Comparative analysis of chemical composition and optical properties of gaseous and disperse phases of the Earth-group planetary atmospheres

The models of chemical composition and structure of the Earth-type planetary atmospheres are offered. The optical properties of gaseous and disperse phases of the atmospheres are investigated.     

Laboratory experiments in the study of the chemistry of the outer planets.

The investigation of chemical evolution of bodies in our solar system has, in the past, included observations, theoretical modeling, and laboratory simulations. Of these programs, the last one has been the most criticized due to the inherent difficulties in accurately recreating alien environments in the laboratory. Processes such as wall reactions and changes in chemistry due to difficulties in achieving realistic conditions of temperature, pressure, composition, and energy flux may yield results which are not truly representative of the systems being modeled. However, many laboratory studies have been done which have yielded data useful in planetary science. Gross simulations of atmospheric chemistry have placed constraints on the nature of complex molecules expected in planetary atmospheres. More precise studies of specific chemical processes have provided information about the sources and properties of product gases and aerosols. Determinations of basic properties such as spectral features and reaction rate constants yield data useful in the interpretation of observations and in computational modeling. Alone, and in conjunction with modeling, laboratory experiments will continue to be used to further our understanding of the outer solar system, and some experiments that need to be done are listed.     

Formation of bioorganic compounds in planetary atmospheres by cosmic radiation.

Simulated planetary atmospheres (mixtures of simple gases) were irradiated with high energy particles to simulate an action of cosmic rays. When a mixture of carbon monoxide, nitrogen and water was irradiated with 2.8-40 MeV protons, a wide variety of bioorganic compounds including amino acids, imidazole, and uracil were identified in the products. The amount of amino acids was proportional to the energy deposit to the system. Various kinds of simulated planetary atmospheres, such as "Titan type" and "Jovian type", were also irradiated with high energy protons, and gave amino acids in the hydrolyzed products. Since cosmic rays are a universal energy source in space, it was suggested that formation of bioorganic compounds in planetary atmospheres is inevitable in the course of cosmic evolution.     

Comparison of methods for the determination of key reactions in chemical systems: Application to Titan’s atmosphere

A new paradigm is emerging in the field of photochemistry modeling in giant planets and Titan atmospheres. The emphasis is placed on the accurate predictions of the models and the quantification of their uncertainties. In order to improve photochemical models predictions, it is necessary to identify in chemical schemes the key reactions that should be studied in priority at conditions relevant to planetary atmospheres.     

Organic syntheses in gas phase and chemical evolution in planetary atmospheres

Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH₄, CO or CO₂), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres.     

The Planetary Laboratory for Image Analysis (PLIA)

The observation, characterization, and understanding of planetary atmospheres are key components of Solar System exploration. Their study requires, among other observations, the use of image data acquired from spacecrafts. The basic tasks that are generally used to work with planetary image data are: image navigation, projection, image processing, limb-darkening correction, composition of multiwavelength images and mosaicing. We illustrate the mathematical techniques required for the study of planetary images obtained from spacecrafts using as an example our own software package (PLIA). We present examples of analysis of Galileo SSI, Cassini ISS and Venus Express VIRTIS observations covering a large range of image peculiarities. The paper is organized as a guide for anyone willing to replicate one or several of the capabilities incorporated in the PLIA software. An open source version of PLIA for astronomical image processing is available.     

Raman scattering as a probe of planetary atmospheres

The observable effects of Raman scattering on the spectra of the giant planets may provide new information on the composition and structure of these atmospheres. Satellite observations have already shown the influence of Raman scattering on the UV continuum albedo. A cross correlation technique is presented for detecting rotational and vibrational transitions of the Raman active gases in the atmosphere. This technique has been applied to ground-based visible spectra of Venus, Jupiter, Saturn and Uranus. Extension of this method into the UV would improve the detectability of the Raman lines because the ratio of Raman to Rayleigh cross section increases with decreasing wavelength. The technology currently exists to efficiently obtain high signal-to-noise ratio UV spectra through the use of silicon diode array detectors. Application of the cross-correlation technique to UV spectra obtained from space vehicles would give us a new important probe of the structure and composition of planetary atmospheres by enabling us to use the UV spectra of a planet to observe that would normally be an infrared molecular transition.     

Isotopic ratios in planetary atmospheres.

Recent progress on measurements of isotopic ratios in planetary or satellite atmospheres include measurements of the D/H ratio in the methane of Uranus, Neptune and Titan and in the water of Mars and Venus. Implications of these measurements on our understanding of the formation and evolution of the planets and satellite are discussed. Our current knowledge of the carbon, nitrogen and oxygen isotopic ratios in the atmospheres of these planets, as well as on Jupiter and Saturn, is also reviewed. We finally show what progress can be expected in the very near future due to some new ground-based instrumentation particularly well suited to such studies, and to forthcoming space missions.     

Modification of planetary atmospheres by material from the rings

The atmospheres and ionospheres of ringed planets can be, and perhaps are, modified by the injection of gaseous neutral and ionized species, and dust of ring origin. Although no direct evidence for such interaction exists, many of the unresolved characteristics of planetary composition, thermal structure and ionosphere would be understood if the rings supplied certain materials to their parent planets.     

Infrared spectroscopy of organics of planetological interest at low temperatures.

In the context of prebiotic chemistry in space, some of the outer planetary objects display H, C, N and O rich chemistry similar to the one in the biosphere of Earth. Of particular interest are Saturn's moon, Titan; Neptune's moon, Triton; and Pluto where extreme cold conditions prevail. Identifications of chemical species on these objects (surfaces and atmospheres) is essential to a better understanding of the radiation induced chemical reactions occurring thereon. There have been several ground based observations of these planetary objects in the infrared windows from 1 to 2.5 micrometers. Voyager also provided spectra in the thermal infrared (6 to 50 micrometers) region. Interpretation of these data require laboratory infrared spectra of relevant species under the temperature conditions appropriate to these objects. The results of some of these studies carried out in our laboratory and elsewhere and their impact on the analyses of the observed data will be summarized.     

Space telescope studies of Jupiter and Saturn simulated by Voyager observations

Space Telescope (ST) observations of Jupiter and Saturn will offer a unique opportunity for monitoring their changing meteorological characteristics. They will provide higher spatial and temporal resolution for composition and vertical structure studies than have been available to date. We have simulated the planetary camera observations of Jupiter and Saturn by Voyager images of the appropriate spatial scale. With this data set we have investigated the meteorological properties of these atmospheres which can be studied at these scales. In addition we have considered the advances obtainable with the high resolution spectrometer on ST compared with observations from ground-based and other Earth-orbiting satellites. These studies will provide insight into the scientific gain and possible problems in the use of ST for planetary studies.     

The correlation of the planetary atmosphere structural characteristics with their optical properties and radiative heat exchange peculiarities

The structure characteristics of the Earth-type planetary atmospheres are calculated solving the radiative heat exchange problem. Their correlations with the surface reflection characteristics and optical properties of their atmospheres are considered.     

The escape of molecular hydrogen and the synthesis of organic nitriles in planetary atmospheres.

What is the influence of hydrogen escape from the atmosphere of small planetary bodies on the synthesis of organic molecules in that atmosphere? To answer this question, laboratory experiments have been performed to study the evolution of different reducing model atmospheres submitted to electrical discharges, with and without the simulation of H₂ escape. A study of mixtures of nitrogen and methane shows a very strong effect of H₂ escape on the formation of organic nitriles, the only nitrogen containing organics detected in the gas phase. These are HCN, CH  CCN, (CN)₂, CH₂CHCN, CH₃ CN and CH₃CH₂CN. The yield of synthesis of most of these compounds is noticeably increased, up to several orders of magnitude, when hydrogen escape is simulated. The escape of H₂ from the atmosphere of the primitive Earth may have played a crucial role in the formation of reactive organic molecules such as CHCCN or (CN)₂, which can be considered as important prebiotic precursors. These experimental results may also explain extant data concerning the nature and relative abundance of organics present in the atmosphere of Titan, a planetary satellite which may be an ideal model within our solar system for the study of organic cosmochemistry and exobiology.     

Past and future of radio occultation studies of planetary atmospheres

Measurements of radio waves that have propagated through planetary atmospheres have provided exploratory results on atmospheric constituents, structure, dynamics, and ionization for Venus, Mars, Titan, Jupiter, Saturn, and Uranus. Highlights of past results are reviewed in order to define and illustrate the potential of occultation and related radio studies in future planetary missions.     

The problems of simulation of planetary systems accumulation processes

Evolution of a system consisting of a great number of bodies that are gravitationally interacting and aggregating in contacts is considered. Body motions take place in the gravitational field of a central massive body (Sun or planet) in the same plane and at the initial time of system evolution orbits of all bodies are circular. It is shown that during evolution of the protoplanetary cloud, ring zones of matter rarefaction and condensation develop. Development of the condensation zones leads to the formation of planets, the most part of which acquire a direct rotation about their axes. In the case under consideration, approximate agreement between the law of planetary distances and that of geometric progression takes place as it is observed in planetary and satellite systems. The formation of the terrestrial planets and Jovian planets has been simulated. The principal numerical results have been obtained through digital simulation of planetary accumulation.     

系外行星大气与宜居系外行星研究进展及发展趋势

探测系外行星的主要目的是研究生命和可供地球生命生存的行星是否普遍存在这一基本科学问题.近20年来已有超过3000颗系外行星被发现,还有几千颗候选系外行星有待确认,其中疑似宜居系外行星的数量近20颗.未来十年疑似宜居系外行星的数目将大为增加.尽管目前对宜居系外行星大气观测的能力和科学结果还很有限,但可以预期未来20年对这一类行星大气的观测将成为行星科学研究的重要领域.本文根据当前系外行星大气科学发展的状态和主要科学问题,在对中国未来系外行星科学发展方向进行分析的基础上,提出一种比较可行的建议,即在近1~2年内有针对性地开展系外行星大气普查和系外行星高层大气观测的可行性论证和预研,并在5~10年内择一予以实施.      

Photospheric composition and structure in white dwarfs

One of the central mysteries of white dwarf studies has been the nature and abundance of trace elements in the atmospheres of these stars. It had been thought that the dominant trace element in otherwise pure hydrogen DA white dwarf atmospheres was helium. However, some spectroscopic and theoretical evidence suggested that, at least in some stars, heavier elements may be important. Prior to the launch of ROSAT the questions regarding the atmospheric composition of DA white dwarfs in general remained unresolved. The ROSAT mission has provided EUV and X-ray data for a large sample of DA white dwarfs with which we can study their photospheric composition and structure through the effect of trace opacity sources on the emergent fluxes. Contrary to expectations little (if any) helium is found and the main sources of opacity appear to be trace heavy elements. Support for these conclusions is found in recent EUV and far-UV spectra of several stars. However, photometric data do not allow us to determine the abundance of the individual elements and observations with the EUVE spectrometers will be essential for detailed composition measurements.     

Ultraviolet emissions from the upper atmospheres of the planets

A large number of atoms and molecules have strong emission lines in the vacuum ultraviolet. As a result, this spectral region is particularly suited to studying the upper atmospheres of the planets. The observed emissions not only identify the constituents, but also provide information on the solar and magnetospheric excitation processes. Long term monitoring of these emissions, particularly with modest spatial resolution, can elucidate the effects of variations in the solar input as well as changes in magnetospheric conditions. Also, earth orbiting telescopes generally provide better spectral resolution than is available on flyby vehicles. A modest beginning in planetary upper atmospheric studies from earth orbit has been made using orbiting observatories designed primarily for stellar astronomy. As examples of the power of this technique, some recent results will be reviewed with an emphasis on Jupiter and the Io torus. The unusual scheduling requirements and the effects of scattered intense long wavelength radiation put demands on orbiting planetary observatories which are somewhat different from those of stellar astronomy. The implications of these demands for continued advances in this area are discussed.     

Numerical simulation of organic compounds formation in planetary atmospheres: comparison with laboratory experiments.

A numerical model of CH4 and CH4-NH3 photochemistry at 147 nm has been developed and results are directly compared with experimental simulations carried out for the same mixtures. Simulations with varying quantities of ammonia and hydrogen show how amines and nitriles can be produce in planetary atmospheres. These comparisons allow one to test schemes of reactions used in photochemical models. In particular, it is shown that the scheme of reactions of CH4 is fairly well consistent with experimental data. On the other hand, the photochemistry of NH3 should be improved.     

New results on planetary lightning

We present the latest observations from spacecraft and ground-based instruments in search for lightning activity in the atmospheres of planets in the solar system, and put them in context of previous research. Since the comprehensive book on planetary atmospheric electricity compiled by Leblanc et al. (2008), advances in remote sensing technology and telescopic optics enable detection of additional and new electromagnetic and optical emissions, respectively. Orbiting spacecraft such as Mars Express, Venus Express and Cassini yield new results, and we highlight the giant storm on Saturn of 2010/2011 that was probably the single most powerful thunderstorm ever observed in the solar system. We also describe theoretical models, laboratory spark experiments simulating conditions in planetary mixtures and map open issues.