Cometary Refractory Grains: Interstellar and Nebular Sources

Comets are heterogeneous mixtures of interstellar and nebular materials. The degree of mixing of interstellar sources and nebular sources at different nuclear size scales holds the promise of revealing how cometary particles, cometesimals, and cometary nuclei accreted. We can ascribe cometary materials to interstellar and nebular sources and see how comets probe planet-forming process in our protoplanetary disk. Comets and cometary IDPs contain carbonaceous matter that appears to be either similar to poorly-graphitized (amorphous) carbon, a likely ISM source, or highly labile complex organics, with possible ISM or outer disk heritage. The oxygen fugacity of the solar nebula depends on the dynamical interplay between the inward migration of carbon-rich grains and of icy (water-rich) grains. Inside the water dissociation line, OH^? reacts with carbon to form CO or CO₂, consuming available oxygen and contributing to the canonical low oxygen fugacity. Alternatively, the influx of water vapor and/or oxygen rich dust grains from outer (cooler) disk regions can raise the oxygen fugacity. Low oxygen fugacity of the canonical solar nebula favors the condensation of Mg-rich crystalline silicates and Fe-metal, or the annealing of Fe-Mg amorphous silicates into Mg-rich crystals and Fe-metal via Fe-reduction. High oxygen fugacity nebular conditions favors the condensation of Fe-bearing to Fe-rich crystalline silicates. In the ISM, Fe-Mg amorphous silicates are prevalent, in stark contrast to Mg-rich crystalline silicates that are rare. Hence, cometary Mg-rich crystalline silicates formed in the hot, inner regions of the canonical solar nebula and they are the touchstone for models of the outward radial transport of nebular grains to the comet-forming zone. Stardust samples are dominated by Mg-rich crystalline silicates but also contain abundant Fe-bearing and Fe-rich crystalline silicates that are too large (?0.1 μm) to be annealed Fe-Mg amorphous silicates. By comparison with asteroids, the Stardust Fe-bearing and Fe-rich crystalline silicates suggests partial aqueous alteration in comet nuclei. However, aqueous alteration transforms Fe-rich olivine to phyllosilicates before Mg-rich olivine, and Stardust has Mg-rich and Fe-rich olivine and no phyllosilicates. Hence, we look to a nebular source for the moderately Fe-rich to nearly pure-Fe crystalline silicates. Primitive matrices have Mg-Fe silicates but no phyllosilicates, supporting the idea that Mg-Fe silicates but not phyllosilicates are products of water-rich shocks. Chondrule-formation is a late stage process in our protoplanetary disk. Stardust samples show comet 81P/Wild 2 formed at least as late to incorporate a few chondrules, requiring radial transport of chondrules out to perhaps >20 AU. By similar radial transport mechanisms, collisional fragments of aqueously altered asteroids, in particular achondrites that formed earlier than chondrules, might reach the comet-forming zones. However, Stardust samples do not have phyllosilicates and chondrules are rare. Hence, the nebular refractory grains in comet 81P/Wild 2, as well as other comets, appear to be pre-accretionary with respect to asteroid parent bodies. By discussing nebular pathways for the formation of Fe-rich crystalline silicates, and also phyllosilicates and carbonates, we put forth the view that comets contain both the interstellar ingredients for and the products of nebular transmutation.     

The Solar System d/h Ratio: Observations and Theories

The measured D/H ratios in interstellar environments and in the solar system are reviewed. The two extreme D/H ratios in solar system water - (720±120)×10⁻⁶ in clay minerals and (88±11)×10⁻⁶ in chondrules, both from LL3 chondritic meteorites - are interpreted as the result of a progressive isotopic exchange in the solar nebula between deuterium-rich interstellar water and protosolar H₂. According to a turbulent model describing the evolution of the nebula (Drouart et al., 1999), water in the solar system cannot be a product of thermal (neutral) reactions occurring in the solar nebula. Taking 720×10⁻⁶ as a face value for the isotopic composition of the interstellar water that predates the formation of the solar nebula, numerical simulations show that the water D/H ratio decreases via an isotopic exchange with H₂. During the course of this process, a D/H gradient was established in the nebula. This gradient was smoothed with time and the isotopic homogenization of the solar nebula was completed in 10⁶ years, reaching a D/H ratio of 88×10⁻⁶. In this model, cometary water should have also suffered a partial isotopic re-equilibration with H₂. The isotopic heterogeneity observed in chondrites result from the turbulent mixing of grains, condensed at different epochs and locations in the solar nebula. Recent isotopic determinations of water ice in cold interstellar clouds are in agreement with these chondritic data and their interpretation (Texeira et al., 1999). This revised version was published online in June 2006 with corrections to the Cover Date.     

Chemical and Physical Processing of Presolar Materials in the Solar Nebula and the Implications for Preservation of Presolar Materials in Comets

Chemical and physical processes in the outer solar nebula are reviewed. It is argued that the outer nebula was a chemically active environment with UV photochemistry and ion-molecule chemistry in its low density regions and grain-catalyzed chemistry in Jovian protoplanetary subnebulae. Presolar material was altered to greater or lesser extent by these spatially and temporally variable processes, which mimic many features of interstellar chemistry. Experiments, models, and observations are recommended to address the questions of presolar versus nebular dominance in the outer solar nebula and of how to distinguish interstellar and nebular sources of cometary volatiles. This revised version was published online in June 2006 with corrections to the Cover Date.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

Formation and Composition of Planetesimals

The composition of planetesimals depends upon the epoch and the location of their formation in the solar nebula. Meteorites produced in the hot inner nebula contain refractory compounds. Volatiles were present in icy planetesimals and cometesimals produced in the cold outer nebula. However, the mechanism responsible for their trapping is still controversial. We argue for a general scenario valid in all regions of the turbulent nebula where water condensed as a crystalline ice (Hersant et al., 2004). Volatiles were trapped in the form of clathrate hydrates in the continuously cooling nebula. The epoch of clathration of a given species depends upon the temperature and the pressure required for the stability of the clathrate hydrate. The efficiency of the mechanism depends upon the local amount of ice available. This scenario is the only one so far which proposes a quantitative interpretation of the non detection of N₂ in several comets of the Oort cloud (Iro et al., 2003). It may explain the large variation of the CO abundance observed in comets and predicts an Ar/O ratio much less than the upper limit of 0.1 times the solar ratio estimated on C/2001 A2 (Weaver et al., 2002). Under the assumption that the amount of water ice present at 5 AU was higher than the value corresponding to the solar O/H ratio by a factor 2.2 at least, the clathration scenario reproduces the quasi uniform enrichment with respect to solar of the Ar, Kr, Xe, C, N and S elements measured in Jupiter by the Galileo probe. The interpretation of the non-uniform enrichment in C, N and S in Saturn requires that ice was less abundant at 10 AU than at 5 AU so that CO and N₂ were not clathrated in the feeding zone of the planet while CH₄, NH₃ and H₂S were. As a result, the 14N/15N ratio in Saturn should be intermediate between that in Jupiter and the terrestrial ratio. Ar and Kr should be solar while Xe should be enriched by a factor 17. The enrichments in C, N and S in Uranus and Neptune suggest that available ice was able to form clathrates of CH₄, CO and the NH₃ hydrate, but not the clathrate of N₂. The enrichment of oxygen by a factor 440 in Neptune inferred by Lodders and Fegley (1994) from the detection of CO in the troposphere of the planet is higher by at least a factor 2.5 than the lower limit of O/H required for the clathration of CO and CH4 and for the hydration of NH₃. If CO detected by Encrenaz et al. (2004) in Uranus originates from the interior of the planet, the O/H ratio in the envelope must be around of order of 260 times the solar ratio, then also consistent with the trapping of detected volatiles by clathration. It is predicted that Ar and Kr are solar in the two planets while Xe would be enriched by a factor 30 to 70. Observational tests of the validity of the clathration scenario are proposed.     

Formation of the outer planets

A discussion is given of a number of physical processes which were probably important during the formation of the outer planets if these formed from a gaseous solar nebula in which magnetic effects were not important. Arguments are given that large-scale gravitational instabilities in the solar nebula did not occur. Qualitative consideration is given to the conditions in which dynamical capture of gas onto a planetary core may take place; this may have played a major role in the formation of Jupiter and Saturn. Because of the great difficulty of fractionating hydrogen from helium in the assembly of the outer planets, it is argued that a new approach should be made to the construction of planetary models. Conditions which may lead to the formation of the regular satellite systems are discussed, and the associated problem of removal of primordial angular momentum from Jupiter, Saturn, and Uranus.This is one of the publications by the Science Advisory Group.     

Are There Chemical Gradients in the Inner Solar System?

The solar system is apparently stratified with regard to the contents of volatile constituents, as judged from the rocky, volatile-poor inner solar system planets and meteorites and the huge volatile-rich outer planets. However, beyond this gross structure there is no evidence for a systematic increase of the volatiles' abundances with distance from the Sun. Although meteorites show comparatively large differences in volatile element contents they also differ in many other respects, such as Mg/Si-ratios, bulk Fe and refractory element contents. These variations reflect variations in the nebular environment from which meteorites formed. The various conditions of meteorite formation cannot, however, be related in a simple way to heliocentric distances. There are also no systematic variations in the chemistry of the inner planets Mercury, Venus, Earth, Moon, Mars, and including the fourth largest asteroid Vesta, that could be interpreted as a relationship between volatility and composition. Although Mars (as judged from the composition of Martian meteorites) is more oxidized and contains more volatile elements than Earth, this trend cannot be extrapolated to the dry volatile poor Vesta (sampled by HED meteorites) in the asteroid belt. If the Earth-Mars trend reflects global inner solar system gradients then Vesta must have formed inside Earth's orbit and moved out later to its present location. The quality of Mercury and Venus composition data is not sufficient to allow reliable extrapolation to distances closer to the Sun. Recent nebula models predict small temperature gradients in the inner solar system supporting the view that no large variations in volatile element contents of inner solar system materials are expected. This revised version was published online in June 2006 with corrections to the Cover Date.     

Iron: Whence it came,where it went

Determinations of the abundances of iron and related elements in the photosphere, chromosphere and corona of the Sun and in solar and galactic cosmic rays are reviewed and compared with abundances derived from meteoritic data. Observed Solar System abundances are found to be in accord with predictions of nucleosynthesis under either hydrostatic or explosive conditions but cannot yet be used to define these processes uniquely.Distribution of iron among planets and meteorites can probably be adequately modelled by condensation and fractionation under equilibrium conditions above about 700 K but below that temperature it is likely that inhibited solid state diffusion perturbed attainment of equilibrium. Pertinent factors which are presently unknown include the mechanism responsible for metal-silicate fractionation, the grain size achieved by metallic iron in the nebula and whether iron-bearing silicate formed prior to accretion.Dedicated to Professor Harold C. UreyPublication Number 1560-Institute of Geophysics and Planetary Physics, University of California, Los Angeles.     

Evolution of the Protosolar Nebula and Formation of the Giant Planets

The formation of planetary systems is intimately tied to the question of the evolution of the gas and solid material in the early nebula. Current models of evolution of circumstellar disks are reviewed here with emphasis on the so-called “alpha models” in which angular momentum is transported outward by turbulent viscosity, parameterized by an dimensionless parameter α. A simple 1D model of protoplanetary disks that includes gas and embedded particles is used to introduce key questions on planetesimal formation. This model includes the aerodynamic properties of solid ice and rock grains to calculate their migration and growth. We show that the evolution of the nebula and migration and growth of its solids proceed on timescales that are generally not much longer than the timescale necessary to fully form the star-disk system from the molecular cloud. Contrary to a widely used approach, planet formation therefore can neither be studied in a static nebula nor in a nebula evolving from an arbitrary initial condition. We propose a simple approach to both account for sedimentation from the molecular cloud onto the disk, disk evolution and migration of solids. Giant planets have key roles in the history of the forming Solar System: they formed relatively early, when a significant amount of hydrogen and helium were still present in the nebula, and have a mass that is a sizable fraction of the disk mass at any given time. Their composition is also of interest because when compared to the solar composition, their enrichment in elements other than hydrogen and helium is a witness of sorting processes that occured in the protosolar nebula. We review likely scenarios capable of explaining both the presence of central dense cores in Jupiter, Saturn, Uranus and Neptune and their global composition. This revised version was published online in August 2006 with corrections to the Cover Date.     

Cometary Materials: Progress Toward Understanding the Composition in the Outer Solar Nebula

A major objective of the workshop was to learn about the chemical composition, physical structure, and thermodynamic conditions of the outer parts of the solar nebula where comets formed. Here we sum up what we have learned from years of research about the molecular constituents of comet comae primarily from in situ measurements of Comet 1P/Halley and remote sensing of Comets 1P/Halley, Hale-Bopp (C/1995 O1), and Hyakutake (C/1996 B2). These three bright comets are presumably captured Oort cloud comets. We summarize the analyses of these data to predict the composition of comet nuclei and project them further to the composition, structure, and thermodynamic conditions in the nebula. Near-future comet missions are directed toward less active short-period Jupiter-family comets. Thus, future analyses will afford a better understanding of the diversity of these two major groups of comets and their respective regions of origin in the solar or presolar nebula. We conclude with recommendations for determining critical data needed to aid in further analyses. Results of the workshop provide new guidelines and constraints for modeling the solar nebula. This revised version was published online in June 2006 with corrections to the Cover Date.     

New Horizons: Anticipated Scientific Investigations at the Pluto System

The New Horizons spacecraft will achieve a wide range of measurement objectives at the Pluto system, including color and panchromatic maps, 1.25–2.50 micron spectral images for studying surface compositions, and measurements of Pluto’s atmosphere (temperatures, composition, hazes, and the escape rate). Additional measurement objectives include topography, surface temperatures, and the solar wind interaction. The fulfillment of these measurement objectives will broaden our understanding of the Pluto system, such as the origin of the Pluto system, the processes operating on the surface, the volatile transport cycle, and the energetics and chemistry of the atmosphere. The mission, payload, and strawman observing sequences have been designed to achieve the NASA-specified measurement objectives and maximize the science return. The planned observations at the Pluto system will extend our knowledge of other objects formed by giant impact (such as the Earth–moon), other objects formed in the outer solar system (such as comets and other icy dwarf planets), other bodies with surfaces in vapor-pressure equilibrium (such as Triton and Mars), and other bodies with N₂:CH₄ atmospheres (such as Titan, Triton, and the early Earth).     

Alteration Assemblages in Martian Meteorites: Implications for Near-Surface Processes

The SNC (Shergotty-Nakhla-Chassigny) meteorites have recorded interactions between martian crustal fluids and the parent igneous rocks. The resultant secondary minerals — which comprise up to 1 vol.% of the meteorites — provide information about the timing and nature of hydrous activity and atmospheric processes on Mars. We suggest that the most plausible models for secondary mineral formation involve the evaporation of low temperature (25 – 150 °C) brines. This is consistent with the simple mineralogy of these assemblages — Fe-Mg-Ca carbonates, anhydrite, gypsum, halite, clays — and the chemical fractionation of Ca-to Mg-rich carbonate in ALH84001 "rosettes". Longer-lived, and higher temperature, hydrothermal systems would have caused more silicate alteration than is seen and probably more complex mineral assemblages. Experimental and phase equilibria data on carbonate compositions similar to those present in the SNCs imply low temperatures of formation with cooling taking place over a short period of time (e.g. days). The ALH84001 carbonate also probably shows the effects of partial vapourisation and dehydration related to an impact event post-dating the initial precipitation. This shock event may have led to the formation of sulphide and some magnetite in the Fe-rich outer parts of the rosettes.Radiometric dating (K-Ar, Rb-Sr) of the secondary mineral assemblages in one of the nakhlites (Lafayette) suggests that they formed between 0 and 670 Myr, and certainly long after the crystallisation of the host igneous rocks. Crystallisation of ALH84001 carbonate took place 0.5 Gyr after the parent rock. These age ranges and the other research on these assemblages suggest that environmental conditions conducive to near-surface liquid water have been present on Mars periodically over the last 1 Gyr. This fluid activity cannot have been continuous over geological time because in that case much more silicate alteration would have taken place in the meteorite parent rocks and the soluble salts would probably not have been preserved.The secondary minerals could have been precipitated from brines with seawater-like composition, high bicarbonate contents and a weakly acidic nature. The co-existence of siderite (Fe-carbonate) and clays in the nakhlites suggests that the pCO₂ level in equilibrium with the parent brine may have been 50 mbar or more. The brines could have originated as flood waters which percolated through the top few hundred meters of the crust, releasing cations from the surrounding parent rocks. The high sulphur and chlorine concentrations of the martian soil have most likely resulted from aeolian redistribution of such aqueously-deposited salts and from reaction of the martian surface with volcanic acid volatiles.The volume of carbonates in meteorites provides a minimum crustal abundance and is equivalent to 50–250 mbar of CO₂ being trapped in the uppermost 200–1000 m of the martian crust. Large fractionations in ¹⁸O between igneous silicate in the meteorites and the secondary minerals (30) require formation of the latter below temperatures at which silicate-carbonate equilibration could have taken place (400°C) and have been taken to suggest low temperatures (e.g. 150°C) of precipitation from a hydrous fluid.     

MESSENGER and the Chemistry of Mercury’s Surface

The instrument suite on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft is well suited to address several of Mercury’s outstanding geochemical problems. A combination of data from the Gamma-Ray and Neutron Spectrometer (GRNS) and X-Ray Spectrometer (XRS) instruments will yield the surface abundances of both volatile (K) and refractory (Al, Ca, and Th) elements, which will test the three competing hypotheses for the origin of Mercury’s high bulk metal fraction: aerodynamic drag in the early solar nebula, preferential vaporization of silicates, or giant impact. These same elements, with the addition of Mg, Si, and Fe, will put significant constraints on geochemical processes that have formed the crust and produced any later volcanism. The Neutron Spectrometer sensor on the GRNS instrument will yield estimates of the amount of H in surface materials and may ascertain if the permanently shadowed polar craters have a significant excess of H due to water ice. A comparison of the FeO content of olivine and pyroxene determined by the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) instrument with the total Fe determined through both GRNS and XRS will permit an estimate of the amount of Fe present in other forms, including metal and sulfides.     

Pressure and Temperature Profiles in the Solar Nebula

Pressure and temperature profiles in several recent solar nebula models are reviewed. These parameters are important to cosmochemists because they determine the mineral assemblages that could form or exist in the nebula. This revised version was published online in June 2006 with corrections to the Cover Date.     

Reservoir for Comet Material: Circumstellar Grains

Primitive meteorites and interplanetary dust particles contain small quantities of dust grains with highly anomalous isotopic compositions. These grains formed in the winds of evolved stars and in the ejecta of stellar explosions, i.e., they represent a sample of circumstellar grains that can be analyzed with high precision in the laboratory. Such studies have provided a wealth of information on stellar evolution and nucleosynthesis, Galactic chemical evolution, grain growth in stellar environments, interstellar chemistry, and the inventory of stars that contributed dust to the Solar System. Among the identified circumstellar grains in primitive solar system matter are diamond, graphite, silicon carbide, silicon nitride, oxides, and silicates. Circumstellar grains have also been found in cometary matter. To date the available information on circumstellar grains in comets is limited, but extended studies of matter returned by the Stardust mission may help to overcome the existing gaps.     

Isotopic Composition of the Solar Wind Inferred from In-Situ Spacecraft Measurements

The Sun is the largest reservoir of matter in the solar system, which formed 4.6 Gyr ago from the protosolar nebula. Data from space missions and theoretical models indicate that the solar wind carries a nearly unfractionated sample of heavy isotopes at energies of about 1 keV/amu from the Sun into interplanetary space. In anticipation of results from the Genesis mission’s solar-wind implanted samples, we revisit solar wind isotopic abundance data from the high-resolution CELIAS/MTOF spectrometer on board SOHO. In particular, we evaluate the isotopic abundance ratios ¹⁵N/¹⁴N, ¹⁷O/¹⁶O, and ¹⁸O/¹⁶O in the solar wind, which are reference values for isotopic fractionation processes during the formation of terrestrial planets as well as for the Galactic chemical evolution. We also give isotopic abundance ratios for He, Ne, Ar, Mg, Si, Ca, and Fe measured in situ in the solar wind.     

Formation of Giant Planets– An Attempt in Matching Observational Constraints

We present models of giant planet formation, taking into account migration and disk viscous evolution. We show that migration can significantly reduce the formation timescale bringing it in good agreement with typical observed disk lifetimes. We then present a model that produces a planet whose current location, core mass and total mass are comparable with the one of Jupiter. For this model, we calculate the enrichments in volatiles and compare them with the one measured by the Galileo probe. We show that our models can reproduce both the measured atmosphere enrichments and the constraints derived by Guillot et al. (2004), if we assume the accretion of planetesimals with ices/rocks ratio equal to 4, and that a substantial amount of CO₂ was present in vapor phase in the solar nebula, in agreement with ISM measurements.     

Formation of Planetesimals and Accretion of the Terrestrial Planets

Planetesimals formed in the solar nebula by collisional coagulation. Dust aggregates settled toward the central plane, the larger ones growing by sweeping up smaller ones. A thin, dense layer of particles formed; shear-generated turbulence and differential motions induced by gas drag inhibited gravitational instability. Growth proceeded by collisions, producing planetesimals on a timescale of a few thousand years in the terrestrial zone. For bodies smaller than about a kilometer, motions were dominated by gas drag, and impact velocities decreased with size. At larger sizes gravitational interactions became significant, and velocities increased due to mutual perturbations. Larger bodies then grew more rapidly, this ``runaway' led to formation of tens to hundreds of lunar- to Mars-sized planetary embryos in the zone of terrestrial planets. The final accretion of these bodies into a few planets involved large impacts, and occurred on a timescale of 10⁷ to 10⁸ years. This scenario gives a reasonably consistent picture of the origin of the terrestrial planets, but does not account for the anomalously low eccentricities of the Earth and Venus. This revised version was published online in June 2006 with corrections to the Cover Date.     

Effects of Low Energetic Neutral Atoms on Martian and Venusian Dayside Exospheric Temperature Estimations

The heating of the upper atmospheres and the formation of the ionospheres on Venus and Mars are mainly controlled by the solar X-ray and extreme ultraviolet (EUV) radiation (λ = 0.1–102.7 nm and can be characterized by the 10.7 cm solar radio flux). Previous estimations of the average Martian dayside exospheric temperature inferred from topside plasma scale heights, UV airglow and Lyman-α dayglow observations of up to ∼500 K imply a stronger dependence on solar activity than that found on Venus by the Pioneer Venus Orbiter (PVO) and Magellan spacecraft. However, this dependence appears to be inconsistent with exospheric temperatures (<250 K) inferred from aerobraking maneuvers of recent spacecraft like Mars Pathfinder, Mars Global Surveyor and Mars Odyssey during different solar activity periods and at different orbital locations of the planet. In a similar way, early Lyman-α dayglow and UV airglow observations by Venera 4, Mariner 5 and 10, and Venera 9–12 at Venus also suggested much higher exospheric temperatures of up to 1000 K as compared with the average dayside exospheric temperature of about 270 K inferred from neutral gas mass spectrometry data obtained by PVO. In order to compare Venus and Mars, we estimated the dayside exobase temperature of Venus by using electron density profiles obtained from the PVO radio science experiment during the solar cycle and found the Venusian temperature to vary between 250–300 K, being in reasonable agreement with the exospheric temperatures inferred from Magellan aerobraking data and PVO mass spectrometer measurements. The same method has been applied to Mars by studying the solar cycle variation of the ionospheric peak plasma density observed by Mars Global Surveyor during both solar minimum and maximum conditions, yielding a temperature range between 190–220 K. This result clearly indicates that the average Martian dayside temperature at the exobase does not exceed a value of about 240 K during high solar activity conditions and that the response of the upper atmosphere temperature on Mars to solar activity near the ionization maximum is essentially the same as on Venus. The reason for this discrepancy between exospheric temperature determinations from topside plasma scale heights and electron distributions near the ionospheric maximum seems to lie in the fact that thermal and photochemical equilibrium applies only at altitudes below 170 km, whereas topside scale heights are derived for much higher altitudes where they are modified by transport processes and where local thermodynamic equilibrium (LTE) conditions are violated. Moreover, from simulating the energy density distribution of photochemically produced moderately energetic H, C and O atoms, as well as CO molecules, we argue that exospheric temperatures inferred from Lyman-α dayglow and UV airglow observations result in too high values, because these particles, as well as energetic neutral atoms, transformed from solar wind protons into hydrogen atoms via charge exchange, may contribute to the observed planetary hot neutral gas coronae. Because the low exospheric temperatures inferred from neutral gas mass spectrometer and aerobraking data, as well as from CO⁺ ₂ UV doublet emissions near 180–260 nm obtained from the Mars Express SPICAM UV spectrograph suggest rather low heating efficiencies, some hitherto unidentified additional IR-cooling mechanism in the thermospheres of both Venus and Mars is likely to exist. An erratum to this article can be found at     

Presolar Grains in Meteorites and Their Compositions

Small amounts of pre-solar “stardust” grains have survived in the matrices of primitive meteorites and interplanetary dust particles. These grains—formed directly in the outflows of or from the ejecta of stars—include thermally and chemically refractory carbon materials such as diamond, graphite and silicon carbide; as well as refractory oxides and nitrides. Pre-solar silicates, which have only recently been identified, are the most abundant type except for possibly diamond. The detailed study with modern analytical tools, of isotopic signatures in particular, provides highly accurate and detailed information with regard to stellar nucleosynthesis and grain formation in stellar atmospheres. Important stellar sources are Red Giant (RG) and Asymptotic Giant Branch (AGB) stars, with supernova contributions apparently small. The survival of those grains puts constraints on conditions they were exposed to in the interstellar medium and in the early solar system.