Mass-spectrometric in situ studies of cometary organics for p/Halley and options for the future.

When the VEGA and GIOTTO spacecrafts flew by comet p/Halley in 1986 the mass-spectrometers Puma and PIA measured the composition of cometary dust particles impacting at speeds of well above 65 km/s. Ion formation upon impact lead to mostly atomic ions. However, a small fraction of the ions measured could be related to molecules. A sophisticated analysis allowed for the first time to point to the chemical nature of cometary organics based on actual mass spectra. With the instrument CoMA for the NASA-BMFT mission CRAF much higher mass-resolution and molecule masses become accessible for in situ measurement, and will yield complementary information to the gas chromatograph CIDEX also onboard CRAF.     

Challenges of the rosetta sample return mission

Rosetta is a correrstone mission of the science programme of the European Space Agency (ESA) and it has been studied as a collaborative project with NASA. The major scientific objectives of Rosetta is to return cometary samples to Earth. About 20 kg of cometary material from up to 3m below the surface would be made available to the scientific community for analysis. Since relatively little is known a priory about the environment to be expected, the mission design must be based on a limited body of knowledge and rely on autonomy. The paper outlines the main mission characteristics and the experimental approach to demonstrate the mission feasibility.     

Planet-A mission to Halley

Looking at the chance of the next apparition of the Halley comet in 1986, ISAS decided to send a first Japasanese interplanetary spacecraft for the study of cometary hydrogen coma and solar wind. The Planet-A spacecraft which carries VUV imaging camera and solar wind plasma analyser will be launched in August 1985 and flyby the Halley comet in early March 1986 with the distance of several million kilometers from the comet nucleus. This mission is not only self-consistent but collaborative with other space mission as well as earth-bound observations. In the present paper, the Planet-A mission to Halley is described with brief explanation of the spacecraft.     

Thermal model and thermo-mechanical stresses in cometary nuclei

Spherically symmetric radial temperature profiles of cometary nuclei have been determined numerically (and for simplified models analytically) in dependence on the orbital position of the periodic comet Halley. These temperature fields in the nucleus are connected with thermal stress fields which have been calculated with the assumption of elastic properties of cometary matter. The remarkable result is the possible existence of stresses, strong enough to cause internal cracking of the nucleus and break-ups of the cometary surface. This may be essential understanding normal cometary activity as well as outbursts and splits.     

Cosmic dust physical properties and theICAPS facility on board the ISS

Cometary comae, cometary tails, and the interplanetary dust cloud, are low density dust clouds built of cosmic dust particles. Light scattering observations, from in-situ space probes and remote observatories, are a key to their physical properties. This presentation updates results on cometary and interplanetary dust derived from such observations (with emphasis on polarization), and compares them with results on asteroidal regoliths. The polarization phase curves follow similar trends, with parameters that may vary from one object to another. The wavelength dependence is highly variable, although it is usually linear in the visible domain. It may be suggested (from observations, modeling and laboratory measurements) that these dust particles are irregular, with a size greater than the wavelength, and that cometary dust is highly porous, as compared to asteroidal or interplanetary dust. Sophisticated numerical models and laboratory measurements on dust analogues are indeed required to interpret without any ambiguity the ensemble of results. The opportunity offered by the ICAPS facility (an ESA project selected for the ISS, now in phase B) to deduce the physical properties of cosmic dust particles from their optical properties, as well as their evolution (breaking-off and agglomeration, ices condensation and evaporation), is presented.     

Cometary probe of the Venera-Halley mission

Venera-Halley mission is to be launched to Venus in Dec. 1984. It will fly by Venus in June 1985. Separation of the cometary probe and Venera descend module will take place at that time. The gravitational swing-by at Venus will provide the encounter with the Halley comet in March 1986. The remote sensing of the inner coma (TV-imagery, spectrometry in the region from 1200 A to 12 μm, polarimetry) and of the nucleus, direct measurements of dust fluxes, dust composition, plasma and magnetic field are planned in the framework of multinational cooperation.     

Current status and scientific capabilities of the Rosetta lander payload

ESA's cornerstone mission “ROSETTA” to comet 46P/Wirtanen will bring a 100 kg Lander (provided by an international European consortium) with a scientific payload of about 27 kg to the surface of the comet's nucleus. After a first scientific sequence it will operate for a considerable fraction of the cometary orbit around the sun (between 3 AU and 2 AU). The Lander is an autonomous spacecraft, powered with solar cells and using the ROSETTA Orbiter as a telemetry relais to Earth. The main scientific objectives are the in-situ investigation of the chemical, elemental, isotopic and mineralogical composition of the comet, study of the physical properties of the surface material, analyze the internal structure of the nucleus, observe temporal variations (day/night cycle, approach to sun), study the relationship between the comet and the interplanetary matter and provide ground reference data for Orbiter instruments.Ten experiments with a number of sub-experiments are foreseen to fulfil these objectives.In this paper we present the current status of the instrumental development and the scientific capabilities of each of the experiments.     

The Giotto mission to Halley''s comet

ESA's Giotto mission to Halley's comet is a fast flyby in March 1986, about four weeks after the comet's perihelion passage when it is most active. The scientific payload comprises 10 experiments with a total mass of about 60 kg: a camera for imaging the comet nucleus, three mass spectrometers for analysis of the elemental and isotopic composition of the cometary gas and dust environment, various dust impact detectors, a photopolarimeter for measurements of the coma brightness, and a set of plasma instruments for studies of the solar wind/comet interaction. In view of the high flyby velocity of 68 km/s the experiment active time is very short (only 4 hours) and all data are transmitted back to Earth in real time at a rate of 40 kbps. The Giotto spacecraft is spin-stabilised with a despun high gain parabolic dish antenna inclined at 44.3° to point at the Earth during the encounter while a specially designed dual-sheet bumper shield at the other end protects the spacecraft from being destroyed by hypervelocity dust impacts. The mission will probably end near the point of closest approach to the nucleus when the spacecraft attitude will be severely perturbed by impacting dust particles leading to a loss of the telecommunications link.     

Cometary magnetospheres: a tutorial

The nucleus of an active comet, such as comet Halley near its perihelion, produces large quantities of gas and dust. The resulting cometary atmosphere, or coma, extends more than a million kilometers into space, where it interacts with the solar wind. An “induced” cometary magnetosphere is a consequence of this interaction. Cometary ion pick-up and mass loading of the solar wind starts to take place at very large cometocentric distances. Eventually this mass loading leads to the formation of a weak cometary bow shock. Even closer to the nucleus, collisional processes, such as ion-neutral chemistry, become important. Other features of the magnetosphere of an active comet include a magnetic barrier, a magnetotail, and a diamagnetic cavity near the nucleus. X-ray emission from comets is produced by the interaction of the solar wind with cometary neutrals and this topic is also discussed. A broad review of the cometary magnetosphere will be given in this paper.     

Evaluating the robustness of the enantioselective stationary phases on the Rosetta mission against space vacuum vaporization

The European Space Agency’s Rosetta mission was launched in March 2004 in order to reach comet 67P/Churyumov–Gerasimenko by August 2014. The Cometary Sampling and Composition experiment (COSAC) onboard the Rosetta mission’s lander “Philae” has been designed for the cometary in situ detection and quantification of organic molecules using gas chromatography coupled to mass spectrometry (GC–MS). The GC unit of COSAC is equipped with eight capillary columns that will each provide a specific stationary phase for molecular separation. Three of these stationary phases will be used to chromatographically resolve enantiomers, as they are composed of liquid polymers of polydimethylsiloxane (PDMS) to which chiral valine or cyclodextrin units are attached. Throughout the ten years of Rosetta’s journey through space to reach comet 67P, these liquid stationary phases have been exposed to space vacuum, as the capillary columns within the COSAC unit were not sealed or filled with carrier gas. Long term exposures to space vacuum can cause damage to such liquid stationary phases as key monomers, volatiles, and chiral selectors can be vaporized and lost in transit. We have therefore exposed identical spare units of COSAC’s chiral stationary phases over eight years to vacuum conditions mimicking those experienced in space and we have now investigated their resolution capabilities towards different enantiomers both before and after exposure to space vacuum environments. We have observed that enantiomeric resolution capabilities of these chiral liquid enantioselective stationary phases has not been affected by exposure to space vacuum conditions. Thus we conclude that the three chiral stationary phases of the COSAC experiment onboard the Rosetta mission lander “Philae” can be considered to have maintained their resolution capacities throughout their journey prior to cometary landing in November 2014.     

Simulation of cometary jets in interaction with the solar wind

The influence of cometary jets on the solar wind interaction is studied with a 3D hybrid simulation. Anisotropic outgassing patterns were until recently not considered in cometary simulations, despite strong anisotropies found at observations. Comet 67P Churyumov–Gerasimenko, the target of the ROSETTA mission, was chosen as a case study for a simulation series. The cometary outgassing at 2.7 AU is modeled to originate from a single sun-facing jet with different levels of collimation, from isotropy to extremely thin jets. As no bow shock is present at this distance, solar wind patterns resulting from the anisotropic outgassing become more apparent. We find narrower jets to increase the standoff distance of the plasma interaction structures. Also, the Mach cone is wider and stronger for certain jet profiles. The magnetic field remains unable to propagate through the coma, resulting in strong draping patterns for narrow jets due to the increased standoff distance.     

First results of plasma and neutral gas measurements from Vega-1/2 near comet Halley

Based on the ion, electron and neutral gas observations, performed by five of the six sensors comprising the PLASMAG-1 experiment on board VEGA-1 and -2, the following results are discussed: (1) the existence of the bow shock and its location at 1.1×10⁶ km for VEGA-1 inbound; (2) the existence of a cometopause and its location at 1.6×10⁵ km for VEGA-2 inbound; (3) the plasma dynamical processes occurring inside the cometosheath; (4) the phenomena taking place within the cometary plasma region including mass-spectroscopy of cometary ions at distances 1.5×10⁴ km; (5) the existence of keV electrons near closest approach to the nucleus; and (6) the radial dependence of the cometary neutral gas and the comparison with model calculations, yielding a mean ionization scale length of 2×10⁶ km and an overall production rate of 1.3×10³⁰ molecules s⁻¹ for VEGA-1 inbound. The results are also discussed in the context of the other, both remote and in-situ, observations, performed on board the VEGA- and GIOTTO-spacecraft.     

The contemporary model of cometary nucleus and the prospects of its improvement by space research

No cometary nucleus has ever been observed directly. A model is deduced from ground-based and space data on cometary atmospheres. The main features of the chemical composition of cometary nuclei and the estimation of their sizes are described. The treatment of the process of vaporization of dusty ice shows, contrary to widespread opinion, that the islands on the non-volatile porous mantle are formed, not in perihelion but at large heliocentric distances and on the coldest parts of a nucleus. It is shown that the mantle does not disappear when the comet approaches the Sun, as it is often supposed, but is fluidized. The proposed model can give a number of properties of cometary nuclei but some of them can be established by direct space methods only. Such properties are the masses, the rotational velocities, the homogeneity of the dust-ice mixture, the internal structure, the power of the internal sources of energy.     

Simulated cometary matter as a test for enantiomer separating chromatography for use on comet 46P/Wirtanen.

The Cometary Sampling and Composition Experiment on board of European Space Agency's cornerstone mission ROSETTA is designed to identify organic molecules in cometary matter in situ by a combined pyrolysis gas chromatographic and mass spectrometric technique. Its capillary columns coated with chiral stationary phases received considerable attention, because they are designed for separations of non-complex enantiomers to allow the determination of enantiomeric ratios of cometary chiral organic compounds and consequently to provide information about the origin of molecular parity violation in biomolecules. To get gas chromatographic access to organic compounds on the comet, where macromolecules and complex organic polymers of low volatility are expected to make up the main organic ingredients, the combination of two injection techniques will be applied. The pyrolysis technique performed by heating cometary samples stepwise to defined temperatures in specific ovens resulting in thermochemolysis reactions of polymers and a chemical derivatization technique, in which the reagent dimethylformamide dimethylacetal assists pyrolysis derivatization reactions in producing methyl esters of polar monomers. The combination of the reagent assisted pyrolysis gas chromatographic technique with enantiomer separating chromatography was tested with laboratory-produced simulated cometary matter.     

On the conditions for fluidisation in cometary mantles

In our current understanding, active cometary nuclei comprise a volatile-depleted outer crust covering a mixture of dust and ices. During each perihelion passage the thermal wave penetrates the crust and sublimates a portion of these ices, which then escape the nucleus, dragging with them dust particles that replenish the coma and dust tail. The flux of released gases is likely to vary as a complex function of solar distance, nucleus structure, spin rate, etc. It has been previously hypothesised that at some point a fluidised state could occur, in which the gas drag is approximately equal to the weight of overlying dust and ice grains. This state is well understood and used in industrial processes where extensive mixing of the gas and solid components is desired. The literature on fluidisation under reduced gravity and pressure conditions is here reviewed and published relations used to predict the conditions under which fluidisation could occur in the near-surface of a cometary nucleus.     

A European probe to comet Halley

A European probe to comet Halley is proposed. The probe's model payload consists of 8 scientific instruments, viz. neutral, ion and dust impact mass spectrometers, magnetometer, medium energy ion and electron analyzer, camera, dust impact detectors and plasma wave experiment. Fly-by of the comet Halley nucleus will take place on November 28th, 1985, at about 500 km miss distance. The main spacecraft serves as relay link to transmit the observed data to Earth. As probe, a modified ISEE 2 design is proposed. Because of the cometary dust hazard expected in the coma a heavy dust shield (27 kg) is required, consisting of a thin front sheet and a 3 layer rear sheet. The probe is spin-stabilized (12 rpm), has no active attitude and orbit control capability and uses battery power only to provide about 1000 Wh for a measuring phase. A despun antenna transmits up to 20 kbit/s, in X-band. The total probe mass is estimated at 250 kg. The 3 model development programme should start in mid 1981 with Phase B.     

EUV observations of Comet Halley

The observation of EUV emissions of comet Halley and its plasma-gas environment by means of rocket- or satellite-borne resonance absorption cell spectrophotometer devices is planned. The technical outlay of the payload, the estimated EUV intensities, and the scientific objectives of this mission are presented. Due to complete suppression of the geocoronal He I emissions by He I resonance absorption cells, a quantitative identification of the cometary object in the He I 58.4 nm line is possible, if the He/H abundance ratio in the evaporating cometary matter is higher than 4.0 E-4.     

Dusty cometary atmospheres

This paper summarizes our present understanding of the physical processes controlling the dust and gas production of cometary nuclei and the evolution of the dusty gas flow in the inner coma. Special emphasis is being made to compile a self-consistent set of governing equations describing the accelerating dusty gas flow in a cometary atmosphere.     

Trapping of gases by water ice and implications for icy bodies.

The trapping of various gases by water ice at low temperatures (20-80K) and their release from the ice upon warming, was studied experimentally. The results of these experiments, together with a computation of the thermal evolution of a cometary nucleus, can explain the gas and dust jets which were observed to emanate from the nucleus of P/Halley. The experimental results are important also to the gas content of Titan.