution of spectral parameters. The burst spectrum is soft with T_in 1.3 keV at the beginning of the outburst. There is a clear evidence of a hard power law component throughout the outburst. There is also an indication of a broad iron line. The source exhibits three state transitions with considerable change in the hardness ratio at low count rates. We discuss the possible scenario under which this unusual behaviour can be explained.     

SCIAMACHY solar irradiance observation in the spectral range from 240 to 2380 nm

The SCanning Imaging Absorption Spectrometer for Atmospheric CHartographY (SCIAMACHY) is part of the payload of ESA’s Environmental Satellite ENVISAT which was launched into a sun-synchronous polar orbit on 2002-03-01. It is the first spaceborne instrument covering a wavelength range from 240 to 2380 nm thus including ultraviolet, visible and near infrared spectral regions.The main purpose of SCIAMACHY is to determine the amount and distribution of a large number of atmospheric trace constituents by measuring the radiance backscattered from the Earth. In addition, several solar observations are performed with daily or orbital frequency.The presented results will cover the following topics: (a) comparison of the solar irradiance measured by SCIAMACHY with data from the instruments SOLSPEC/SOLSTICE/SUSIM and a solar spectrum derived by Kurucz; (b) comparison of the SCIAMACHY solar Mg II index with GOME and NOAA data; (c) correlation of the relative change of solar irradiance measured by SCIAMACHY with the sun spot index.The mean solar irradiance for each of the 8 SCIAMACHY channels agrees with the Kurucz data within ±2–3%. The presented analysis proves that SCIAMACHY is a valuable tool to monitor solar irradiance variations.     

Remote infrared observations of parent volatiles in comets: A window on the early solar system

Organic volatiles and water in Oort Cloud comets were investigated at infrared wavelengths. The detected species include H₂O, CO, CH₃OH, CH₄, C₂H₂, C₂H₆, OCS, HCN, NH₃, and H₂CO. Several daughter fragments (CN, OH, NH₂, etc.) are also measured, and OH prompt emission provides a proxy for water. Long-slit spectra are taken at high spectral dispersion and high spatial resolution, eliminating several sources of systematic error. The resulting parent volatile production rates are highly robust, permitting a sensitive search for compositional diversity among comets. Here, seven OC comets are compared. Six (including Halley) exhibit similar compositions (excepting CO and CH₄). Their low formation temperatures (30 K) suggest this group probably formed beyond 30 AU from the young sun. However, C/1999 S4 is severely depleted in hypervolatiles and also in methanol, and it likely formed near 5–10 AU. C/2001 A2 is discussed briefly to illustrate future prospects.     

Fe XVII X-ray lines in solar coronal plasmas

Calculated intensities of the Fe X-ray lines due to transitions 2p⁶ − 2p⁵3d lines (near 15 Å) and 2p⁶ − 2p⁵3s lines (near 17 Å) are compared with measured line intensities in solar and tokamak spectra. For the solar spectra, temperature T_e is obtained from the ratio of the Fe 16.776 Å line to a nearby Fe line. We find excellent agreement for all the major Fe line features in the 15–17 Å region except the Fe 15.015 Å line, the observed flux of which is less than the theoretical by a factor f. We find that f strongly depends on the heliocentric angle θ of the emitting region, being smallest (0.2) when the region is nearest Sun centre, but nearly 1 near the limb. Attributing this to resonance scattering, we are able to deduce the path length and electron density from the observations. Possible application to stellar active regions is given.     

Reevaluation of thermosphere heating by auroral electrons

This paper presents a new calculation of neutral gas heating by precipitating auroral electrons. It is found that the heating rate of the neutral gas is significantly lower than previous determinations below 200 km altitude. The neutral gas heating arises from the many exothermic chemical reactions that take place from the ions and excited species created by the energetic electrons. The calculations show that less than half the energy initially deposited ends up heating the neutral gases. The rest is radiated or lost in the dissociation of O₂ because the O atoms do not recombine in the thermosphere. This paper also presents a new way of calculating the heating rate per ionization that can be used for efficient determination of the overall neutral gas heating for global thermosphere models. The heating rates are relatively insensitive to the neutral atmosphere when plotted against pressure rather than altitude coordinates. At high altitudes, the heating rates are sensitive to the thermal electron density and long-lived species. The calculations were performed with the Field Line Interhemispheric Plasma (FLIP) model using a 2-stream auroral electron precipitation model. The heating rate calculations in this paper differ from previous heating rate calculations in the treatment of backscattered electrons to produce better agreement with observed flux spectra. This paper shows that more realistic model auroral electron spectra can be obtained by reflecting the up going flux back to the ionosphere at the upper boundary of the model. In this case, the neutral gas heating rates are 20%–25% higher than when the backscattered flux escapes from the ionosphere.     

Boundary layer aerosol retrieval from thermal infrared nadir sounding – Preliminary results

A non-empirical algorithm is presented to retrieve the optical depth in the 750–1250 cm⁻¹ spectral range, of aerosol located in the boundary layer over the ocean, from nadir high-resolution radiance spectra in the thermal infrared. The algorithm is based on a line-by-line radiative transfer forward model and used the Optimal Estimation Method for the retrieval. Its performance strongly depends on the quality of the a priori temperature and H₂O atmospheric profiles. To demonstrate the relevance of the algorithm, distributions of maritime aerosol parameters have been retrieved from IMG/ADEOS data for December 1996, using the algorithm with the LBLRTM radiative transfer code, and ERA40 (ECMWF) a priori atmospheric profiles and surface conditions.     

First results of ozone profiles between 35 and 65 km retrieved from SCIAMACHY limb spectra and observations of ozone depletion during the solar proton events in October/November 2003

Ozone density profiles between 35 and 65 km altitude are derived from scattered sunlight limb radiance spectra measured by the SCIAMACHY instrument on the Envisat satellite. The method is based on the inversion of normalized limb radiance profiles in the Hartley absorption bands of ozone at selected wavelengths between 250 and 310 nm. It employs a non-linear Newtonian iteration version of Optimal Estimation (OE) coupled with the radiative transfer model SCIARAYS. The limb scatter technique combined with a classical OE retrieval in the short-wave UV-B and long-wave UV-C delivers reliable results as shown by a first comparison with MIPAS V4.61 profiles yielding agreement within 10% between 38 and 55 km. An overview of the methodology and an initial error analysis are presented. Furthermore the effect of the solar proton storm between 28 October and 6 November 2003 on the ozone concentration profiles is shown. They indicate large depletion of ozone of about 60% at 50 km in the Northern hemisphere, a weaker depletion in the Southern hemisphere and a dependence of the depletion on the Earth’s magnetic field.     

Carbon monoxide spatial gradients over source regions as observed by SCIAMACHY: A case study for the United Kingdom

Carbon monoxide (CO) is an important air pollutant whose emissions and atmospheric concentrations need to be monitored. The measurements of the SCIAMACHY instrument on ENVISAT are sensitive to CO concentration changes at all atmospheric altitude levels including the boundary layer. The SCIAMACHY CO measurements therefore contain information on CO emissions. Until now no studies have been published where the SCIAMACHY CO measurements have been used to quantify CO emissions by applying, for example, inverse modelling approaches. Here we report about a step in this direction. We have analysed three years of CO columns to investigate if spatial gradients resulting from United Kingdom (UK) CO emissions can be observed from space. The UK is an interesting target area because the UK is a relatively well isolated CO source region. On the other hand, the UK is not the easiest target as its emissions are only moderate and because the surrounding water has low reflectivity in the 2.3 μm spectral region used for CO retrieval. We determined horizontal CO gradients from seasonally and yearly averaged CO during 2003–2005 over the UK taking into account daily wind fields. We show that the measured CO longitudinal (downwind) gradients have the expected order of magnitude. The estimated 2σ error of the gradients depends on time period and applied filtering criteria (e.g., land only, cloud free) and is typically 10–20% of the total column. The gradients are barely statistically significant within the 2σ error margin. This is mainly because of the relatively high noise of the SCIAMACHY CO measurements in combination with a quite low number of measurements (∼100) mainly due to cloud cover.     

Supersoft X-ray sources

More than 100 supersoft X-ray sources (SSS) are reported in 20 external galaxies, the Magellanic Clouds (MCs) and our Galaxy. The effective temperatures of the brighter SSS are 20–100 eV. SSS with luminosities below ≈3 × 10³⁸ erg s⁻¹ are consistent with accreting white dwarfs (WDs) with steady nuclear burning or post-novae. Optical identifications exist for SSS in our Galaxy and the MCs (including orbital period determinations) and for SSS in M31 (with novae and symbiotic stars, SySs). High resolution X-ray spectra of the brightest SSS in our Galaxy and the MCs reveal the existence of spectral features due to high gravity WDs. Timing studies in X-rays (combined with the optical) of the stable nuclear burning phase in steady nuclear burning sources and in post-novae allow to constrain the mass accretion rate onto and the mass of the nuclear burning WD. The nature of a few SSS with luminosities 10³⁹ erg s⁻¹ remains unclear.     

Diurnal variations of ion flux intensity on a synchronous orbit

The data from the synchronous-orbit satellites of the Gorizont series are used to study the dependences of the ion flux variation amplitudes in the synchronous altitude region (the diurnal behaviour) on particle energies and on the form and rigidity of the particle energy spectrum. The proton fluxes were measured in the energy range E 60–120 keV, and the [N,0]²⁺ and [C,N,0]⁴⁺ ion fluxes in the energy range E 60–70 keV/e.

The ratio of the diurnal variation amplitudes of the studied ions is shown to correspond to the similarity of their energy spectra in the E/Q representation. The magnetically-quiet time gradient of the distribution function F(μ,J,L) in the synchronous-orbit region is shown to be (∂F/∂L)=0 for the H⁺ and [N,0]²⁺ ions and (∂F/∂L) > 0 for the [C,N,0]⁴⁺ ions (at the values of μ corresponding to the examined energy ranges). During magnetically-disturbed periods the inner boundary of the (∂F/∂L)=0 region shifts to lower L and (∂ F/∂L) = O in the synchronous altitude region must be also for the [C,N,O]⁴⁺ ions.     

X-ray measurements of the dark matter distribution in clusters of galaxies with Chandra

We investigate the dark matter distributions in the central region of two clusters of galaxies (A1835 and MKW3S) using Chandra data. N-body simulations in the standard cold dark matter (CDM) model predict the dark matter distribution shows a cuspy dark matter profile: ρ(r) ∝ r, with in the range 1–2, while observations of dwarf and low surface brightness galaxies seem to favor the presence of a relatively flat core: 0 <  < 1. To investigate the dark matter distributions in the central region of clusters of galaxies, we analyze the Chandra data of A1835 and MKW3S with a deprojection method. We derive the mass profiles without the assumption of analytical models. We examine the inner slope of derived mass profiles assuming the dark matter profile is described with a power-law expression. The values of the slope are 0.95 ± 0.10 for A1835 and 1.33 ± 0.12 for MKW3S within the radius of 200 kpc. These are consistent with the result of the CDM simulations. However, within the radius of 100 kpc, the value of is less than unity for A1835 (0.47 ± 0.31). Our result implies that the central dark matter profile of some clusters cannot be described by CDM halos.     

Energy deposition in the upper atmosphere in the EXCEDE III experiment

The EXCEDE III sounding rocket flight of April 27, 1990 used a 18 Ampere 2.5 keV electron beam to produce an artificial aurora in the region 90 to 115 km. A “daughter” sensor payload remotely monitored the low-energy X-ray spectrum while scanning photometers measured the spatial profile of prompt emissions of N₂⁺ (1N) and N₂ (2P) transitions (3914Å and 3805Å, respectively). Two Ebert-Fastie spectrometers measured the spectral region from 1800 to 8000Å. On the “mother” accelerator payload, the return current electron differential energy spectra were monitored by an electrostatic analyzer (up to 10 keV) and by a retarding potential analyzer (0 eV to 100 eV). We present an overview of the results from this experiment.     

The 2.5 to 5 microns spectrum of comet Halley from the IKS instrument of Vega

Results of the 2.5–5 micron spectroscopic channel of the IKS instrument on Vega are reported and the data reduction process is described. H₂O and CO₂ molecules have been detected with production rates of 10³⁰ s⁻¹ and 1.5 10²⁸ s⁻¹ respectively. Emission features between 3.3 and 3.7 microns are tentatively attributed to CH - bearing compounds - CO is marginally detected with a mixing ratio CO/H₂O 0.2. OH emission and H₂O - ice absorption might also be present in the spectra.     

Numerical simulations of the radiance from the comet 46P/Wirtanen in the various configurations of the measurements during “Rosetta” mission

The work we present deals with the spectrometric measurements of VIRTIS instrument of the Comet P/Wirtanen planned for the Rosetta mission. This spectrometer can monitor (VIRTIS M channel: 0.250μm – 0.980μm; Δκ=20cm⁻¹; 0.980 – 5.0 μm; Δκ = 5cm⁻¹; VIRTIS H channel: 2.0 μm – 5.0 μm; Δκ=2cm⁻¹) the nucleus and the coma in order to provide a general picture of coma's composition, the production of gas and dust, the relationship of coma production to surface composition and the structure and variation of mineralogy of the nucleus surface. During the mission the observation conditions of the spectroscopic investigation change due to different relative positions spacecraft/comet, and to the different illumination conditions of the surface at various distances of the comet to the Sun. The nucleus surface is continuously modified by the ice sublimation accompanied by gas and dust emission. Consequently the surface also its spectrophotometric properties changes and their monitoring can give a new insight. The important role of simulations is to predict the results of measurements in various experimental condition what, in the future, can help in interpretation of the measured data.

In this paper the first results of our simulation the radiance from the comet in the 0.25–5.0μm spectral range at two distances from the Sun (1AU and 3AU) are shown. The distance between the Rosetta orbiter and the nucleus surface as well as the sun zenith angles are taken into account according to the Rosetta mission phases. In fact the surface and coma properties vary along the comet orbit, and should be taken into account in our calculations. The optical parameters of the dust on the surface (e.g. reflectance) and in the coma (e.g. Q_ext) were calculated from optical constants of possible comet analogues. The thermodynamic parameters of the comet are taken from the models of comet evolution. Through this kind of modelling it is possible to identify the surface characteristics in spectra of the radiation from the surface of nucleus transmitted through the coma loaded with dust and gases.

Even if the “Rosetta mission” is postponed, with the consequence of a target change, we think that our idea and the method used for the simulations can be useful also for the new Rosetta target - the comet 67P/Churyumov Gerasimenko.