The Cool Interstellar Medium

Infrared spectroscopy and photometry with ISO covering most of the emission range of the interstellar medium has led to important progress in the understanding of the physics and chemistry of the gas, the nature and evolution of the dust grains and also the coupling between the gas and the grains. We review here the ISO results on the cool and low-excitation regions of the interstellar medium, where T _gas≲ 500 K, n _H∼ 100–10⁵ cm⁻³ and the electron density is a few 10⁻⁴. JEL codes: D24, L60, 047 Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

The Planets and Titan Observed by ISO

Infrared spectroscopic observations of planets and Saturn's satellite Titan with the Infrared Space Observatory led to many significant discoveries that improved our understanding on the formation, physics and chemistry of these objects. The prime results achieved by ISO are: (1) a new and consistent determination of the D/H ratios on the giant planets and Titan; (2) the first precise measurement of the ¹⁵N/¹⁴N ratio in Jupiter, a valuable indicator of the protosolar nitrogen isotopic ratio; (3) the first detection of an external oxygen flux for all giant planets and Titan; (4) the first detection of some stratospheric hydrocarbons (CH₃, C₂H₄, CH₃C₂H, C₄H₂, C₆H₆); (5) the first detection of tropospheric water in Saturn; (6) the tentative detection of carbonate minerals on Mars; (7) the first thermal lightcurve of Pluto. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Molecular Hydrogen

Observations of H₂ line emission in galactic and extragalactic environments obtained with the Infrared Space Observatory (ISO) are reviewed. The diagnostic capability of H₂ observations is illustrated. We discuss what one has learned about such diverse astrophysical sources as photon-dominated regions, shocks, young stellar objects, planetary nebulae and starburst galaxies from ISO observations of H₂ emission. In this context, we emphasise use of measured H₂ line intensities to infer important physical quantities such as the gas temperature, gas density and radiation field and we discuss the different possible excitation mechanisms of H₂. We also briefly consider future prospects for observation of H₂ from space and from the ground. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Spectroscopy Between the Stars

The emission and absorption spectra of interstellar molecules are reviewed with special consideration of recent observational and technical advances in the shorter submillimeter wave region of the electromagnetic spectrum. Single-dish observations have contributed in the past probably most of the information about the structure of interstellar molecular clouds. At present about 120 interstellar molecules have been identified in interstellar clouds and circumstellar envelopes, evidence of a rich and diversified chemistry. CO, the most abundant interstellar molecule and other diatomic molecules and radicals are found throughout molecular clouds, whereas the more complex molecules are found in high-density cores, which are often the sites of active star formation. These locations represent prime targets for the search for larger molecules, such as glycine. The ignition of young stars is accompanied by strong heating of the surrounding material by radiation and/or shocks, leading to photoevaporation of molecules depleted on dust grains driving a "hot core" chemistry, traceable by its rich organic chemistry and its prevailing high excitation conditions (up to about 2000 cm^-1). However, in the list of detected interstellar molecules many simple hydrides are still missing, e.g. SH, PH, PH₂, etc., which constitute the building blocks for larger molecules. With the technological opening of the terahertz region (ν ∼1 THz corresponds to λ ∼0.3 mm) to both laboratory and interstellar spectroscopy, great scientific advances are to be expected. Amongst these will be the direct detection of the lowest rotational transitions of the light hydrides, the low energy bending vibrations of larger (linear) molecules, and possibly the ring-puckering motion of larger ring molecules such as the polycyclic (multiring) aromatic hydrocarbons. This revised version was published online in June 2006 with corrections to the Cover Date.     

High Excitation ISM and Gas

An overview is given of ISO results on regions of high excitation ISM and gas, i.e. HII regions, the Galactic Centre and Supernova Remnants. IR emission due to fine-structure lines, molecular hydrogen, silicates, polycyclic aromatic hydrocarbons and dust are summarised, their diagnostic capabilities illustrated and their implications highlighted. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

The Coma of Comet 9P/Tempel 1

As comet 9P/Tempel 1 approaches the Sun in 2004–2005, a temporary atmosphere, or “coma,” will form, composed of molecules and dust expelled from the nucleus as its component icy volatiles sublimate. Driven mainly by water ice sublimation at surface temperatures T > 200 K, this coma is a gravitationally unbound atmosphere in free adiabatic expansion. Near the nucleus (≤ 10² km), it is in collisional equilibrium, at larger distances (≥10⁴ km) it is in free molecular flow. Ultimately the coma components are swept into the comet’s plasma and dust tails or simply dissipate into interplanetary space. Clues to the nature of the cometary nucleus are contained in the chemistry and physics of the coma, as well as with its variability with time, orbital position, and heliocentric distance. The DI instrument payload includes CCD cameras with broadband filters covering the optical spectrum, allowing for sensitive measurement of dust in the comet’s coma, and a number of narrowband filters for studying the spatial distribution of several gas species. DI also carries the first near-infrared spectrometer to a comet flyby since the VEGA mission to Halley in 1986. This spectrograph will allow detection of gas emission lines from the coma in unprecedented detail. Here we discuss the current state of understanding of the 9P/Tempel 1 coma, our expectations for the measurements DI will obtain, and the predicted hazards that the coma presents for the spacecraft. An erratum to this article is available at .     

Late Stages of Stellar Evolution

A large fraction of ISO observing time was used to study the late stages of stellar evolution. Many molecular and solid state features, including crystalline silicates and the rotational lines of water vapour, were detected for the first time in the spectra of (post-)Asymptotic Giant Branch (AGB) stars. Their analysis has greatly improved our knowledge of stellar atmospheres and circumstellar environments. A surprising number of objects, particularly young planetary nebulae with Wolf-Rayet (WR) central stars, were found to exhibit emission features in their ISO spectra that are characteristic of both oxygen-rich and carbon-rich dust species, while far-IR observations of the PDR around NGC 7027 led to the first detections of the rotational line spectra of CH and CH⁺. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Short-Lived Radionuclides in Meteorites: Constraints on Nebular Timescales for the Production of Solids

Variations in the abundances of short-lived radionuclides such as ²⁶Al (τ_1/2 ≈ 0.74 Ma) and ⁵³Mn (τ_1/2 ≈ 3.7 Ma) in meteoritic solids may be used to infer relative formation intervals of these solids in the nebula at precisions of less than 1 Ma. In a strict chronometric interpretation of the isotopic variations, whereby criteria such as spatial and temporal isotopic homogeneity and closed system isotopic evolution are met, solid formation occurred in the nebula for at least several million years. This is longer than some theoretical and astronomical estimates for the duration of the active nebula. The evidence for live ⁴¹Ca (τ_1/2 ≈ 0.10 Ma) in meteoritic inclusions further indicates that the onset of solid formation occurred quite early, perhaps within a few hundred thousand years after the onset of the collapse of the sun's parent molecular cloud. Failure of the chronometric interpretation may arise for a variety of reasons, including but not limited to, the late, inhomogeneous injection of material from a nearby stellar source or the local production of short-lived radionuclides by an energetic particle irradiation, e. g., from T Tauri (X-wind) or galactic cosmic ray sources. Although some isotopic evidence exists that the criteria required for a strict chronometric interpretation are not met by each of the short-lived chronometers, there is no compelling reason to shorten the interval of solid formation in the nebula to less than 1 Ma. This revised version was published online in June 2006 with corrections to the Cover Date.     

An ISO View on Interstellar and Cometary Ice Chemistry

The ISO-SWS instrument offering a large wavelength coverage and a resolution well adapted to the solid phase has changed our knowledge of the physical-chemical properties of ices in space. The discovery of many new ice features was reported and the comparison with dedicated laboratory experiments allowed the determination of more accurate abundances of major ice components. The presence of CO₂ ice has recently been confirmed with the SWS (Short Wavelength Spectrometer) as a dominant ice component of interstellar grain mantles. The bending mode of CO₂ ice shows a particular triple-peak structure which provides first evidence for extensive ice segregation in the line-of-sight toward massive protostars. A comparison of interstellar and cometary ices using recent ISO data and ground-based measurements has revealed important similarities but also indicated that comets contain, beside pristine interstellar material, admixtures of processed material. The investigation of molecules in interstellar clouds is essential to reveal the link between dust in the interstellar medium and in the Solar System. This revised version was published online in June 2006 with corrections to the Cover Date.     

COS-B views on the diffuse galactic gamma-ray emission and some point sources

The correlation between diffuse galactic gamma rays and gas tracers is studied using the final COS-B database and H i and CO surveys covering the entire galactic plane. A good quantitative fit to the gamma rays is obtained, with a small galacto-centric gradient in the gamma-ray emissivity per hydrogen atom. The average ratio of H₂ column density to integrated CO temperature is determined, the best estimate being (2.3 ± 0.3) × 10² molecules cm^–2 (K km s^–1)^–1. Strictly taken, this value is an upper limit. The corresponding mass of molecular hydrogen in the inner galaxy, derived using both 1st and 4th quadrants, is 1.0 × 10⁹ M .The softer gamma-ray spectrum towards the inner galaxy found in previous work can be attributed to a steeper emissivity gradient at low energies and/or to a softer gamma-ray spectrum of the emission distributed like molecular gas. A steeper emissivity gradient at low energies could be related to cosmic-ray spectral variations in the Galaxy, to different distributions of cosmic-ray electrons and nuclei, or to a contribution from discrete sources. A softer spectrum for the emission associated with molecular clouds may be physically related to the clouds themselves (i.e., cosmic-ray spectral variations) or to an associated discrete source distribution.New results on the temporal and spectral characteristics of the high-energy (50 MeV to 5 GeV) gammaray emission from the Vela pulsar are presented. The whole pulsed flux is found to exhibit long-term variability. Five discrete emission regions within the pulsar lightcurve have been identified, with the spectral characteristics and long-term behaviour being different. These characteristics differ significantly from those reported earlier for the Crab pulsar. However, geometrical pulsar models have been proposed (e.g., Morini, 1983; Smith, 1986) which could explain many of these features.     

Recent progress in astrochemistry

Models of the four currently recognized regimes of astrochemistry are compared with observations. Ion-Molecule Gas Phase Chemistry is fundamental throughout all interstellar and circumstellar molecular clouds, and by itself explains fairly well the simpler molecular species in diffuse and cold quiescent dense interstellar clouds, as well as in the outer envelopes of circumstellar clouds. Dust-Grain Chemistry may modify ion-molecule chemistry noticeably in regions containing UV radiation, shocks, or other heating agents which can serve to promote surface reactions and to desorb molecules frozen on grains; it likely plays no role in cold quiescent clouds except to adsorb gas phase molecules. Shock Chemistry occurs in regions of star formation and appears important in explaining certain molecular species and in disrupting grains. Circumstellar envelopes combine several chemistries, including those of thermochemical equilibrium in the dense inner regions, and ion-molecule in the outer regions, with grain processes also likely. The limitations of all current models are lack of knowledge of reaction rates, of detailed physical conditions (interstellar clouds), and of the relative depletions (onto grains) of the chemical elements, as well as grain surface chemistry in general. In both interstellar and circumstellar objects, ion-molecule gas phase models are now quite successful in explaining, semi-quantitatively, observed species with up to 4 atoms, but difficulties remain for larger species, as well as the state of carbon, and the models are not yet very predictive.NRAO is operated by Associated Universities Inc. under contract with NSF.     

The Solar System d/h Ratio: Observations and Theories

The measured D/H ratios in interstellar environments and in the solar system are reviewed. The two extreme D/H ratios in solar system water - (720±120)×10⁻⁶ in clay minerals and (88±11)×10⁻⁶ in chondrules, both from LL3 chondritic meteorites - are interpreted as the result of a progressive isotopic exchange in the solar nebula between deuterium-rich interstellar water and protosolar H₂. According to a turbulent model describing the evolution of the nebula (Drouart et al., 1999), water in the solar system cannot be a product of thermal (neutral) reactions occurring in the solar nebula. Taking 720×10⁻⁶ as a face value for the isotopic composition of the interstellar water that predates the formation of the solar nebula, numerical simulations show that the water D/H ratio decreases via an isotopic exchange with H₂. During the course of this process, a D/H gradient was established in the nebula. This gradient was smoothed with time and the isotopic homogenization of the solar nebula was completed in 10⁶ years, reaching a D/H ratio of 88×10⁻⁶. In this model, cometary water should have also suffered a partial isotopic re-equilibration with H₂. The isotopic heterogeneity observed in chondrites result from the turbulent mixing of grains, condensed at different epochs and locations in the solar nebula. Recent isotopic determinations of water ice in cold interstellar clouds are in agreement with these chondritic data and their interpretation (Texeira et al., 1999). This revised version was published online in June 2006 with corrections to the Cover Date.     

Normal Nearby Galaxies

Following on from IRAS, ISO has provided a huge advancement in our knowledge of the phenomenology of the infrared (IR) emission of normal galaxies and the underlying physical processes. Highlights include the discovery of an extended cold dust emission component, present in all types of gas-rich galaxies and carrying the bulk of the dust luminosity; the definitive characterisation of the spectral energy distribution in the IR, revealing the channels through which stars power the IR light; the derivation of realistic geometries for stars and dust from ISO imaging; the discovery of cold dust associated with H I extending beyond the optical body of galaxies; the remarkable similarity of the near-IR (NIR)/mid-IR (MIR) SEDs for spiral galaxies, revealing the importance of the photo-dissociation regions in the energy budget for that wavelength range; the importance of the emission from the central regions in shaping up the intensity and the colour of the global MIR luminosity; the discovery of the “hot” NIR continuum emission component of interstellar dust; the predominance of the diffuse cold neutral medium as the origin for the main interstellar cooling line, [C II] 158 μm, in normal galaxies. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Influence of Solar Wind on the Global Electric Circuit,and Inferred Effects on Cloud Microphysics,Temperature, and Dynamics in the Troposphere

There are at least three independent ways in which the solar wind modulates the flow of current density (Jz) in the global electric circuit. These are (A) changes in the galactic cosmic ray energy spectrum, (B) changes in the precipitation of relativistic electrons from the magnetosphere, and (C) changes in the ionospheric potential distribution in the polar caps due to magnetosphere-ionosphere coupling. The current density J _z flows between the ionosphere and the surface, and as it passes through conductivity gradients it generates space charge concentrations dependent on J _z and the conductivity gradient. The gradients are large at the surfaces of clouds and space charge concentrations of order 1000 to 10,000 elementary charges per cm³ can be generated at cloud tops. The charge transfers to droplets, many of which are evaporating at the cloud-clear air interface. The charge remains on the residual evaporation nuclei with a lifetime against leakage of order 1000 sec, and for a longer period the nuclei also retain coatings of sulfate and organic compounds adsorbed by the droplet while in the cloud.The charged evaporation nuclei become well mixed with more droplets in many types of clouds with penetrative mixing. The processes of entrainment and evaporation are also efficient for these clouds. The collection of such nuclei by nearby droplets is greatly increased by the electrical attraction between the charge on the particle and the image charge that it creates on the droplet. This process is called electroscavenging. Because the charge on the evaporation nuclei is derived from the original space charge, it depends on J _z, giving a rate of electroscavenging responsive to the solar wind inputs.There may be a number of ways in which the electroscavenging has consequences for weather and climate. One possibility is enhanced production of ice. The charged evaporation nuclei have been found to be good ice forming nuclei because of their coatings, and so in supercooled clouds droplet freezing can occur by contact ice nucleation, as the evaporation nuclei are electroscavenged. Although quantitative models for the all the cloud microphysical processes that may be involved have not yet been produced, we show that for many clouds, especially those with broad droplet size distributions, relatively high droplet concentrations, and cloud top temperatures just below freezing, this process is likely to dominate over other primary ice nucleation processes. In these cases there are likely to be effects on cloud albedo and rates of sedimentation of ice, and these will depend on J _z.For an increase in ice production in thin clouds such as altocumulus or stratocumulus the main effect is a decrease in albedo to incoming solar radiation, and in opacity to outgoing longwave radiation. At low latitudes the surface and troposphere heat, and at high latitudes in winter they cool. The change in meridional temperature gradient affects the rate of cyclogenesis, and the amplitude of planetary waves. For storm clouds, as in winter cyclones, the effect of increased ice formation is mainly to increase the rate of glaciation of lower level clouds by the seeder-feeder process. The increase in precipitation efficiency increases the rate of transfer of latent heat between the air mass and the surface. In most cyclones this is likely to result in intensification, producing changes in the vorticity area index as observed. Cyclone intensification also increases the amplitude of planetary waves, and shifts storm tracks, as observed.In this paper we first describe the production of space charge and the way in which it may influence the rate of ice nucleation. Then we review theory and observations of the solar wind modulation of J _z, and the correlated changes in atmospheric temperature and dynamics in the troposphere. The correlations are present for each input, (A, B, and C), and the detailed patterns of responses provide support for the inferred electrical effects on the physics of clouds, affecting precipitation, temperature and dynamics.     

Water in Space: The Water World of ISO

In this review we present the main results obtained by the ISO satellite on the abundance and spatial distribution of water vapor in the direction of molecular clouds, evolved stars, galaxies, and in the bodies of our Solar System. We also discuss the modeling of H₂O and the difficulties found in the interpretation of the data, the need of collisional rates and the perspectives that future high angular and high spectral resolution observations of H₂O with the Herschel Space Observatory will open.     

Evolution of the Protosolar Nebula and Formation of the Giant Planets

The formation of planetary systems is intimately tied to the question of the evolution of the gas and solid material in the early nebula. Current models of evolution of circumstellar disks are reviewed here with emphasis on the so-called “alpha models” in which angular momentum is transported outward by turbulent viscosity, parameterized by an dimensionless parameter α. A simple 1D model of protoplanetary disks that includes gas and embedded particles is used to introduce key questions on planetesimal formation. This model includes the aerodynamic properties of solid ice and rock grains to calculate their migration and growth. We show that the evolution of the nebula and migration and growth of its solids proceed on timescales that are generally not much longer than the timescale necessary to fully form the star-disk system from the molecular cloud. Contrary to a widely used approach, planet formation therefore can neither be studied in a static nebula nor in a nebula evolving from an arbitrary initial condition. We propose a simple approach to both account for sedimentation from the molecular cloud onto the disk, disk evolution and migration of solids. Giant planets have key roles in the history of the forming Solar System: they formed relatively early, when a significant amount of hydrogen and helium were still present in the nebula, and have a mass that is a sizable fraction of the disk mass at any given time. Their composition is also of interest because when compared to the solar composition, their enrichment in elements other than hydrogen and helium is a witness of sorting processes that occured in the protosolar nebula. We review likely scenarios capable of explaining both the presence of central dense cores in Jupiter, Saturn, Uranus and Neptune and their global composition. This revised version was published online in August 2006 with corrections to the Cover Date.     

Evaluation of the influence of a measurable parameter error on precision of determining αΣ and Tg* by regression models

We present the regression models for determining the total excess air ratio α_Σ and gas temperature T _g ^* upstream of the high-pressure turbine formed on the basis of the engine parameter values that are regularly measured. The sensitivity of the regression models presented to the sensor and instrumentation precision is studied. The errors of measuring and calculating α_Σ and T _g ^* in different altitude-speed engine operation conditions are shown.     

ISO's Contribution to the Study of Clusters of Galaxies

Starting with nearby galaxy clusters like Virgo and Coma, and continuing out to the furthest galaxy clusters for which ISO results have yet been published (z = 0.56), we discuss the development of knowledge of the infrared and associated physical properties of galaxy clusters from early IRAS observations, through the “ISO-era” to the present, in order to explore the status of ISO's contribution to this field. Relevant IRAS and ISO programmes are reviewed, addressing both the cluster galaxies and the still-very-limited evidence for an infrared-emitting intra-cluster medium. ISO made important advances in knowledge of both nearby and distant galaxy clusters, such as the discovery of a major cold dust component in Virgo and Coma cluster galaxies, the elaboration of the correlation between dust emission and Hubble-type, and the detection of numerous Luminous Infrared Galaxies (LIRGs) in several distant clusters. These and consequent achievements are underlined and described. We recall that, due to observing time constraints, ISO's coverage of higher-redshift galaxy clusters to the depths required to detect and study statistically significant samples of cluster galaxies over a range of morphological types could not be comprehensive and systematic, and such systematic coverage of distant clusters will be an important achievement of the Spitzer Observatory. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, the Netherlands, and the United Kingdom) and with the participation of ISAS and NASA.     

Radiolysis and Photolysis of Icy Satellite Surfaces: Experiments and Theory

The transport and exchange of material between bodies in the outer solar system is often facilitated by their exposure to ionizing radiation. With this in mind we review the effects of energetic ions, electrons and UV photons on materials present in the outer solar system. We consider radiolysis, photolysis, and sputtering of low temperature solids. Radiolysis and photolysis are the chemistry that follows the bond breaking and ionization produced by incident radiation, producing, e.g., O₂ and H₂ from irradiated H₂O ice. Sputtering is the ejection of molecules by incident radiation. Both processes are particularly effective on ices in the outer solar system. Materials reviewed include H₂O ice, sulfur-containing compounds (such as SO₂ and S₈), carbon-containing compounds (such as CH₄), nitrogen-containing compounds (such as NH₃ and N₂), and mixtures of those compounds. We also review the effects of ionizing radiation on a mixture of N₂ and CH₄ gases, as appropriate to Titan’s upper atmosphere, where radiolysis and photolysis produce complex organic compounds (tholins).     

Emergence of a Habitable Planet

We address the first several hundred million years of Earth’s history. The Moon-forming impact left Earth enveloped in a hot silicate atmosphere that cooled and condensed over ∼1,000 yrs. As it cooled the Earth degassed its volatiles into the atmosphere. It took another ∼2 Myrs for the magma ocean to freeze at the surface. The cooling rate was determined by atmospheric thermal blanketing. Tidal heating by the new Moon was a major energy source to the magma ocean. After the mantle solidified geothermal heat became climatologically insignificant, which allowed the steam atmosphere to condense, and left behind a ∼100 bar, ∼500 K CO₂ atmosphere. Thereafter cooling was governed by how quickly CO₂ was removed from the atmosphere. If subduction were efficient this could have taken as little as 10 million years. In this case the faint young Sun suggests that a lifeless Earth should have been cold and its oceans white with ice. But if carbonate subduction were inefficient the CO₂ would have mostly stayed in the atmosphere, which would have kept the surface near ∼500 K for many tens of millions of years. Hydrous minerals are harder to subduct than carbonates and there is a good chance that the Hadean mantle was dry. Hadean heat flow was locally high enough to ensure that any ice cover would have been thin (<5 m) in places. Moreover hundreds or thousands of asteroid impacts would have been big enough to melt the ice triggering brief impact summers. We suggest that plate tectonics as it works now was inadequate to handle typical Hadean heat flows of 0.2–0.5 W/m². In its place we hypothesize a convecting mantle capped by a ∼100 km deep basaltic mush that was relatively permeable to heat flow. Recycling and distillation of hydrous basalts produced granitic rocks very early, which is consistent with preserved >4 Ga detrital zircons. If carbonates in oceanic crust subducted as quickly as they formed, Earth could have been habitable as early as 10–20 Myrs after the Moon-forming impact.