Infrared spectroscopy of organics of planetological interest at low temperatures.

In the context of prebiotic chemistry in space, some of the outer planetary objects display H, C, N and O rich chemistry similar to the one in the biosphere of Earth. Of particular interest are Saturn's moon, Titan; Neptune's moon, Triton; and Pluto where extreme cold conditions prevail. Identifications of chemical species on these objects (surfaces and atmospheres) is essential to a better understanding of the radiation induced chemical reactions occurring thereon. There have been several ground based observations of these planetary objects in the infrared windows from 1 to 2.5 micrometers. Voyager also provided spectra in the thermal infrared (6 to 50 micrometers) region. Interpretation of these data require laboratory infrared spectra of relevant species under the temperature conditions appropriate to these objects. The results of some of these studies carried out in our laboratory and elsewhere and their impact on the analyses of the observed data will be summarized.     

New results on planetary lightning

We present the latest observations from spacecraft and ground-based instruments in search for lightning activity in the atmospheres of planets in the solar system, and put them in context of previous research. Since the comprehensive book on planetary atmospheric electricity compiled by Leblanc et al. (2008), advances in remote sensing technology and telescopic optics enable detection of additional and new electromagnetic and optical emissions, respectively. Orbiting spacecraft such as Mars Express, Venus Express and Cassini yield new results, and we highlight the giant storm on Saturn of 2010/2011 that was probably the single most powerful thunderstorm ever observed in the solar system. We also describe theoretical models, laboratory spark experiments simulating conditions in planetary mixtures and map open issues.     

The physical nature of Titan's aerosols: laboratory simulations.

The atmosphere of Titan is known to contain aerosols, as evidenced by the Voyager observations of at least three haze layers. Such aerosols can have significant effects on the reflection spectrum of Titan and on the chemistry and thermal structure of its atmosphere. To investigate some of these effects, laboratory simulations of the chemistry of Titan's atmosphere have been done. The results of these studies show that photolysis of acetylene, ethylene, and hydrogen cyanide, known constituents of Titan's atmosphere, yields sub-micron sized spheres, with mean diameters ranging from 0.4 to 0.8 microns, depending on the pressures of the reactant gases. Most of the spheres are contained in near-linear aggregates. The formation of the aggregates is consistent with models of Titan's reflection spectrum and polarization, which are best fit with non-spherical particles. At room temperature, the particles are very sticky, but their properties at low temperatures on Titan are presently not known.     

Mercury's magnetosphere

The Mariner 10 observations of Mercury's miniature magnetosphere collected during its close encounters in 1974 and 1975 are reviewed. Subsequent data analysis, re-interpretation and theoretical modeling, often influenced by new results obtained regarding the Earth's magnetosphere, have greatly expanded our impressions of the structure and dynamics of this small magnetosphere. Of special interest are the Earth-based telescopic images of this planet's tenuous atmosphere that show great variability on time scales of tens of hours to days. Our understanding of the implied close linkage between the sputtering of neutrals into the atmosphere due to solar wind and magnetospheric ions impacting the regolith and the resultant mass loading of the magnetosphere by heavy planetary ions is quite limited due to the dearth of experimental data. However, the influence of heavy ions of planetary origin (O⁺, Na⁺, K⁺, Ca⁺ and others as yet undetected) on such basic magnetospheric processes as wave propagation, convection, and reconnection remain to be discovered by future missions. The electrodynamic aspects of the coupling between the solar wind, magnetosphere and planet are also very poorly known due to the limited nature of the measurements returned by Mariner 10 and our lack of experience with a magnetosphere that is rooted in a regolith as opposed to an ionosphere. The review concludes with a brief summary of major unsolved questions concerning this very small, yet potentially complex magnetosphere.     

Mapping lunar surface chemistry: New prospects with the Chandrayaan-2 Large Area Soft X-ray Spectrometer (CLASS)

Surface chemistry of airless bodies in the solar system can be derived from remote X-ray spectral measurements from an orbiting spacecraft. X-rays from planetary surfaces are excited primarily by solar X-rays. Several experiments in the past have used this technique of X-ray fluorescence for deriving abundances of the major rock forming elements. The Chandrayaan-2 orbiter carries an X-ray fluorescence experiment named CLASS that is designed based on results from its predecessor C1XS flown on Chandrayaan-1. We discuss the new aspects of lunar science that can be potentially achieved with CLASS.     

Organic syntheses in gas phase and chemical evolution in planetary atmospheres

Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH₄, CO or CO₂), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres.     

Some Investigations on the Ionosphere during 2012–2014 in China

In this national biannual report, we will outline some recent progresses in ionospheric studies conducted by Chinese scientists since 2012. The mentioned aspects include: the solar activity control of the ionosphere; couplings between the ionosphere, lower atmosphere and plasmasphere;ionospheric climatology and disturbances; ionospheric irregularities and scintillation; models, data assimilation and simulations; unusual phenomena of the ionosphere; possible seismic signatures presented in ionospheric observations, and some methodology progresses. These progresses will enhance our ability to observe the ionosphere, provide more reasonable understanding about the states of the ionosphere and underlying fundamental processes, and stimulate ionospheric modeling, forecasting and related applications.     

New insights into Titan's organic chemistry in the gas and aerosol phases.

Titan, the largest satellite of Saturn, with a dense atmosphere very rich in organics, and many couplings in the various parts of its "geofluid", is a reference for studying prebiotic chemistry on a planetary scale. New data have been obtained from experiments simulating this organic chemistry (gas and aerosol phases), within the right ranges of temperature and a careful avoiding of any chemical contamination. They show a very good agreement with the observational data, demonstrating for the first time the formation of all the organic species already detected in Titan atmosphere including, at last, C4N2, together with many other species not yet detected in Titan. This strongly suggests the presence of more complex organics in Titan's atmosphere and surface, including high molecular weight polyynes and cyanopolyynes. The NASA-ESA Cassini-Huygens mission has been successfully launched in October 1997. The Cassini spacecraft will reach the Saturn system in 2004 and become an orbiter around Saturn, while the Huygens probe will penetrate into Titan's atmosphere. In situ measurements, in particular from Huygens GC-MS and ACP instruments, will provide a detailed analysis of the organics present in the air, aerosols, and surface. This very ambitious mission should yield much information of crucial importance for our knowledge of the complexity of Titan's chemistry, and, more generally for the field of exobiology.     

An empirical model of the plasma environment around Mercury

Since the flyby observations by Mariner 10 in 1974 and 1975, Mercury has been one of the most interesting objects for space physics and planetary exploration. The MESSENGER and BepiColombo missions now plan to revisit this planet. In order to design plasma instruments for the BepiColombo mission, we have estimated electron and ion fluxes around Mercury with an empirical model, which has been developed for the Earth’s magnetotail. The solar wind data needed as input parameters are derived from Helios observations. The result shows that our predicted electron fluxes at aphelion agree well with the Mariner-10 data. It is also noted that ion instruments must cover a very wide dynamic range of proton fluxes. However, the applicability of the Earth’s magnetospheric model to Mercury is, in itself, an important issue for comparative magnetospheric studies.     

Accurate determination of the successive moments of the sun: a new window open on the sun''s interior

Despite its great importance for solar physics, mainly in the fields of solar fundamental astrometry, helioseismology, planetary motions and relativistic effects, the successive zonal harmonics of the Sun still remain elusive and subject to some controversy. Direct observations from the ground suffer from atmospheric effects and are not of enough accuracy. Up to now, space flights (SOHO) or balloon missions give consistent data but lead to spurious results due to the noise. As far as indirect observations are concerned, the more precise determination of the successive moments (mainly J₂, J₄ and even J₆), will be provided unambiguously by the study of the orbit of a spacecraft flying close to the Sun or around Mercury. This has been scheduled, but not yet achieved. In this paper we will first emphasize why it is important to know the successive zonal harmonics of the Sun with a high accuracy. We will show how their precise knowledge permits to obtain informations on the Sun's interior, mainly the shear's regions (tacholine or leptocline). Then we will give an up-to-date review of both theories (including the heliosismology approach) and data. We will explain some of the difficulties, mainly due to the differential rotation and we will give an insight of what the PICARD's mission will bring in that field. Then we will propose a novel concept for a Sun's mission, which would lead to the most accurate determination of the successive solar moments (that could be part of another project), and thus opening a new window on the Sun's interior.     

The escape of molecular hydrogen and the synthesis of organic nitriles in planetary atmospheres.

What is the influence of hydrogen escape from the atmosphere of small planetary bodies on the synthesis of organic molecules in that atmosphere? To answer this question, laboratory experiments have been performed to study the evolution of different reducing model atmospheres submitted to electrical discharges, with and without the simulation of H₂ escape. A study of mixtures of nitrogen and methane shows a very strong effect of H₂ escape on the formation of organic nitriles, the only nitrogen containing organics detected in the gas phase. These are HCN, CH  CCN, (CN)₂, CH₂CHCN, CH₃ CN and CH₃CH₂CN. The yield of synthesis of most of these compounds is noticeably increased, up to several orders of magnitude, when hydrogen escape is simulated. The escape of H₂ from the atmosphere of the primitive Earth may have played a crucial role in the formation of reactive organic molecules such as CHCCN or (CN)₂, which can be considered as important prebiotic precursors. These experimental results may also explain extant data concerning the nature and relative abundance of organics present in the atmosphere of Titan, a planetary satellite which may be an ideal model within our solar system for the study of organic cosmochemistry and exobiology.     

Model simulations of the impact of the 27-day solar rotation period on stratospheric ozone and temperature

Results are presented from two-year simulations of the effects of short-term solar ultraviolet (UV) variability using the Met. Office coupled chemistry-climate model. The model extends from the ground to 0.1 mbar and contains a complete range of chemical reactions allowing representation of all the main ozone formation and destruction processes in the stratosphere. The simulations were achieved by incorporating a 27-day oscillation in the pre-calculated model photolysis rates. Amplitudes for this signal were determined using solar spectral UV observations from the SOLar STellar Irradiance Comparison Experiment (SOLSTICE) instrument. Two experiments were carried out, one in which the UV variability was included in both the photolysis and radiation schemes and one in which only the photolysis scheme was modified.

The model reproduced several main features of observed correlations between short-term solar UV variability and both ozone and temperature in the tropical upper stratosphere, including the downward propagation of the phase lag and sensitivities of ozone and temperature to solar UV which are similar in magnitude to those observed. In the lower stratosphere, the ozone response to solar UV variability has not been well characterised from observations. Both model runs show a reversal of the propagation of phase lag below 10mb. The model response was found to be different between the two runs indicating that radiatively induced dynamical effects may play a significant role in the ozone response to solar UV variability.     

Space telescope studies of Jupiter and Saturn simulated by Voyager observations

Space Telescope (ST) observations of Jupiter and Saturn will offer a unique opportunity for monitoring their changing meteorological characteristics. They will provide higher spatial and temporal resolution for composition and vertical structure studies than have been available to date. We have simulated the planetary camera observations of Jupiter and Saturn by Voyager images of the appropriate spatial scale. With this data set we have investigated the meteorological properties of these atmospheres which can be studied at these scales. In addition we have considered the advances obtainable with the high resolution spectrometer on ST compared with observations from ground-based and other Earth-orbiting satellites. These studies will provide insight into the scientific gain and possible problems in the use of ST for planetary studies.     

A Review on the Ionospheric Research： Chinese Works During 2006-2008

This paper reviews various progresses on the ionospheric studies by the scientists in China during the last two years.The main contents concern the 4 aspects of the ionospheric research:(1)ionospheric weather and coupling with magnetosphere(polar and auroral ionosphere,ionospheric response to substorms,ionospheric storms);(2)mid-and low-latitude ionospheric climatology(ionospheric properties,yearly variations and solar activity dependence,long term variation);(3)ionospheric coupling with neutral atmosphere(gravity waves,tides,planetary waves,background upper atmosphere,and ionospheric response);and(4)ionospheric diagnostics(observation,modeling,and prediction).     

Multi-wavelength observations of the pre-cursor phase of solar flares

Observational studies of the pre-cursor phase of solar flares have shown that there are many and varied signatures that may or may not indicate the probable onset of a flare. Combining data from Yohkoh, SOHO and TRACE and more recent observations from RHESSI, SOHO and TRACE we, investigate the relationships between the different manifestations of pre-flare behaviour in two solar flares with a view to determining how they are related to the subsequent flare energy release. We find that in one case the preflare activity seems strongly related to the subsequent flare and probably represents a build-up of energy in the active region prior to flare onset. The second case we find to be less clear cut suggesting that significant further work remains to be done in order to determine which pre-flare signatures are most useful in indicating the build-up to flare onset.     

Some observations on amino acid racemization under pyrolytic temperatures and inorganic oxide-catalyzed intermolecular condensation.

The problem of homochirality is of crucial importance for the origins of Life. While most laboratory studies are focused on the search of physical and chemical sources of handedness in the Universe, they reflect only one aspect of the problem: the origin of homochiral biomolecules. At the same time, any space environments where biomolecules are expected to form and where they have to pass through before the first primitive forms of Life emerge, include strong irradiation or/and high temperatures. This automatically implies the possibility of losing the optical activity, i.e. racemization. The simulation experiments performed by our group deal with the following two aspects of amino acid abiotic chemistry: (1) amino acid pyrolysis associated with their extraterrestrial delivery; and (2) peptide formation from amino acids catalyzed by inorganic oxides. According to our observations, the racemization phenomena are very common in the systems considered, not only under pyrolytic temperatures, but in some cases also under rather mild conditions (<100 degrees C). Our results put additional constraints on the environments where the chirality of biomolecules can be efficiently preserved.     

Solar X-ray Monitor (XSM) on-board Chandrayaan-2 orbiter

The remote X-ray fluorescence spectroscopy is a powerful technique to investigate the elemental abundances in the atmosphere-less planetary bodies. The experiment involves measuring spectra of fluorescent X-rays from lunar surface using a low energy X-ray detector onboard an orbiting satellite. Since the flux of fluorescent X-ray lines critically depend on the flux and spectrum of the incident solar X-rays, it is essential to have simultaneous and accurate measurement of X-ray from both Moon and Sun. In the context of Moon, this technique has been employed since early days of space exploration to determine elemental composition of lunar surface. However, so far it has not been possible to exploit it to its full potential due to various reasons. Therefore it is planned to continue the remote X-ray fluorescence spectroscopy experiment on-board Chandrayaan-2 which includes both lunar X-ray observations and solar X-ray observations as two separate payloads. The lunar X-ray observations will be carried out by Chandra Large Area Soft x-ray Spectrometer (CLASS) experiment; whereas the solar X-ray observations will be carried out by a separate payload, Solar X-ray Monitor (XSM). Here we present the overall design of the XSM instrument, the present development status as well as preliminary results of the laboratory model testing. XSM instrument will have two packages namely – XSM sensor package and XSM electronics package. XSM will accurately measure spectrum of Solar X-rays in the energy range of 1–15 keV with energy resolution ∼200 eV @ 5.9 keV. This will be achieved by using state-of-the-art Silicon Drift Detector (SDD), which has a unique capability of maintaining high energy resolution at very high incident count rate expected from Solar X-rays. XSM onboard Chandrayaan-2 will be the first experiment to use such detector for Solar X-ray monitoring.     

月球表面太空风化作用及其效应

太空风化作用普遍发生在月球、小行星等一些无大气层的天体表面, 主要包括太阳风离子辐射和微陨石撞击等作用. 通过对真实月球样品太空风化作用的研究成果以及低能离子和激光照射等地面模拟实验结果的系统综述和分析, 重点分析了月壤颗粒中非晶质层和纳米铁的成因, 指出太空风化研究中存在的太阳风离子辐射和微陨石撞击贡献难以区分及模拟实验模拟效果尚不充分的问题.进而提出月球太空风化研究不能简单套用其他天体的模型, 并建议未来开展更多月球和陨石样品的精细化学分析.      

The dynamics of the solar radiative zone

The picture of the solar radiative zone is evolving quickly. This review is separated in two parts. We first recall how the two powerful probes of the solar interior, namely the neutrinos and helioseismology have scrutinized the microscopic properties of the solar radiative plasma. Recent observations stimulate today complementary activities beyond the standard stellar model through theoretical modeling of angular momentum transport by rotation, internal waves or (and) by magnetic fields to get access to the dynamical motions of this important region of the Sun. So in the second part, we summarize the first impact of such processes on the radiative zone.     

A Review on the Ionospheric Research:Chinese Works During 2006—2008

This paper reviews various progresses on the ionospheric studies by the scientists in China during the last two years.The main contents concern the 4 aspects of the ionospheric re-search:(1) ionospheric weather and coupling with magnetosphere(polar and auroral ionosphere,ionospheric response to substorms,ionospheric storms);(2) mid-and low-latitude ionospheric clima-tology(ionospheric properties,yearly variations and solar activity dependence,long term variation);(3) ionospheric coupling with neutral atmosphere(gravity waves,tides,planetary waves,background upper atmosphere,and ionospheric response);and(4) ionospheric diagnostics(observation,modeling,and prediction).