Operational testing of valve regulated lead acid batteries incommercial aircraft

Valve regulated lead acid (VRLA) batteries provide electrical performance that is virtually identical to sintered plate nickel-cadmium battery systems. In addition, the VRLA batteries offer the user a no-maintenance battery and other enhanced features that make this a very desirable battery for aircraft applications. In field trials, where VRLA batteries were substituted for nickel-cadmium batteries, the VRLA provided the user with a high reliability turbine engine starting battery under a wide variety of climatic conditions     

Life cycle testing of a sealed 24-V, 42-Ah nickel-cadmium aircraftbattery

Extensive research has been conducted in the design and manufacture of very long life sealed maintenance free nickel-cadmium aircraft batteries. This study presents data on a 100% depth of discharge (DOD) life test performed on a nominal capacity 42-Ah battery. The purpose of this study is to validate design concepts, determine the life characteristics of the newly designed sealed Ni-Cd batteries, and develop baseline information on failure rates and mechanisms. The data from this experiment can be used to compare depth of discharge versus battery life with similar tests such as the lower DOD experiments performed on spacecraft batteries. This information is important in the ongoing development of long life batteries and in developing failure models for life prediction     

Nickel-Cadmium Batteries as Capacitive Filters for Pulsed Loads

This investigation consisted of several tests of specially fabricated nickel-cadmium batteries having circular disk-type electrodes. These batteries were evaluated as filter elements between a constant current power supply and a 5 Hz pulsed load demanding approximately twice the power supply current during the load on a portion of the cycle. Short tests lasting 104 cycles were conducted at up to a 21 C rate and an equivalent energy density of over 40 J/Ib. In addition, two batteries were subjected to 10h dischar cycles, one at a 6.5 C rate and the other at a 13 C rate. Assuming an electrode-to-battery weight ratio of 0.5, these tests represent an energy density of about 7 and 14 J/Ib, respectively. Energy density, efficiency, capacitance, average voltage, and available capacity were tracked during these tests. After 10y capacity degradation was negligible for one battery and about 20 percent for the other. Cadmium electrode failure may be the factor limiting lifetime at extremely low depth of discharge cycling. The output was examined and a simple equivalent circuit was proposed.     

Nickel-hydrogen multicell common pressure vessel batterydevelopment update

Flight qualification of the multicell common pressure vessel (CPV) nickel-hydrogen (Ni-H₂) battery is discussed. The battery has completed full flight qualification, including random vibration at 19.5 g for two minutes in each axis, electrical characterization in a thermal vacuum chamber, and mass-spectroscopy vessel leak detection. A first launch is scheduled in 1992. Several design variations, ranging from 9 Ah to 125 Ah and 12 to 32 V, have been developed and prototypes fabricated. Designs for smaller capacity, smaller diameter (6.4-8.9 cm), and higher voltage (up to 100 V) are in progress. The CPV battery offers cost and weight savings of up to 30% as compared to traditional nickel-cadmium (Ni-Cd) and individual pressure vessel (IPV) Ni-H₂ batteries. The fully qualified design provided a 50% weight savings over its Nd-Cd predecessor for the same application. Its reduced volume also provides a significant advantage over IPV technology. Resistance data show a further advantage     

A maintenance-free lead acid battery for inertial navigationsystems aircraft

Historically, aircraft inertial navigation system (INS) batteries have utilized vented nickel-cadmium batteries for emergency DC power. The United States Navy and Air Force developed separate systems during their respective INS developments. The Navy contracted with Litton industries to produce the LTN-72 and Air Force contracted with Delco to produce the Carousel IV INS for the large cargo and specialty aircraft applications, over the years, a total of eight different battery national stock numbers (NSNs) have entered the stock system along with 75 battery spare part NSNs. The standard hardware acquisition and reliability program is working with the Aircraft Battery Group at Naval Surface Warfare Center Crane Division, Naval Air Systems Command (AIR 536), Wright Laboratory, Battelle Memorial Institute, and Concorde Battery Corporation to produce a standard INS battery. This paper discusses the approach taken to determine whether the battery should be replaced and to select the replacement chemistry. The paper also discusses the battery requirements, aircraft that the battery is compatible with, and status of Navy flight evaluation. Projected savings in avoided maintenance in Navy and Air Force INS systems is projected to be $14.7 million per year with a manpower reduction of 153 maintenance personnel. The new INS battery is compatible with commercially sold INS systems which represents 66% of the systems sold     

Five-year update: nickel hydrogen industry survey

A 1984 survey of the nickel hydrogen (NiH₂) battery industry is updated. Late 1980s and early 1990s issues are identified, and usage and testing results of the survey are summarized. NiH₂ is the system of choice for new geosynchronous-earth-orbit (GEO) satellites and is being seriously considered for low-earth-orbit (LEO) applications. In five years, the annual cell production rate has doubled from approximately 1000 to 2000 cells. A number of cells under test have exceeded 20000 cycles at 40% DOD in LEO regimes, while other cells have achieved over 35 seasons in accelerated GEO regimes. The LEO database clearly indicates that NiH₂ performance is at least as good as the best conventional nickel-cadmium performance demonstrated under test     

Safety tests of lithium 9-volt batteries for Navy applications

COTS batteries are relatively inexpensive, readily accessible, and extremely versatile. These attributes allow the military to save time and money during the research and development stages. Of these COTS batteries, a 9-Volt (9 V) lithium/manganese dioxide battery is the subject of this paper. This 9 V battery has the ability to provide a low magnetic signature, which is very important to the Navy for many applications, Also, it is Underwriters Laboratories (UL) listed at the unit level; however, these UL tests cannot be directly related to the safety of these 9 V batteries when they are combined in various series and parallel configurations. Naval Surface Warfare Center (NSWC) Carderock was tasked to rate the safety of several such specialized battery packs. It was found that packs consisting of two 9 V batteries in parallel were relatively safe, experiencing no violent behavior. Battery packs with six 9 Vs in parallel vented and deformed the 9 V batteries, but no smoke or flames were noticed. A battery pack with thirty 9 V batteries, 2 in series with 15 legs, experienced venting, smoke, and flames under certain circumstances, After testing, the six and thirty 9 V packs were required to include the addition of various safety devices     

Electric vehicles (EVs): `a look behind the scenes'

The author addresses and summarizes some of the broader issues relating to electric vehicles including legislation, regulation, funding, infrastructure, niche markets, safety, and the near-term need for lead-acid batteries. The impact of low emission requirements is examined. The principle hazards associated with lead-acid batteries and the attendant liability issues are identified. Federal safety requirements are discussed in some detail     

Self-discharge losses in lithium-ion cells

The self-discharge losses in several lithium-ion cell designs have been measured by three different methods. The losses are separated into time-dependent and state-of-charge dependent contributions. For most cycling conditions, the time-dependent self-discharge losses are dominant; however, after several months of stand on open circuit or float charge, the state-of-charge dependent losses become significant. The self-discharge rate has been found to not increase monotonically with state-of-charge, but to drop somewhat at intermediate states of charge. The implications of these measurements for maintaining balanced cell capacities in batteries and establishing optimum storage voltage levels for batteries are discussed.     

航空锂电池适航审定规章解读及符合性方法研究

锂离子电池作为动力电池有着优异的性能,在民航行业上有广阔的应用前景。但行业对其技术特征 和安全风险的认识还不充分,现行的规章条款缺乏足够的安全要求,国外局方针对锂离子电池颁发了专用条 件,但回顾相关事故可以发现,锂离子电池的验证和审查环节还不完善,相关条款更新修正的步伐也同锂电池 的发展现状和技术水平不相适应。以航空锂电池事故为例,分析航空锂离子电池作为动力电池的安全性风险, 从对现有规章条款和专用条件的解读出发,借鉴不同行业近年来积累的锂电池验证和使用经验,针对航空动力 锂电池的适航符合性方法提出一些改进方案,可作为现有锂电池适航符合性方法的有益补充,为自主建立健全 适航验证规范体系做出探索。     

Bipolar nickel-metal hydride batteries for aerospace applications

Electro Energy Inc. (EEI) is developing high power, long life, bipolar nickel-metal hydride batteries for aerospace applications. Bipolar nickel-metal hydride designs allow for high energy and high power designs with a 25 percent reduction in both weight and volume as compared to prismatic and/or cylindrical Ni-MH designs. Utilizing a sealed wafer cell design EEI has demonstrated a 1.2 kW/kg power capability. Prototype designs have achieved 70 Wh/kg. Designs studies show 80 Wh/kg are achievable with EEI's state-of-the-art technology. The sealed wafer cell is the building block for EEI's high power and high voltage bipolar batteries making the assembly easy and significantly lower in cost. Satellite and aircraft batteries are being developed which provide high power and long life. Sealed cells now show excellent rate capability and life. Cells tested in a low earth orbit (LEO) cycle have reached 9000 cycles and continue on test. High power, bipolar battery designs are ideal in applications where using conventional aerospace battery technology would require excessive capacity; weight and volume, thereby reducing usable payload on the vehicle     

A microcontroller-based intelligent battery system

State-of-charge indication for a secondary battery is becoming increasingly important for battery-operated electronics. Consumers are demanding fast charging times, increased battery lifetime, and fuel gauge capabilities. All of these demands require that the state of charge within a battery be known. One of the simplest methods employed to determine state of charge is to monitor the voltage of the battery. However, this method alone is not a good indicator of battery energy, since both NiMH and NiCd batteries have voltage-versus-energy curves that are essentially flat. This paper presents a more effective method of determining the state of charge in secondary cell batteries. A NiMH battery is used as our test vehicle, since it is one of the more difficult batteries to determine state of charge. This method monitors the battery's temperature, voltage, and discharge/charge rate. A microcontroller then manipulates the information, using look-up tables to determine the state of charge. Also, by modifying the look-up tables, this technique can be employed in many other battery technologies and is not limited to NiMH     

Hubble performance on-orbit

A summary of the Hubble Space Telescope (HST) nickel-hydrogen (NiH/sub 2/) battery performance from launch to the present. Over the life of HST vehicle configuration, charge system degradation and failures, together with thermal design limitations, have had a significant effect on the capacity of HST batteries. Changes made to the charge system configuration to protect against power system failures and to maintain battery thermal stability resulted in undercharging of the batteries. This undercharging resulted in decreased usable battery capacity as well as battery cell voltage/capacity divergence. This cell divergence was made evident during on-orbit battery capacity measurements by a relatively shallow slope of the discharge curve following the discharge knee. Early efforts to improve battery performance have been successful. On-orbit capacity measurement data indicates increases in the usable battery capacity of all six batteries as well as improvements in the battery cell voltage/capacity divergence. Additional measures have been implemented to improve battery performance, however, failures within the HST Power Control Unit (PCU) have prevented verification of battery status.     

The passenger aircraft cargo hold environment: the implications of a fire on lithium-ion battery shipments

Although very rare events, fires in aircraft cargo holds are a concern for regulators, aircraft operators, and passengers. Lithium-ion cells and batteries are often shipped as cargo aboard passenger aircraft. This paper provides an overview of cargo hold configurations and fire suppression systems in passenger aircraft. Next, ways in which a cargo hold fire might affect a shipment of lithium-ion cells or batteries, and the degree to which the cells or batteries might interact with a fire are discussed. Finally, the results of FAA simulated cargo hold fire testing are presented and discussed in the context of lithium-ion cell or battery shipments.     

Aerospace lithium solid polymer batteries

Lockheed Martin Missiles and Space and Ultralife Batteries, Inc. are developing batteries for spacecraft and launchers based on Li-ion solid-polymer-electrolyte cell technology. These cells utilize a carbon anode, a manganese dioxide cathode and a solid polymer electrolyte. Electrode and electrolyte layers are thin and flexible. The electrode assembly is easily fabricated into thin, flat prismatic shapes using ordinary lamination techniques and is hermetically sealed in thin foil packaging. Cells ranging in capacity from 4 Ah to 50 Ah have been designed and are in development testing. The packaged cells have specific energies in excess of 100 Wh/kg. Prototype 30 volt batteries have also been designed and are being assembled and tested along with the critical battery cell charge management controllers needed to recharge all cells to full capacity while preventing overvoltage damage. The major results of this development effort are reviewed and the key issues for advancing this technology to flight qualification demonstrations are discussed     

Portable power source needs of the future Army-batteries and fuelcells

This paper describes the US Army's future needs for silent portable power in the area of batteries and fuel cells. These needs will continue to increase as a result of the introduction of newer types of equipment, the increasing digitization of the battlefield, and future integrated Soldier Systems. Current battery programs are aimed at improved, low-cost primary batteries, and rechargeable batteries with increased energy densities. The Army fuel cell program aimed at portable systems capable of the order of 150 W is also described     

Lithium-ion battery software safety protection

Production Li-ion batteries include hardware and software safety protection. The hardware protection includes PTC (positive temperature coefficient) thermistor switch, electrical circuit disconnect and rupture vent. The software protection involves a charging algorithm (charging to ultimate voltage), which is used with internal electrical circuitry (cell voltage control and equalization circuit). This paper discusses a specific charging algorithm and additional software protection features associated with hard, soft and chemical shunt recognition     

Safety testing of lithium ion batteries for navy devices

Lithium ion battery technology is being introduced into power supplies used by our armed forces for a variety of applications. In many cases, the same cells and design parameters that support commercial battery packs are being used in military battery packs. This approach is expected to result in a major decrease in the total life cycle cost of the equipment these batteries support. On June 13, 1991, NAVSEA issued INST9310.1B1, which states that all lithium battery powered equipment must undergo safety evaluation and approval prior to fleet use. This safety program governs a process whereby approvals are issued for lithium batteries to be used in specific equipment on ground facilities, surface combatants, air combatants, and/or submarines. The Naval Ordnance Safety and Security Activity (NOSSA) manages the program. The chief technical advisors are Code 644 at NSWC Carderock Division and Code 609A at NSWC Crane Division. This paper describes three battery designs that incorporate lithium ion technology, and the results of battery safety tests conducted in accordance with navy requirements.     

Hubble Space Telescope at twelve years of age

The Hubble Space Telescope was deployed from the Space Shuttle Discovery into a 380-mile high Earth orbit on April 25, 1990. It subsequently made outstanding astronomical discoveries with its 8-foot (2.4-meter) telescope and other scientific instruments. Critical to the successful observations was continuous availability of power from its solar arrays during sunlit periods, and from nickel-hydrogen batteries when the satellite was in the Earth's shadow. The adopted nickel-hydrogen batteries were carefully selected and tested to confirm their depth-of-discharge and operating temperature that delivered the longest life in charge/discharge cycling service. These batteries had a design life of 7 years. At 12 years after launch the Hubble batteries have delivered more charge/discharge cycles than any other batteries in low-Earth orbit. However, the Hubble batteries have been subjected to many unexpected stresses, and peculiar reductions in battery capacity have been observed. Battery replacement requires a costly trip to the Hubble Space Telescope by astronauts, so the remaining useful life of the batteries must be predicted. Already in four servicing missions, astronauts have replaced or modified optics, solar arrays, a power control unit, and various science packages. A fifth servicing mission is scheduled in 2004. This paper discusses battery charging hardware and software controls, history of battery events in Hubble, cell performance model and spare battery tests, and capacity walkdown.