Cratering Chronology and the Evolution of Mars

Results by Neukum et al. (2001) and Ivanov (2001) are combined with crater counts to estimate ages of Martian surfaces. These results are combined with studies of Martian meteorites (Nyquist et al., 2001) to establish a rough chronology of Martian history. High crater densities in some areas, together with the existence of a 4.5 Gyr rock from Mars (ALH84001), which was weathered at about 4.0 Gyr, affirm that some of the oldest surfaces involve primordial crustal materials, degraded by various processes including megaregolith formation and cementing of debris. Small craters have been lost by these processes, as shown by comparison with Phobos and with the production function, and by crater morphology distributions. Crater loss rates and survival lifetimes are estimated as a measure of average depositional/erosional rate of activity.We use our results to date the Martian epochs defined by Tanaka (1986). The high crater densities of the Noachian confine the entire Noachian Period to before about 3.5 Gyr. The Hesperian/Amazonian boundary is estimated to be about 2.9 to 3.3 Gyr ago, but with less probability could range from 2.0 to 3.4 Gyr. Mid-age dates are less well constrained due to uncertainties in the Martian cratering rate. Comparison of our ages with resurfacing data of Tanaka et al. (1987) gives a strong indication that volcanic, fluvial, and periglacial resurfacing rates were all much higher in approximately the first third of Martian history. We estimate that the Late Amazonian Epoch began a few hundred Myr ago (formal solutions 300 to 600 Myr ago). Our work supports Mariner 9 era suggestions of very young lavas on Mars, and is consistent with meteorite evidence for Martian igneous rocks 1.3 and 0.2 – 0.3 Gyr old. The youngest detected Martian lava flows give formal crater retention ages of the order 10 Myr or less. We note also that certain Martian meteorites indicate fluvial activity younger than the rock themselves, 700 Myr in one case, and this is supported by evidence of youthful water seeps. The evidence of youthful volcanic and aqueous activity, from both crater-count and meteorite evidence, places important constraints on Martian geological evolution and suggests a more active, complex Mars than has been visualized by some researchers.     

Martian Volatiles: Isotopic Composition, Origin, and Evolution

Information about the composition of volatiles in the Martian atmosphere and interior derives from Viking spacecraft and ground-based measurements, and especially from measurements of volatiles trapped in Martian meteorites, which contain several distinct components. One volatile component, found in impact glass in some shergottites, gives the most precise measurement to date of the composition of Martian atmospheric Ar, Kr, and Xe, and also contains significant amounts of atmospheric nitrogen showing elevated ¹⁵N/¹⁴N. Compared to Viking analyses, the ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are larger in shergottites, the ¹²⁹Xe/¹³²Xe ratio is similar, and the ⁴⁰Ar/³⁶Ar and ³⁶Ar/³⁸Ar ratios are smaller. The isotopic composition of atmospheric Kr is very similar to solar Kr, whereas the isotopes of atmospheric Xe have been strongly mass fractionated in favor of heavier isotopes. The nakhlites and ALH84001 contain an atmospheric component elementally fractionated relative to the recent atmospheric component observed in shergottites. Several Martian meteorites also contain one or more Martian interior components that do not show the mass fractionation observed in atmospheric noble gases and nitrogen. The D/H ratio in the atmosphere is strongly mass fractionated, but meteorites contain a distinct Martian interior hydrogen component. The isotopic composition of Martian atmospheric carbon and oxygen have not been precisely measured, but these elements in meteorites appear to show much less variation in isotopic composition, presumably in part because of buffering of the atmospheric component by larger condensed reservoirs. However, differences in the oxygen isotopic composition between meteorite silicate minerals (on the one hand) and water and carbonates indicate a lack of recycling of these volatiles through the interior. Many models have been presented to explain the observed isotopic fractionation in Martian atmospheric N, H, and noble gases in terms of partial loss of the planetary atmosphere, either very early in Martian history, or over extended geological time. The number of variables in these models is large, and we cannot be certain of their detailed applicability. Evolutionary data based on the radiogenic isotopes (i.e., ⁴⁰Ar/³⁶Ar, ¹²⁹Xe/¹³²Xe, and ¹³⁶Xe/¹³²Xe ratios) are potentially important, but meteorite data do not yet permit their use in detailed chronologies. The sources of Mars' original volatiles are not well defined. Some Martian components require a solar-like isotopic composition, whereas volatiles other than the noble gases (C, N, and H₂O) may have been largely contributed by a carbonaceous (or cometary) veneer late in planet formation. Also, carbonaceous material may have been the source of moderate amounts of water early in Martian history.     

Alteration Assemblages in Martian Meteorites: Implications for Near-Surface Processes

The SNC (Shergotty-Nakhla-Chassigny) meteorites have recorded interactions between martian crustal fluids and the parent igneous rocks. The resultant secondary minerals — which comprise up to 1 vol.% of the meteorites — provide information about the timing and nature of hydrous activity and atmospheric processes on Mars. We suggest that the most plausible models for secondary mineral formation involve the evaporation of low temperature (25 – 150 °C) brines. This is consistent with the simple mineralogy of these assemblages — Fe-Mg-Ca carbonates, anhydrite, gypsum, halite, clays — and the chemical fractionation of Ca-to Mg-rich carbonate in ALH84001 "rosettes". Longer-lived, and higher temperature, hydrothermal systems would have caused more silicate alteration than is seen and probably more complex mineral assemblages. Experimental and phase equilibria data on carbonate compositions similar to those present in the SNCs imply low temperatures of formation with cooling taking place over a short period of time (e.g. days). The ALH84001 carbonate also probably shows the effects of partial vapourisation and dehydration related to an impact event post-dating the initial precipitation. This shock event may have led to the formation of sulphide and some magnetite in the Fe-rich outer parts of the rosettes.Radiometric dating (K-Ar, Rb-Sr) of the secondary mineral assemblages in one of the nakhlites (Lafayette) suggests that they formed between 0 and 670 Myr, and certainly long after the crystallisation of the host igneous rocks. Crystallisation of ALH84001 carbonate took place 0.5 Gyr after the parent rock. These age ranges and the other research on these assemblages suggest that environmental conditions conducive to near-surface liquid water have been present on Mars periodically over the last 1 Gyr. This fluid activity cannot have been continuous over geological time because in that case much more silicate alteration would have taken place in the meteorite parent rocks and the soluble salts would probably not have been preserved.The secondary minerals could have been precipitated from brines with seawater-like composition, high bicarbonate contents and a weakly acidic nature. The co-existence of siderite (Fe-carbonate) and clays in the nakhlites suggests that the pCO₂ level in equilibrium with the parent brine may have been 50 mbar or more. The brines could have originated as flood waters which percolated through the top few hundred meters of the crust, releasing cations from the surrounding parent rocks. The high sulphur and chlorine concentrations of the martian soil have most likely resulted from aeolian redistribution of such aqueously-deposited salts and from reaction of the martian surface with volcanic acid volatiles.The volume of carbonates in meteorites provides a minimum crustal abundance and is equivalent to 50–250 mbar of CO₂ being trapped in the uppermost 200–1000 m of the martian crust. Large fractionations in ¹⁸O between igneous silicate in the meteorites and the secondary minerals (30) require formation of the latter below temperatures at which silicate-carbonate equilibration could have taken place (400°C) and have been taken to suggest low temperatures (e.g. 150°C) of precipitation from a hydrous fluid.     

Geochemistry of Carbonates on Mars: Implications for Climate History and Nature of Aqueous Environments

Ongoing research on martian meteorites and a new set of observations of carbonate minerals provided by an unprecedented series of robotic missions to Mars in the past 15 years help define new constraints on the history of martian climate with important crosscutting themes including: the CO₂ budget of Mars, the role of Mg-, Fe-rich fluids on Mars, and the interplay between carbonate formation and acidity. Carbonate minerals have now been identified in a wide range of localities on Mars as well as in several martian meteorites. The martian meteorites contain carbonates in low abundances (<1 vol.%) and with a wide range of chemistries. Carbonates have also been identified by remote sensing instruments on orbiting spacecraft in several surface locations as well as in low concentrations (2–5 wt.%) in the martian dust. The Spirit rover also identified an outcrop with 16 to 34 wt.% carbonate material in the Columbia Hills of Gusev Crater that strongly resembled the composition of carbonate found in martian meteorite ALH 84001. Finally, the Phoenix lander identified concentrations of 3–6 wt.% carbonate in the soils of the northern plains. The carbonates discovered to date do not clearly indicate the past presence of a dense Noachian atmosphere, but instead suggest localized hydrothermal aqueous environments with limited water availability that existed primarily in the early to mid-Noachian followed by low levels of carbonate formation from thin films of transient water from the late Noachian to the present. The prevalence of carbonate along with evidence for active carbonate precipitation suggests that a global acidic chemistry is unlikely and a more complex relationship between acidity and carbonate formation is present.     

The Accretion, Composition and Early Differentiation of Mars

The early development of Mars is of enormous interest, not just in its own right, but also because it provides unique insights into the earliest history of the Earth, a planet whose origins have been all but obliterated. Mars is not as depleted in moderately volatile elements as are other terrestrial planets. Judging by the data for Martian meteorites it has Rb/Sr 0.07 and K/U 19,000, both of which are roughly twice as high as the values for the Earth. The mantle of Mars is also twice as rich in Fe as the mantle of the Earth, the Martian core being small (20% by mass). This is thought to be because conditions were more oxidizing during core formation. For the same reason a number of elements that are moderately siderophile on Earth such as P, Mn, Cr and W, are more lithophile on Mars. The very different apparent behavior of high field strength (HFS) elements in Martian magmas compared to terrestrial basalts and eucrites may be related to this higher phosphorus content. The highly siderophile element abundance patterns have been interpreted as reflecting strong partitioning during core formation in a magma ocean environment with little if any late veneer. Oxygen isotope data provide evidence for the relative proportions of chondritic components that were accreted to form Mars. However, the amount of volatile element depletion predicted from these models does not match that observed — Mars would be expected to be more depleted in volatiles than the Earth. The easiest way to reconcile these data is for the Earth to have lost a fraction of its moderately volatile elements during late accretionary events, such as giant impacts. This might also explain the non-chondritic Si/Mg ratio of the silicate portion of the Earth. The lower density of Mars is consistent with this interpretation, as are isotopic data. ⁸⁷Rb-⁸⁷Sr, ¹²⁹I-¹²⁹Xe, ¹⁴⁶Sm-¹⁴²Nd, ¹⁸²Hf-¹⁸²W, ¹⁸⁷Re-¹⁸⁷Os, ²³⁵U-²⁰⁷Pb and ²³⁸U-²⁰⁶Pb isotopic data for Martian meteorites all provide evidence that Mars accreted rapidly and at an early stage differentiated into atmosphere, mantle and core. Variations in heavy xenon isotopes have proved complicated to interpret in terms of ²⁴⁴Pu decay and timing because of fractionation thought to be caused by hydrodynamic escape. There are, as yet, no resolvable isotopic heterogeneities identified in Martian meteorites resulting from ⁹²Nb decay to ⁹²Zr, consistent with the paucity of perovskite in the martian interior and its probable absence from any Martian magma ocean. Similarly the longer-lived ¹⁷⁶Lu-¹⁷⁶Hf system also preserves little record of early differentiation. In contrast W isotope data, Ba/W and time-integrated Re/Os ratios of Martian meteorites provide powerful evidence that the mantle retains remarkably early heterogeneities that are vestiges of core metal segregation processes that occurred within the first 20 Myr of the Solar System. Despite this evidence for rapid accretion and differentiation, there is no evidence that Mars grew more quickly than the Earth at an equivalent size. Mars appears to have just stopped growing earlier because it did not undergo late stage (>20 Myr), impacts on the scale of the Moon-forming Giant Impact that affected the Earth.     

Core Formation and Mantle Differentiation on Mars

Geochemical investigation of Martian meteorites (SNC meteorites) yields important constraints on the chemical and geodynamical evolution of Mars. These samples may not be representative of the whole of Mars; however, they provide constraints on the early differentiation processes on Mars. The bulk composition of Martian samples implies the presence of a metallic core that formed concurrently as the planet accreted. The strong depletion of highly siderophile elements in the Martian mantle is only possible if Mars had a large scale magma ocean early in its history allowing efficient separation of a metallic melt from molten silicate. The solidification of the magma ocean created chemical heterogeneities whose ancient origin is manifested in the heterogeneous ¹⁴²Nd and ¹⁸²W abundances observed in different meteorite groups derived from Mars. The isotope anomalies measured in SNC meteorites imply major chemical fractionation within the Martian mantle during the life time of the short-lived isotopes ¹⁴⁶Sm and ¹⁸²Hf. The Hf-W data are consistent with very rapid accretion of Mars within a few million years or, alternatively, a more protracted accretion history involving several large impacts and incomplete metal-silicate equilibration during core formation. In contrast to Earth early-formed chemical heterogeneities are still preserved on Mars, albeit slightly modified by mixing processes. The preservation of such ancient chemical differences is only possible if Mars did not undergo efficient whole mantle convection or vigorous plate tectonic style processes after the first few tens of millions of years of its history.     

Long-Term Evolution of the Martian Crust-Mantle System

Lacking plate tectonics and crustal recycling, the long-term evolution of the crust-mantle system of Mars is driven by mantle convection, partial melting, and silicate differentiation. Volcanic landforms such as lava flows, shield volcanoes, volcanic cones, pyroclastic deposits, and dikes are observed on the martian surface, and while activity was widespread during the late Noachian and Hesperian, volcanism became more and more restricted to the Tharsis and Elysium provinces in the Amazonian period. Martian igneous rocks are predominantly basaltic in composition, and remote sensing data, in-situ data, and analysis of the SNC meteorites indicate that magma source regions were located at depths between 80 and 150 km, with degrees of partial melting ranging from 5 to 15 %. Furthermore, magma storage at depth appears to be of limited importance, and secular cooling rates of 30 to 40 K?Gyr^?1 were derived from surface chemistry for the Hesperian and Amazonian periods. These estimates are in general agreement with numerical models of the thermo-chemical evolution of Mars, which predict source region depths of 100 to 200 km, degrees of partial melting between 5 and 20 %, and secular cooling rates of 40 to 50 K?Gyr^?1. In addition, these model predictions largely agree with elastic lithosphere thickness estimates derived from gravity and topography data. Major unknowns related to the evolution of the crust-mantle system are the age of the shergottites, the planet’s initial bulk mantle water content, and its average crustal thickness. Analysis of the SNC meteorites, estimates of the elastic lithosphere thickness, as well as the fact that tidal dissipation takes place in the martian mantle indicate that rheologically significant amounts of water of a few tens of ppm are still present in the interior. However, the exact amount is controversial and estimates range from only a few to more than 200 ppm. Owing to the uncertain formation age of the shergottites it is unclear whether these water contents correspond to the ancient or present mantle. It therefore remains to be investigated whether petrologically significant amounts of water of more than 100 ppm are or have been present in the deep interior. Although models suggest that about 50 % of the incompatible species (H₂O, K, Th, U) have been removed from the mantle, the amount of mantle differentiation remains uncertain because the average crustal thickness is merely constrained to within a factor of two.     

Geophysical Constraints on the Evolution of Mars

The evolution of Mars is discussed using results from the recent Mars Global Surveyor (MGS) and Mars Pathfinder missions together with results from mantle convection and thermal history models and the chemistry of Martian meteorites. The new MGS topography and gravity data and the data on the rotation of Mars from Mars Pathfinder constrain models of the present interior structure and allow estimates of present crust thickness and thickness variations. The data also allow estimates of lithosphere thickness variation and heat flow assuming that the base of the lithosphere is an isotherm. Although the interpretation is not unambiguous, it can be concluded that Mars has a substantial crust. It may be about 50 km thick on average with thickness variations of another ±50 km. Alternatively, the crust may be substantially thicker with smaller thickness variations. The former estimate of crust thickness can be shown to be in agreement with estimates of volcanic production rates from geologic mapping using data from the camera on MGS and previous missions. According to these estimates most of the crust was produced in the Noachian, roughly the first Gyr of evolution. A substantial part of the lava generated during this time apparently poured onto the surface to produce the Tharsis bulge, the largest tectonic unit in the solar system and the major volcanic center of Mars. Models of crust growth that couple crust growth to mantle convection and thermal evolution are consistent with an early 1 Gyr long phase of vigorous volcanic activity. The simplest explanation for the remnant magnetization of crustal units of mostly the southern hemisphere calls for an active dynamo in the Noachian, again consistent with thermal history calculations that predict the core to become stably stratified after some hundred Myr of convective cooling and dynamo action. The isotope record of the Martian meteorites suggest that the core formed early and rapidly within a few tens of Myr. These data also suggest that the silicate rock component of the planet was partially molten during that time. The isotope data suggest that heterogeneity resulted from core formation and early differentiation and persisted to the recent past. This is often taken as evidence against vigorous mantle convection and early plate tectonics on Mars although the latter assumption can most easily explain the early magnetic field. The physics of mantle convection suggests that there may be a few hundred km thick stagnant, near surface layer in the mantle that would have formed rapidly and may have provided the reservoirs required to explain the isotope data. The relation between the planform of mantle convection and the tectonic features on the surface is difficult to entangle. Models call for long wavelength forms of flow and possibly a few strong plumes in the very early evolution. These plumes may have dissolved with time as the core cooled and may have died off by the end of the Noachian.     

Martian Seeps and their Relation to Youthful Geothermal Activity

Gullies found on Martian hillsides by Malin and Edgett (2000) appear in many cases to be formed by water seeps produced by underground aquifers. It is proposed that these aquifers result from geologically recent melting of permafrost ice by sporadic, localized geothermal activity. This is consistent with evidence from crater counts and Martian meteorites that much higher-temperature geothermal activity has produced volcanic activity and lava flows within the last 200 Myr, and perhaps within the last 10 Myr. This hypothesis explains an aspect initially described as surprising, namely concentration of the gullies at high latitudes and on shadowed slopes. Similar features are found on Icelandic basaltic hillsides, which may be ideal analogs for further studies that may clarify the Martian phenomena.     

Locations of Atmospheric Photoelectron Energy Peaks Within the Mars Environment

By identifying peaks in the photoelectron spectrum produced by photoionization of CO₂ in the Martian atmosphere, we have conducted a pilot study to determine the locations of these photoelectrons in the space around Mars. The significant result of this study is that these photoelectrons populate a region around Mars bounded externally by the magnetic pileup boundary, and internally by the lowest altitude of our measurements (∼250 km) on the dayside and by a cylinder of approximately the planetary radius on the nightside. It is particularly noteworthy that the photoelectrons on the nightside are observed from the terminator plane tailward to a distance of ∼3 R _M, the Mars Express apoapsis. The presence of the atmospherically generated photoelectrons on the nightside of Mars may be explained by direct magnetic field line connection between the nightside observation locations and the Martian dayside ionosphere. Thus the characteristic photoelectron peaks may be used as tracers of magnetic field lines for the study of the magnetic field configuration and particle transport in the Martian environment.     

Geochemical Reservoirs and Timing of Sulfur Cycling on Mars

Sulfate-dominated sedimentary deposits are widespread on the surface of Mars, which contrasts with the rarity of carbonate deposits, and indicates surface waters with chemical features drastically different from those on Earth. While the Earth’s surface chemistry and climate are intimately tied to the carbon cycle, it is the sulfur cycle that most strongly influences the Martian geosystems. The presence of sulfate minerals observed from orbit and in-situ via surface exploration within sedimentary rocks and unconsolidated regolith traces a history of post-Noachian aqueous processes mediated by sulfur. These materials likely formed in water-limited aqueous conditions compared to environments indicated by clay minerals and localized carbonates that formed in surface and subsurface settings on early Mars. Constraining the timing of sulfur delivery to the Martian exosphere, as well as volcanogenic H₂O is therefore central, as it combines with volcanogenic sulfur to produce acidic fluids and ice. Here, we reassess and review the Martian geochemical reservoirs of sulfur from the innermost core, to the mantle, crust, and surficial sediments. The recognized occurrences and the mineralogical features of sedimentary sulfate deposits are synthesized and summarized. Existing models of formation of sedimentary sulfate are discussed and related to weathering processes and chemical conditions of surface waters. We also review existing models of sulfur content in the Martian mantle and analyze how volcanic activities may have transferred igneous sulfur into the exosphere and evaluate the mass transfers and speciation relationships between volcanic sulfur and sedimentary sulfates. The sedimentary clay-sulfate succession can be reconciled with a continuous volcanic eruption rate throughout the Noachian-Hesperian, but a process occurring around the mid-Noachian must have profoundly changed the composition of volcanic degassing. A hypothetical increase in the oxidation state or in water content of Martian lavas or a decrease in atmospheric pressure is necessary to account for such a change in composition of volcanic gases. This would allow the pre mid-Noachian volcanic gases to be dominated by water and carbon-species but late Noachian and Hesperian volcanic gases to be sulfur-rich and characterized by high SO₂ content. Interruption of early dynamo and impact ejection of the atmosphere may have decreased the atmospheric pressure during the early Noachian whereas it remains unclear how the redox state or water content of lavas could have changed. Nevertheless, volcanic emission of SO₂ rich gases since the late Noachian can explain many features of Martian sulfate-rich regolith, including the mass of sulfate and the particular chemical features (i.e. acidity) of surface waters accompanying these deposits. How SO₂ impacted on Mars’s climate, with possible short time scale global warming and long time scale cooling effects, remains controversial. However, the ancient wet and warm era on Mars seems incompatible with elevated atmospheric sulfur dioxide because conditions favorable to volcanic SO₂ degassing were most likely not in place at this time.     

The Modern Near-Surface Martian Climate: A Review of In-situ Meteorological Data from Viking to Curiosity

We analyze the complete set of in-situ meteorological data obtained from the Viking landers in the 1970s to today’s Curiosity rover to review our understanding of the modern near-surface climate of Mars, with focus on the dust, CO₂ and H₂O cycles and their impact on the radiative and thermodynamic conditions near the surface. In particular, we provide values of the highest confidence possible for atmospheric opacity, atmospheric pressure, near-surface air temperature, ground temperature, near-surface wind speed and direction, and near-surface air relative humidity and water vapor content. Then, we study the diurnal, seasonal and interannual variability of these quantities over a span of more than twenty Martian years. Finally, we propose measurements to improve our understanding of the Martian dust and H₂O cycles, and discuss the potential for liquid water formation under Mars’ present day conditions and its implications for future Mars missions. Understanding the modern Martian climate is important to determine if Mars could have the conditions to support life and to prepare for future human exploration.     

Chemistry,accretion, and evolution of Mars

The high FeO concentrations measured by VIKING for the Martian soils correspond to all probability to a FeO-rich mantle. In general, the VIKING XRF-data indicate a mafic crust with a considerably smaller degree of fractionation compared to the terrestrial crust.In recent years evidence has been collected which points towards Mars being the parent body of SNC-meteorites and, hence, these meteorites have become a valuable source of information about the chemistry of Mars. Using element correlations observed in SNC-meteorites and general cosmochemical constraints, it is possible to estimated the bulk composition of Mars. Normalized to Si and Cl, the mean abundance value for the elements Ga, Fe, Na, P, K, F, and Rb in the Martian mantle is found to be 0.35 and thus exceeds the terrestrial value by about a factor of two. Aside pressure effects and the H₂O poverty, the high P and K content of the Martian mantle may lead to magmatic processes different from those on Earth.The composition of the Earth's mantle can successfully be described by a two component model. Component A: highly reduced and almost free of all elements more volatile than Na; component B: oxidized and containing all elements in Cl-abundances including volatile elements. The same two components can be used as building blocks for Mars, if one assumes that, contrary to the inhomogeneous accretion of the Earth, Mars accreted almost homogeneously. The striking depletion of all elements with chalcophile character indicates that chemical equilibrium between component A and B was achieved on Mars which lead to the formation of significant amounts of FeS which, on segregation, extracted the elements according to their sulphide-silicate partition coefficients. While for the Earth a mixing ratio AB = 8515 was derived, the Mars ratio of 6040 reflects the higher concentrations of moderately volatile elements like Na, K, and sulphur on Mars. A homogeneous accretion of Mars could also explain the obvious low abundances of water and primordial rare gases.     

Light elements and their isotopes in SNC meteorites and the Martian atmosphere

Nitrogen isotopes have played an important part in the acceptance of the hypothesis that SNC meteorites derive from Mars. As a result, these meteorites can be investigated for their carbon, sulphur, and hydrogen systematics with a view to learning something about the environmental conditions on the planet. Important aspects of the role of carbon, present in the form of carbon dioxide as an atmospheric gas and leading to the formation of carbonates by weathering or hydrothermal activity, can be established. The presence of indigenous organics is an intriguing possibility. A variety of new or emerging techniques which could improve our understanding of SNC meteorites and might be applied to a returned Martian sample are discussed.     

Chronology of SNC meteorites

In this paper a model is presented for the geochemical evolution of Mars which is constrained by the isotope systematics of Pb, Nd, and Sr determined for SNC meteorites (SNCs). The young magmatic crystallization ages (internal or mineral ages) of SNCs may indicate that these meteorites indeed stem from Mars. Internal ages and U-Pb and Pb-Pb systematics strongly suggest that they are the result of two magmatic processes. In addition, shock metamorphism is implied from observed petrographic shock features. For ALHA 77009 a shock-age < 15 Ma is obtained which is within uncertainty identical to the independently determined cosmic ray exposure age. It is therefore plausible that shock and exposure ages are identical for all SNCs. The Rb/Sr data of all common (non-SNC) meteorites form a 4.55 Ga isochron as do the Pb-Pb data (geochron). The SNC data fall close to these two isochrons. The Sr and Pb isotopic compositions in SNCs suggest that they formed in a recent (1.3-0.15 Ga) melting event from reservoirs which had been magmatically differentiated 4.3 ± 0.2 Ga ago. In a concordia diagram (U-Pb evolution plot) the SNC data reflect recent increase of the U/Pb ratio and the same two stage magmatic history as suggested by the other isotopic systems. The oxygen isotopic composition as well as the Nd isotopic systematics strongly suggest that the SNCs stem from one common reservoir which chemically differentiated 4.3 ± 0.2 Ga ago and then formed sub-reservoirs. In contrast to common meteorites, SNCs experienced an early magmatic differentiation where the Sm/Nd, U/Pb and Rb/Sr ratios have been strongly fractionated. In the recent magmatic process (1.3-0.15 Ga ago), in which the SNCs were formed as rocks, Sm/Nd and U/Pb were fractionated, while Rb/Sr remained similar to that of the source from which the magmas originated. During these melting events, mixing of components from different sub-reservoirs might have had occurred. At least three subreservoirs are necessary to explain the isotopic variations observed in SNCs. In contrast to the isotopic evolution of the Earth, Mars conserved remnants of the primary differentiation, a fact, which places important constraints on the tectonic evolution of Mars.     

Stratigraphy and Isotope Ages of Lunar Geologic Units: Chronological Standard for the Inner Solar System

The absolute ages of cratered surfaces in the inner solar system, including Mars, are derived by extrapolation from the impact flux curve for the Moon which has been calibrated on the basis of absolute ages of lunar samples. We reevaluate the lunar flux curve using isotope ages of lunar samples and the latest views on the lunar stratigraphy and the principles of relative and absolute age dating of geologic surface units of the Moon. The geological setting of the Apollo and Luna landing areas are described as far as they are relevant for this reevaluation. We derive the following best estimates for the ages of the multi-ring basins and their related ejecta blankets and present alternative ages for the basin events (in parentheses): 3.92 ± 0.03 Gyr (or 3.85 ± 0.05 Gyr) for Nectaris, 3.89 ± 0.02 Gyr (or 3.84 ± 0.04 Gyr) for Crisium, 3.89 ± 0.01 Gyr (or 3.87 ± 0.03 Gyr) for Serenitatis, and 3.85 ± 0.02 Gyr (or 3.77 ± 0.02 Gyr) for Imbrium. Our best estimates for the ages of the mare landing areas are: 3.80 ± 0.02 Gyr for Apollo 11 (old surface), 3.75 ± 0.01 Gyr for Apollo 17, 3.58 ± 0.01 Gyr for Apollo 11 (young surface), 3.41 ± 0.04 Gyr for Luna 16, 3.30 ± 0.02 Gyr for Apollo 15, 3.22 ± 0.02 Gyr for Luna 24, and 3.15 ± 0.04 Gyr for Apollo 12. The ages of Eratosthenian and Copernican craters remain: ～ 2.1 (?) Gyr (Autolycus), 800 ± 15 Myr (Copernicus), 109 ± 4 Myr (Tycho), 50.3 ± 0.8 (North Ray crater, Apollo 16), and 25.1 ± 1.2 (Cone crater, Apollo 14). When plotted against the crater densities of the relevant lunar surface units, these data result in a revised lunar impact flux curve which differs from the previously used flux curve in the following respects: (1) The ages of the stratigraphically most critical impact basins are notably younger, (2) the uncertainty of the calibration curve is decreased, especially in the age range from about 4.0 to 3.0 Gyr, (3) any curve for ages older than 3.95 Gyr (upper age limit of the Nectaris ejecta blanket) is abandoned because crater frequencies measured on such surface formations cannot be correlated with absolute ages obtained on lunar samples. Therefore, the impact flux curve for this pre-Nectarian time remains unknown. The new calibration curve for lunar crater retention ages less than about 3.9 Gyr provides an updated standard reference for the inner solar system bodies including Mars.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Hydrogen Exospheric Density Profile Measured with ASPERA-3/NPD

We have evaluated the Lyman-α limb emission from the exospheric hydrogen of Mars measured by the neutral particle detector of the ASPERA-3 instrument on Mars Express in 2004 at low solar activity (solar activity index = 42, F_10.7=100). We derive estimates for the hydrogen exobase density, n _H = 10¹⁰ m^?3, and for the apparent temperature, T > 600 K. We conclude that the limb emission measurement is dominated by a hydrogen component that is considerably hotter than the bulk temperature at the exobase. The derived values for the exosphere density and temperature are compared with similar measurements done by the Mariner space probes in the 1969. The values found with Mars Express and Mariner data are brought in a broader context of exosphere models including the possibility of having two hydrogen components in the Martian exosphere. The present observation of the Martian hydrogen exosphere is the first one at high altitudes during low solar activity, and shows that for low solar activity exospheric densities are not higher than for high solar activity.     

Radiation climate map for analyzing risks to astronauts on the mars surface from galactic cosmic rays

The potential risks for late effects including cancer, cataracts, and neurological disorders due to exposures to the galactic cosmic rays (GCR) is a large concern for the human exploration of Mars. Physical models are needed to project the radiation exposures to be received by astronauts in transit to Mars and on the Mars surface, including the understanding of the modification of the GCR by the Martian atmosphere and identifying shielding optimization approaches. The Mars Global Surveyor (MGS) mission has been collecting Martian surface topographical data with the Mars Orbiter Laser Altimeter (MOLA). Here we present calculations of radiation climate maps of the surface of Mars using the MOLA data, the radiation transport model HZETRN (high charge and high energy transport), and the quantum multiple scattering fragmentation model, QMSFRG. Organ doses and the average number of particle hits per cell nucleus from GCR components (protons, heavy ions, and neutrons) are evaluated as a function of the altitude on the Martian surface. Approaches to improve the accuracy of the radiation climate map, presented here using data from the 2001 Mars Odyssey mission, are discussed.     

Energisation of O+ and O+ 2 Ions at Mars: An Analysis of a 3-D Quasi-Neutral Hybrid Model Simulation

We have studied the loss of O⁺ and O⁺ ₂ ions at Mars with a numerical model. In our quasi-neutral hybrid model ions (H⁺, He⁺⁺, O⁺, O⁺ ₂) are treated as particles while electrons form a massless charge-neutralising fluid. The employed model version does not include the Martian magnetic field resulting from the crustal magnetic anomalies. In this study we focus the Martian nightside where the ASPERA instrument on the Phobos-2 spacecraft and recently the ASPERA-3 instruments on the Mars Express spacecraft have measured the proprieties of escaping atomic and molecular ions, in particular O⁺ and O⁺ ₂ ions. We study the ion velocity distribution and how the escaping planetary ions are distributed in the tail. We also create similar types of energy-spectrograms from the simulation as were obtained from ASPERA-3 ion measurements. We found that the properties of the simulated escaping planetary ions have many qualitative and quantitative similarities with the observations made by ASPERA instruments. The general agreement with the observations suggest that acceleration of the planetary ions by the convective electric field associated with the flowing plasma is the key acceleration mechanism for the escaping ions observed at Mars.