Isotopic ratios in planetary atmospheres.

Recent progress on measurements of isotopic ratios in planetary or satellite atmospheres include measurements of the D/H ratio in the methane of Uranus, Neptune and Titan and in the water of Mars and Venus. Implications of these measurements on our understanding of the formation and evolution of the planets and satellite are discussed. Our current knowledge of the carbon, nitrogen and oxygen isotopic ratios in the atmospheres of these planets, as well as on Jupiter and Saturn, is also reviewed. We finally show what progress can be expected in the very near future due to some new ground-based instrumentation particularly well suited to such studies, and to forthcoming space missions.     

Photochemical growing of complex organics in planetary atmospheres

UV induced syntheses of organic compounds from the main atmospheric constituents can be a very important source of organics in a given planetary environment provided the atmosphere is in a reduced state. The evolution of a CO₂ rich medium only produces very low yields of formaldehyde and related oxygenated compounds. Considering a CO rich atmosphere, the photochemical yield of O-organics formation is much higher, when the synthesis of N-organics remains difficult. The most favourable atmosphere as far as photochemical organic synthesis is concerned is a CH₄ rich milieu.. The photochemical evolution of such a CH₄ atmosphere under UV irradiation leads to a chain of various organics, the complexity of which increases together with the number of pathways involved in their formation. Their complexity also closely correlates with their UV photoabsorption spectrum: the more complex they are, the more shifted is their UV spectrum toward the visible range. Direct photodissociation of methane requires UV photon of wavelengths shorter than about 145 nm. It mainly produces ethane which absorbs UV at wavelengths shorter than about 160 nm, and acetylene, that presents an absorption spectrum extending up to 200 nm. This shift still continuously increases with further increase in number of C atoms. Unsaturated hydrocarbons with 4 and more C atoms have UV absorption characteristics including noticeable band structures in the 250–300 nm range. This trend has very important implication in the photochemical behaviour of a CH₄-rich planetary atmosphere, as it induces many catalytic processes. The occurrence of such processes is closely related to vertical atmospheric and energy deposition profiles. Titan provides a very good example of such a UV-directed organic atmospheric chemistry.     

Modification of planetary atmospheres by material from the rings

The atmospheres and ionospheres of ringed planets can be, and perhaps are, modified by the injection of gaseous neutral and ionized species, and dust of ring origin. Although no direct evidence for such interaction exists, many of the unresolved characteristics of planetary composition, thermal structure and ionosphere would be understood if the rings supplied certain materials to their parent planets.     

Formation of bioorganic compounds in planetary atmospheres by cosmic radiation.

Simulated planetary atmospheres (mixtures of simple gases) were irradiated with high energy particles to simulate an action of cosmic rays. When a mixture of carbon monoxide, nitrogen and water was irradiated with 2.8-40 MeV protons, a wide variety of bioorganic compounds including amino acids, imidazole, and uracil were identified in the products. The amount of amino acids was proportional to the energy deposit to the system. Various kinds of simulated planetary atmospheres, such as "Titan type" and "Jovian type", were also irradiated with high energy protons, and gave amino acids in the hydrolyzed products. Since cosmic rays are a universal energy source in space, it was suggested that formation of bioorganic compounds in planetary atmospheres is inevitable in the course of cosmic evolution.     

Organic syntheses in gas phase and chemical evolution in planetary atmospheres

Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH₄, CO or CO₂), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres.     

Mass loading of planetary atmospheres by rocky satellites—II: Transport and enhanced lifetimes of satellite ejecta in planetary magnetospheres

Extensive studies have been conducted concerning individual mass, temporal and positional distribution of submicron rocky ejecta existing in the satellite-planetary gravitational sphere of influence. The transit time of the major portion of the ejecta that is transported from the satellite's gravitational sphere of influence to the planetary magnetopause is about one week and represents a mass loading pulse occurring each satellite orbit. The mass-flux distributions of lunar ejecta at the surface of the magnetopause for a complete lunar orbit are presented. Spatial mass densities of lunar ejecta in specific zones of the magnetosphere provide a means to compare sporadic interplanetary dust spatial mass densities in the same zones.     

Numerical simulation of organic compounds formation in planetary atmospheres: comparison with laboratory experiments.

A numerical model of CH4 and CH4-NH3 photochemistry at 147 nm has been developed and results are directly compared with experimental simulations carried out for the same mixtures. Simulations with varying quantities of ammonia and hydrogen show how amines and nitriles can be produce in planetary atmospheres. These comparisons allow one to test schemes of reactions used in photochemical models. In particular, it is shown that the scheme of reactions of CH4 is fairly well consistent with experimental data. On the other hand, the photochemistry of NH3 should be improved.     

The escape of molecular hydrogen and the synthesis of organic nitriles in planetary atmospheres.

What is the influence of hydrogen escape from the atmosphere of small planetary bodies on the synthesis of organic molecules in that atmosphere? To answer this question, laboratory experiments have been performed to study the evolution of different reducing model atmospheres submitted to electrical discharges, with and without the simulation of H₂ escape. A study of mixtures of nitrogen and methane shows a very strong effect of H₂ escape on the formation of organic nitriles, the only nitrogen containing organics detected in the gas phase. These are HCN, CH  CCN, (CN)₂, CH₂CHCN, CH₃ CN and CH₃CH₂CN. The yield of synthesis of most of these compounds is noticeably increased, up to several orders of magnitude, when hydrogen escape is simulated. The escape of H₂ from the atmosphere of the primitive Earth may have played a crucial role in the formation of reactive organic molecules such as CHCCN or (CN)₂, which can be considered as important prebiotic precursors. These experimental results may also explain extant data concerning the nature and relative abundance of organics present in the atmosphere of Titan, a planetary satellite which may be an ideal model within our solar system for the study of organic cosmochemistry and exobiology.     

Conjecture on superrotation in planetary atmospheres: A diffusion model with mixing length theory

Superrotation on Venus is discussed in the context of comparative planetary atmospheres. In our planetary system, the rigid shell component (global average) of superrotation is ubiquitous (Jupiter, Saturn, Earth, Venus, Mars, Titan). The largest equatorial values of the component are between 25 and 150 m/sec. We present a simplified, heuristic analysis, utilizing mixing length theory to describe the small scale non-linear advections of energy and angular momentum, thereby providing a closure of the dynamic system. This leads to the conjecture that the zonal velocity may be crudely estimated by

, approximating the observed planetary trends; with c the speed of sound, the parameter a being 1 or 2 for geostrophic or cyclostrophic conditions respectively, P_α an effective Prandtl number which becomes less than one when radiative cooling is important, S_o the average stability, Γ the adiabatic lapse rate and γ the ratio of specific heats.     

Formation of bioorganic compounds in simulated planetary atmospheres by high energy particles or photons.

Various types of organic compounds have been detected in Jupiter, Titan, and cometary coma. It is probable that organic compounds were formed in primitive Earth and Mars atmospheres. Cosmic rays and solar UV are believed to be two major energy sources for organic formation in space. We examined energetics of organic formation in simulated planetary atmospheres. Gas mixtures including a C-source (carbon monoxide or methane) and a N-source (nitrogen or ammonia) was irradiated with the followings: High energy protons or electrons from accelerators, gamma-rays from 60Co, UV light from a deuterium lamp, and soft X-rays or UV light from an electron synchrotron. Amino acids were detected in the products of particles, gamma-rays and soft X-rays irradiation from each gas mixture examined. UV light gave, however, no amino acid precursors in the gas mixture of carbon monoxide, nitrogen and nitrogen. It gave only a trace of them in the gas mixture of carbon monoxide, ammonia and water or that of methane, nitrogen and water. Yield of amino acid precursors by photons greatly depended on their wavelength. These results suggest that nitrogen-containing organic compounds like amino acid precursors were formed chiefly with high energy particles, not UV photons, in Titan or primitive Earth/Mars atmospheres where ammonia is not available as a predominant N-source.     

Comparative analysis of chemical composition and optical properties of gaseous and disperse phases of the Earth-group planetary atmospheres

The models of chemical composition and structure of the Earth-type planetary atmospheres are offered. The optical properties of gaseous and disperse phases of the atmospheres are investigated.     

Characterization of complex organic compounds formed in simulated planetary atmospheres by the action of high energy particles.

A wide variety of organic compounds, which are not simple organics but also complex organics, have been found in planets and comets. We reported that complex organics was formed in simulated planetary atmospheres by the action of high energy particles. Here we characterized the experimental products by using chromatographic and mass spectrometric techniques. A gaseous mixture of CO, N2 and H2O was irradiated with high energy protons (major components of cosmic rays). Water-soluble non-volatile substances, which gave amino acids after acid-hydrolysis, were characterized by HPLC and mass spectrometry. Major part of the products were complex compounds with molecular weight of several hundreds. Amino acid precursors were produced even when no water was incorporated with the starting materials. It was suggested that complex molecules including amino acid precursors were formed not in solution from simple molecules like HCN, but directly in gaseous phase.     

Synchrotron radiation as a probe of the inner magnetosphere of Jupiter

A short review is given on the characteristics of Jupiter's inner magnetosphere derived from radio observations in the decimetric wavelength range. A comparison of the data with sophisticated model calculations yields information on the magnetic field configuration and the electron distribution, its density, energy spectrum, and pitch angle dependence as a function of spatial coordinates. The latter information can be used to derive e.g. the radial diffusion parameters plus the effects of the satellites, Jupiter's ring, and wave-particle interactions upon the electron distribution.     

Theory of planetary radio-emissions

In this short review, we limit our comments to the different theories which have been proposed to explain the observed features of the terrestrial, Jovian and Saturnian radio-emissions, and mainly to the high frequency portion of the spectra.     

Photopolarimetric sensing of planetary surfaces

Polarization measurements over the surfaces of the Moon, Mercury, Mars and Saturn's rings, and global data for the Galilean satellites, have been recorded with telescopes in France. A number of asteroids were measured by B. Zellner in USA. The curves of polarization are diagnostic of the micro-texture of the surface, and demonstrate that all the atmosphereless Solar System objects so far observed (except Callisto trailing hemisphere) have their surfaces covered with a regolith of fines, as for the Moon, which is produced by the cumulative effect of meteoroid impacts. For all the silicaceous objects down to a diameter of 700 km, namely Mars, Mercury, the Moon, Callisto (for the apex hemisphere), the mean grain sizes are no larger than 20um. The asteroids have coarser grained regoliths, apparently because of their smaller gravitational escape velocities. The C type asteroid surfaces, assumed to be carbon rich, appear finer grained than the silicaceous S types. The M astereroids assumed to be metallic, are also covered with small fragments, becuase metals loose their ductile properties at low temperature and behave at impact like brittle silicates. The trailing hemisphere of Callisto has a texture almost reminiscent of bare rocks. Orbital considerations to excluse significant impact effects, and a scenario for the past evolution of the satellite are implied.The planet Mars, with wind effects due to a tenuous atmosphere, several intense past volcanic episodes, a high tectonic activity and a permafrost underground has a more diversified surface regolith. A detailed analysis was achieved with photopolarimeters placed on board the soviet Mars Orbiter Spacecraft MARS-5.The Saturn's rings, anisotropic multiple scattering effects are observed and exhibit variations often in few days or weeks. Mutual interactions and gravitational forces are at work to produce organized structures, whereas disorganization forces occur and the competition produced ephemeral situations.     

Societal issues as Mars mission impediments: planetary protection and contamination concerns.

Societal and non-scientific factors represent potentially significant impediments for future Mars missions, especially in areas involving planetary protection. This paper analyzes public concerns about forward contamination to Mars and back contamination to Earth, evaluates major areas where lack of information may lead to uncontrollable impacts on future missions, and concludes that NASA should adopt a strategy that actively plans both the generation and subsequent management of planetary protection information to ensure that key audiences obtain needed information in a timely manner. Delay or avoidance in dealing with societal issues early in mission planning will increase the likelihood of public opposition, cost increases and missed launch windows. While this analysis of social and non-scientific considerations focuses on future Mars missions, the findings are also relevant for RTG launches, nuclear propulsion and other NASA activities perceived to have health, safety or environmental implications.     

Understanding the organization of the amphibian egg cytoplasm: gravitational force as a probe.

A combination of hypergravity (centrifugation) and hypogravity (clinostat) studies have been carried out on amphibian (frog, Xenopus) eggs. The results reveal that the twinning caused by centrifugation exhibits substantial spawning to spawning variation. That variation can be attributed to the apparent viscosity of the egg's internal cytoplasm. Simulated hypogravity results in a relocation of the egg's third (horizontal) cleavage furrow, towards the equator. Substantial egg-to-egg variation is also observed in this "cleavage effect". For interpreting spaceflight data and for using G-forces as probes for understanding the egg's architecture the egg variation documented herein should be considered.     

Entry of dust particles into planetary magnetospheres

While interplanetary dust constitutes a primary source of cosmic particulate matter in planetary magnetospheres, the debris produced by its impact with small satellites and ring material provides an important secondary source. Internal processes, such as volcanic activity, particularly in the smaller satellites, could result in a third source. In the case of the terrestrial magnetosphere there are also artificial (internal) sources: 1–10μ sized A?₂O₃ particles injected by solid rocket mortar burns between near earth and geosynchronous orbit constitute one such source, while the fragments of larger bodies (artificial satellites) due to explosions (e.g., “killer satellites”) and collisions constitute another. Finally, if we include the purely induced cometary magnetosphere among planetary magnetospheres, the injection of cometary dust into it due to entrainment by the outflowing gases constitutes another source.As a result of being immersed in a radiative and plasma environment these dust grains get electrically charged up to some potential (positive or negative). Particularly in those regions where the magnetospheric plasma is hot and dense and their own spatial density is low, the dust grains could get charged to numerically large negative potentials.While this charging may have physical consequences for the larger grains, such as electrostatic erosion (“chipping”) and disruption, it also can effect the dynamics of the smaller grains. Indeed, the small but finite capacitance of these grains, which leads to a phase lag in the gyrophase oscillation of the grain potential, could even lead to the permanent magneto-gravitational capture of interplanetary grains within planetary magnetospheres in certain situations. Here we will review the sources of dust in planetary magnetospheres and discuss their physics and their dynamics under the combined action of both planetary gravitational and magnetospheric electromagnetic forces.     

Height and time variability of planetary wave activity

The height–season and year-to-year regularities of parameters of first and second spatial harmonics determine the structure of the stratosphere and mesosphere circulation and its variability. In the period 1992–2002 at heights 0–55 km, the amplitudes and phases of the first and second spatial harmonics in the field of temperature, geopotential height, zonal and meridional wind were calculated by the method of harmonic decomposition. Dispersion (standard or mean square deviation) of their day-to-day and year-to-year variations was calculated by their wavelength constants. Height and season patterns of variability have been estimated. The difference in height–longitude variability for wave numbers m = 1 and 2 has been discovered. At the same time, the intensity of wave disturbances for m = 1 is less than for m = 2 excluding the polar areas, where a significant variability appears at the heights 0–55 km. There is also a tendency for the intensity of year-to-year variations to decrease in comparison with day-to-day variations. In cold and warm periods the amplitude of perturbation waves with m = 2 both for day-to-day and year-to-year variations is greater than for waves with m = 1. Transient height areas in the interval of 20–30 km are more distinct for day-to-day variations of polar area.